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The European Water Framework Directive (WFD) aims at achieving a good ecological and chemical status of surface waters in river basins by 2015. The chemical status is considered good if the Environmental Quality Standards (EQSs) are met for all substances listed on the priority list and eight additional specific emerging substances. To check compliance with these standards, the WFD requires the establishment of monitoring programmes. The minimum measuring frequency for priority substances is currently set at once per month. This can result in non-representative sampling and increased probability of misinterpretation of the surface water quality status. To assist in the classification of the water body, the combined use of monitoring data and pollutant fate models is recommended. More specifically, dynamic models are suggested, as possible exceedance of the quality standards can be predicted by such models. In the presented work, four realistic scenarios are designed and discussed to illustrate the usefulness of dynamic pollutant fate models for implementing the WFD. They comprise a combination of two priority substances and two rivers, representative for Western Europe.
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http://dx.doi.org/10.1016/j.chemosphere.2009.02.046 | DOI Listing |
Sci Total Environ
September 2025
University Hohenheim, Department of Process Analytics and Cereal Science, Stuttgart, 70599, Germany.
Per- and polyfluoroalkyl substances (PFAS) are persistent organic pollutants with increasing prevalence in agricultural soils, primarily introduced through biosolid application, wastewater irrigation, and atmospheric deposition. This review provides a meta-analysis of terminologies across 145 peer-reviewed studies, identifying inconsistency in the classification of PFAS subgroups-such as "long-chain vs. short-chain," "precursors," and "emerging PFAS"-which hinders regulatory harmonization and model calibration.
View Article and Find Full Text PDFEnviron Int
August 2025
Eawag: Swiss Federal Institute of Aquatic Science and Technology, Ueberlandstrasse 133, 8600, Duebendorf, Switzerland; Institute of Biogeochemistry and Pollutant Dynamics, Universitaetstrasse 16, 8092, Zurich, Switzerland. Electronic address:
Synthetic antioxidants (SAOs) are widely used additives in industrial and consumer products, yet their human exposure and fate throughout wastewater treatment remain poorly understood. This study investigates the occurrence of SAOs and their human metabolites in wastewater influent as well as their abatement in three wastewater treatment plants (WWTPs) employing both conventional and advanced treatment technologies. In vitro human liver S9 assays were performed to generate a SAO metabolite MS2 library containing over 2500 potential metabolites, which was matched against wastewater influent data.
View Article and Find Full Text PDFJ Hazard Mater
September 2025
Department of Civil & Environmental Engineering, National University of Singapore, E1A-07-03, 1 Engineering Drive 2, Singapore 117576, Singapore; NUS Environmental Research Institute, National University of Singapore, 1 Create way, Create Tower, #15-02, Singapore 138602, Singapore.
Antibiotic resistance (AR), driven by antibiotics as emerging pollutants, has become a critical global health threat, jeopardizing both environmental and human health. The persistence and spread of AR in aquatic ecosystems are governed by the intricate interplay between antibiotics, antibiotic resistance genes (ARGs), and antibiotic-resistant bacteria (ARB), which collectively influences its occurrence, transportation, and fate in aquatic ecosystems. However, most assessments focus primarily on antibiotics and ARGs, often relying on single-factor criteria while overlooking critical influence factors such as ARG forms, non-antibiotic chemicals, antibiotic pressure, and microbial competition.
View Article and Find Full Text PDFJ Hazard Mater
September 2025
School of Environmental Science and Engineering, Southwest Jiaotong University, Chengdu, Sichuan 611756, China; Sichuan Engineering Research Center for Pollution Control in Rail Transit Engineering, Chengdu, Sichuan 611756, China; Sichuan International Science and Technology Cooperation base for Int
In alpine meadow regions, macropore flow is a critical but inadequately understood pathway for antibiotic transport. The complex relationship between macropore structure, flow dynamics, and solute properties presents a significant research gap. Methodological limitations hinder the accurate characterization of solute migration mechanisms due to complex macropore structures.
View Article and Find Full Text PDFWater Res
September 2025
State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, PR China. Electronic address:
Freezing enhancing the photochemistry of dissolved organic matter (DOM), yet the mechanism of reactive intermediate (RIs) generation influenced by DOM property and structure remain elusive. Here, we demonstrate that freezing induces exceptional amplification of RIs, with steady-state concentrations in ice (-10 °C) surpassing aqueous solutions by 5-41 times. Laser scanning confocal microscopy first visualized cryo-concentration of DOM and RIs in liquid-like regions (LLR).
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