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The composition, size distribution, and abundance of floating plastic debris in surface waters of the Mediterranean Sea were analyzed in relation to distance to land. We combined data from previously published reports with an intensive sampling in inshore waters of the Northwestern Mediterranean. The highest plastic concentrations were found in regions distant from from land as well as in the first kilometer adjacent to the coastline. In this nearshore water strip, plastic concentrations were significantly correlated with the nearness to a coastal human population, with local areas close to large human settlements showing hundreds of thousands of plastic pieces per km2. The ratio of plastic to plankton abundance reached particularly high values for the coastal surface waters. Polyethylene, polypropylene and polyamides were the predominant plastic polymers at all distances from coast (86 to 97% of total items), although the diversity of polymers was higher in the 1-km coastal water strip due to a higher frequency of polystyrene or polyacrylic fibers. The plastic size distributions showed a gradual increase in abundance toward small sizes indicating an efficient removal of small plastics from the surface. Nevertheless, the relative abundance of small fragments (< 2 mm) was higher within the 1-km coastal water strip, suggesting a rapid fragmentation down along the shoreline, likely related with the washing ashore on the beaches. This study constitutes a first attempt to determine the impact of plastic debris in areas closest to Mediterranean coast. The presence of a high concentration of plastic including tiny plastic items could have significant environmental, health and economic impacts.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4996504 | PMC |
http://journals.plos.org/plosone/article?id=10.1371/journal.pone.0161581 | PLOS |
Langmuir
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State Grid Hubei Electric Power Xiaogan Power Supply Co., Xiaogan 430075, China.
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Department of Obstetrics, The Second Hospital of Shandong University, Jinan, 250033, PR China. Electronic address:
Background: Sulfur dioxide (SO) is recognized as a major atmospheric pollutant and its excessive emissions can pose a great threat to the environment, flora and fauna, and human health. Long-term exposure to excessive SO can cause chronic poisoning, leading to neurological disorders and cardiovascular diseases. However, there are two sides to everything.
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Inner Mongolia Key Laboratory for the Natural Products Chemistry and Functional Molecular Synthesis; College of Chemistry and Materials Science, Inner Mongolia Minzu University, Tongliao 028000, PR China. Electronic address:
A hydrophilic phenothiazine-based fluorescent probe (PTZMN) was developed for the selective and sensitive detection of hypochlorite (ClO) in pure water. Upon ClO stimulation, PTZMN exhibited a distinct colorimetric shift and a "turn-on" fluorescence response at 496 nm, with a low detection limit of 5.2 × 10 mol/L and excellent linearity (R = 0.
View Article and Find Full Text PDFJ Fluoresc
September 2025
Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran.
A novel fluorescent and colorimetric probe (L3), based on 2,6-pyridinedicarbohydrazide, was rationally designed and synthesized for the highly selective and reversible detection of Cu²⁺ ions. The structural and optical properties of the probe were comprehensively characterized by FT-IR, ¹H NMR, UV-Vis spectroscopy, fluorescence analysis, ESI⁺-MS, and elemental analysis. The probe L3 displayed a high selectivity, high sensitivity and quick response to Cu ions in the presence of other competing cations including Ba, K, Pb, Hg, Al, Zn, Fe, Tl, Mg, Ni, Nd, Fe, Ag, Ca, Cs, Co, Cd, Sr, and Mn ions).
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
August 2025
School of Pharmacy, North China University of Science and Technology, Tangshan 063210, PR China. Electronic address:
Sulfite (HSO) and hypochlorous acid (HClO) serve as essential food additives and key raw materials in bleaching agents. However, excessive consumption of these compounds may disrupt cellular redox homeostasis, leading to a series of adverse physical effects. Therefore, the development of reliable analytical methods to detect HSO and HClO levels in food products is of significant importance.
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