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The effective annealing times (t(eff)) for nucleating various oxides from an amorphous matrix under nanosecond pulsed laser irradiation have been determined. The oxides, which had perovskite, bixbyite, anatase, and pyrochlore structures, showed similar t(eff) values for crystal nucleation of around 60 ns. This indicates that the effective annealing time is a good universal value for evaluating pulsed laser-induced oxide nucleation. Time-resolved resistance measurements of tin-doped In2O3 thin films under pulsed laser irradiation showed that crystal nucleation and rapid growth proceeded spontaneously with an instantaneous temperature rise.
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http://dx.doi.org/10.1039/c3cp52224e | DOI Listing |
J Phys Chem Lett
September 2025
National Laboratory of Solid-State Microstructures, School of Electronic Science and Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, P. R. China.
Stress engineering is an effective way to tune the performance of semiconductors, which has been verified in the work of inorganic and organic single-crystal semiconductors. However, due to the limitations of the vapor-phase growth preparation conditions, the deposited polycrystalline organic semiconductors are more susceptible to residual stress. Therefore, it is of great research significance to develop a low-cost stress engineering applicable to vapor-deposited semiconductors.
View Article and Find Full Text PDFSmall
September 2025
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing, 100875, China.
This study presents a novel carbazole derivative functionalized with hydroxy diphosphonic acid groups (HDPACz) as an efficient annealing-free hole transport layer (HTL) through strong bidentate anchoring to indium tin oxide (ITO). Compared to conventional mono-phosphonic acid counterparts, HDPACz demonstrates superior ITO surface coverage and interfacial dipole, effectively modulating the work function of ITO. Theoretical calculations reveal enhanced adsorption energy (-3.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou, 450000, China.
With growing public attention to environmental issues and sustainable development, biodegradable bio-based plastics have attracted widespread interest. This study reveals the chemical-physical synergistic regulation mechanism of biodegradable PLA/PBAT blends through the synergistic modification of epoxidized natural rubber (ENR) and epoxy chain extender (ADR). Interfacial interaction analysis shows that PBAT tends to encapsulate ENR to form aggregates.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
Ministry-of-Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei Key Laboratory of Polymer Materials, School of Materials Science & Engineering, Hubei University, Wuhan 430062, PR China. Electronic address:
Effective removal of ethylene (CH) during fruit and vegetables storage and transport remains a critical challenge for post-harvest preservation. Although S-scheme heterojunctions can improve charge separation and redox capacity for ethylene degradation, their efficiency is still restricted by limited carrier transfer and sluggish oxygen activation. Here, we rationally designed a novel 2D/2D SnNbO/BiMoO monolayer S-scheme heterojunction integrated with Pt co-catalyst to address these limitations.
View Article and Find Full Text PDFChem Sci
August 2025
State Key Laboratory of Antiviral Drugs, Pingyuan Laboratory, NMPA Key Laboratory for Research and Evaluation of Innovative Drug, School of Chemistry and Chemical Engineering, Henan Normal University 46 Jianshe Road Xinxiang 453007 China +86
The construction of polymer-based photoactivated room-temperature phosphorescence systems remains a prominent research focus, yet the development of ultrafast activated systems under ambient conditions continues to pose a challenge. In this study, cyclized phenothiazine derivatives bearing diverse substituents are synthesized and incorporated into an amorphous polyvinyl alcohol (PVA) matrix, resulting in significantly enhanced dynamic photoactivation characteristics compared with those of their pristine monomeric counterparts. Under ambient conditions and 2 s irradiation, the lifetime and quantum yield of C[4]PTZ-OH@PVA increase by factors of 1.
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