Synthesis of lead-free (K, Na)(Nb, Ta)O3 nanopowders using a sol-gel process.

J Nanosci Nanotechnol

Department of Materials Science and Engineering, Korea University, Seoul 136-713, Korea.

Published: April 2012


Category Ranking

98%

Total Visits

921

Avg Visit Duration

2 minutes

Citations

20

Article Abstract

Lead-free (K0.5Na0.5)(Nb0.7Ta0.3)O3 piezoelectric material was successfully synthesized via a sol-gel process. Crystalline (K0.5Na0.5)(Nb0.7Ta0.3)O3 nanopowders were obtained after heat treatment at 700 degrees C. The particle size was estimated to be 87nm +/- 23 nm. The transmission electron microscopy images showed that individual nanoparticles were single crystalline and had a pseudo-cubic structure with a lattice parameter of -3.96 angstroms. Both X-ray diffraction and scanning electron microscopy studies consistently showed that the crystallization of the (K0.5Na0.5)(Nb0.7Ta0.3)O3 occurred slightly above 500 degrees C. The samples have an appropriate stoichiometry as found via energy dispersive X-ray spectroscopy. The demonstration of the synthesis of (K0.5Na0.5)(Nb0.7Ta0.3)O3 via a sol-gel process as presented in this paper can provide an important foundation for the development of a synthetic route towards (K0.5Na0.5)(Nb0.7Ta0.3)O3 doped with various other elements for high performance piezoelectric devices.

Download full-text PDF

Source
http://dx.doi.org/10.1166/jnn.2012.5585DOI Listing

Publication Analysis

Top Keywords

sol-gel process
12
electron microscopy
8
k05na05nb07ta03o3
5
synthesis lead-free
4
lead-free nanb
4
nanb tao3
4
tao3 nanopowders
4
nanopowders sol-gel
4
process lead-free
4
lead-free k05na05nb07ta03o3
4

Similar Publications

The persistent presence of Metronidazole (MTZ), a commonly used antibiotic, in water bodies is a serious environmental and health concern because of its genotoxic and carcinogenic potential. Here, we report an effective visible-light photocatalyst system comprising an S-scheme glycine-modified TiO/FeO heterojunction immobilized on chitosan-polyacrylonitrile nanofibers. The photocatalyst nanocomposite was synthesized through a sol-gel and ultrasonication process coupled with electrospinning-assisted immobilization.

View Article and Find Full Text PDF

Hollow Double-Layered Mesoporous Silica as an Enzyme Immobilization Platform: Enhancing Biocatalytic Efficiency in Docosahexaenoic Acid Phosphatidylcholine-Phosphatidylcholine.

ACS Appl Mater Interfaces

September 2025

Oil Crops Research Institute, Hubei Key Laboratory of Lipid Chemistry and Nutrition, Hubei Hongshan Laboratory, Key Laboratory of Oilseeds Processing, Ministry of Agriculture, Chinese Academy of Agricultural Sciences, Wuhan 430062, China.

This study reports the synthesis of bifunctional hollow double-layered mesoporous silica (HdlMS) nanoparticles as an effective support for enzyme catalysis. Using a self-template method combined with sol-gel processing, selective etching, and surface modification with alkyl groups and nitrogenous fatty amine groups, we successfully prepared the NH/C-HdlMS carrier. Phospholipase A1 was then immobilized onto this carrier to construct PLA1@NH/C-HdlMS, which was subsequently applied to the synthesis of docosahexaenoic-acid-enriched phosphatidylcholine.

View Article and Find Full Text PDF

A new, readily accessible inorganic hole transporting material (HTM), Cu doped SnCoO (Cu-SCO), is developed for inverted tin-perovskite solar modules (TPSMs). To overcome the intrinsic defect of inorganic solid-state material Cu-SCO and potential interfacial incompatibility with TPsk, an amphiphilic neutral donor-acceptor copolymer (PTSN) is rationally designed as a surface/interface modification agent. TPSMs based on Cu doped SnCoO HTLs integrated with PTSN surface/interface modification achieved the highest conversion efficiency of 10.

View Article and Find Full Text PDF

Sustainable TOCNS/chitosan aerogels: Green synthesis, enhanced flavonoid adsorption, and recyclability for environmental applications.

Int J Biol Macromol

September 2025

Jiangsu Co-Innovation Centre of Efficient Processing and Utilization of Forest Resources, Jiangsu Key Lab for the Chemistry and Utilization of Agro-Forest Biomass, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, PR China. Electronic address:

In response to the urgent need for highly efficient adsorbents for natural flavonoid compounds, this study proposes a novel layered porous aerogel (TOCNS@CS) based on a synergistic hydrogen bonding/electrostatic interaction mechanism. Through a green aqueous sol-gel method, TEMPO-oxidized cellulose nanocrystals (TOCNS) were cross-linked with chitosan (CS), and combined with freeze-drying technology to construct a lightweight, recyclable adsorbent material. Density functional theory (DFT) calculations revealed the synergistic adsorption pathways of carboxyl (-COOH) and amino (-NH₂) groups, enabling ultra-high selectivity in the capture of flavonoid compounds.

View Article and Find Full Text PDF

In pursuit of lightweight, functional thermoplastic materials, novel monolithic aerogels composed entirely of poly(methyl methacrylate) (PMMA) and its stereocomplex crystals are reported. Herein, PMMA aerogels are fabricated using a one-pot thermoreversible gelation procedure, coupled with supercritical CO (scCO) drying. These aerogels exhibit either mixed macro- and mesoporous, or exclusively mesoporous character, with low densities (0.

View Article and Find Full Text PDF