Highly active self-immobilized FI-Zr catalysts in a PCP framework for ethylene polymerization.

Chem Commun (Camb)

State Key Laboratory for Supramolecular Structure and Materials, School of Chemistry, Jilin University, 2699 Qianjin Avenue, Changchun, 130012, China.

Published: December 2015


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Article Abstract

A series of zirconium-based porous coordination polymers (PCPs) containing FI catalysts in the frameworks have been developed and studied as catalysts for ethylene polymerization. These PCPs exhibit good catalytic activities and long life times, producing polyethylenes with high molecular weights and bimodal molecular weight distribution in the form of particles.

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http://dx.doi.org/10.1039/c5cc06460kDOI Listing

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