Phosphorus as a Lewis acid: CO2 sequestration with amidophosphoranes.

Angew Chem Int Ed Engl

Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, M5S 3H6 Canada.

Published: May 2012


Category Ranking

98%

Total Visits

921

Avg Visit Duration

2 minutes

Citations

20

Article Abstract

Download full-text PDF

Source
http://dx.doi.org/10.1002/anie.201201422DOI Listing

Publication Analysis

Top Keywords

phosphorus lewis
4
lewis acid
4
acid co2
4
co2 sequestration
4
sequestration amidophosphoranes
4
phosphorus
1
acid
1
co2
1
sequestration
1
amidophosphoranes
1

Similar Publications

Reference Values for Minerals in Human Milk: the Mothers, Infants and Lactation Quality (MILQ) Study.

Adv Nutr

August 2025

Obesity and Metabolism Research, USDA, ARS Western Human Nutrition Research Center, Davis, California, United States; Institute for Global Nutrition, Department of Nutrition, University of California, Davis, California, United States. Electronic address:

This fifth article in the series presenting reference values for nutrients in human milk describes minerals. The Mothers, Infants and Lactation Quality (MILQ) and Early-MILQ studies collected human milk samples throughout the first 8.5 mo of lactation in 1242 well-nourished women in Bangladesh, Brazil, Denmark, and The Gambia.

View Article and Find Full Text PDF

Lipid accumulation in nitrogen and phosphorus-limited yeast is caused by less growth-related dilution.

Metab Eng

August 2025

Department of Chemistry, Princeton University, Princeton, NJ 08544, United States; Lewis Sigler Institute for Integrative Genomics, Princeton University, Princeton, NJ 08544, United States; Ludwig Institute for Cancer Research, Princeton Branch, Princeton, NJ 08544, United States; DOE Center for Adv

Oleaginous yeasts are used commercially to produce oleochemicals and hold potential also for biodiesel production. In response to nitrogen or phosphorous limitation, oleaginous yeasts accumulate lipids in the form of triacylglycerols. Previous work has investigated potential mechanisms by which nutrient limitation induces lipid biosynthesis without verifying whether lipid biosynthesis flux is actually enhanced.

View Article and Find Full Text PDF

Using density functional theory (M06-2X-D3/def2-TZVP), we investigated the 1,2-addition reactions of NH with a series of heavy imine analogues, (where G13 denotes a Group 13 element; Rea = reactant), featuring a mixed G13-P-Ga backbone. Theoretical analyses revealed that the bonding nature of the G13=P moiety in molecules varies with the identity of the Group 13 center. For G13=B, Al, Ga, and In, the bonding is best described as a donor-acceptor (singlet-singlet) interaction, whereas for G13=Tl, it is characterized by an electron-sharing (triplet-triplet) interaction.

View Article and Find Full Text PDF

Coral reef-inspired hierarchical channel electrolyte: LATP framework-ZrO₂ triggering activation of amorphous fast-ion channels in PVDF-HFP.

J Colloid Interface Sci

December 2025

Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials, School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China; Academy of Green Manufacturing Engineering, Wuhan University of Science and Technology, Wuhan 430081, China. E

To cope with the demand for high-safe lithium-ion batteries, this study developed a new PVDF-HFP/LiTFSI/LATP/ZrO₂ (PHLZ) composite solid electrolyte with coral reef-type hierarchical channel structure. This electrolyte integrates the advantages of the NASICON fast ion conductor Li₁.₃Al₀.

View Article and Find Full Text PDF

Aim: Distinguish the relative importance of intramuscular acidosis (hydrogen ion) and inorganic phosphate in skeletal muscle fatigue in vivo in rats.

Methods: We used direct sciatic nerve electrical stimulations to evoke twitches at different frequencies of contraction (0.25-, 0.

View Article and Find Full Text PDF