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Two groups of retrieved tibial inserts from one manufacturer's knee system were analyzed to evaluate the effect of a highly cross-linked bearing surface on wear and in vivo oxidation. The two groups ((1) conventional gamma-inert sterilized and (2) highly cross-linked, coupled with the same rough (Ra=0.25) Ti-6Al-4V tray) were matched with statistically similar in vivo duration and patient variables. The retrieved inserts were analyzed for ketone oxidation and wear in the form of dimensional change. The difference in oxidation rate between highly cross-linked and conventional gamma-inert sterilized inserts did not reach statistical significance. Observations suggest that the majority of wear can be accounted for by the backside interface with the rough Ti-6Al-4V tray; however, wear measured by thickness-change rate was statistically indistinguishable between the two bearing materials.
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http://dx.doi.org/10.1016/j.arth.2015.06.014 | DOI Listing |
Langmuir
September 2025
Department of Materials Science and Engineering, Drexel University, Philadelphia, Pennsylvania 19104, United States.
The surfaces of 1D layered lepidocrocite-structured titanates (1DLs) are negatively charged due to an oxygen-to-titanium atomic ratio >2. This, and their layered structure, allow for facile ion exchange and high colloidal stability, demonstrated by ζ-potentials of ≈ -85 mV at their unadjusted pH of ≈10.4.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Department of Materials Science and Engineering, College of Engineering, Texas A&M University, College Station, Texas 77843, United States.
Hydrogel-based bioinks are widely adopted in digital light processing (DLP) 3D printing. Modulating their mechanical properties is especially beneficial in biomedical applications, such as directing cell activity toward tissue regeneration and healing. However, in both monolithic and granular hydrogels, the tunability of mechanical properties is limited to parameters such as cross-linking or packing density.
View Article and Find Full Text PDFWater Res
August 2025
School of Materials and Energy, University of Electronic Science and Technology of China, 610054 Chengdu, China; Sichuan Province Engineering Technology Research Center of Novel CN Polymeric Materials, Chengdu, China. Electronic address:
The scalable fabrication of high performance dyes desalination loose nanofiltration (LNF) membrane through facile thermal annealing remains challenging due to the susceptible pore collapse. Herein, we have developed a metal ion mediated sub-Tg thermal crosslinking protocol, which can convert the phase inverted reactive polymeric ultrafiltration substrate into LNF membrane showing high permselectivity as well as resistance to both extremely acid and alkaline solution. The original ultrafiltration substrate was composed of scalable-produced reactive polyarylene ether amidoxime (PEA) that was pre-crosslinked with ferric ions.
View Article and Find Full Text PDFAdv Mater
September 2025
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, 130012, P. R. China.
Developing amphibious adhesives that combine high adhesion strength with on-demand erasability in both dry and wet environments remains a significant challenge. In this study, biomass-derived, amphibious, and erasable adhesives are fabricated by grafting 3-aminobenzoic acid and 3-aminobenzeneboronic acid onto epoxidized soybean oil (ESO), yielding ESO-Am adhesives. These adhesives are dynamically cross-linked with boroxines, hydrogen bonds, and hydrogen-bonded hydrophobic nanodomains.
View Article and Find Full Text PDFSpecific protein detection plays a crucial role in biological analysis and clinical diagnostics, serving as an essential tool for disease diagnosis, therapeutic monitoring, and biological research. However, conventional methods such as immunofixation electrophoresis (IFE) and western blotting (WB) suffer from complex workflows, time-consuming operations, and limited quantification capabilities owing to intricate staining and de-staining procedures. In addition, these traditional immunological detection methods require extensive manual handling and specialized expertise, while low levels of automation restrict their applicability to high-throughput or large-scale analysis scenarios.
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