Publications by authors named "Zhiliang Han"

Hydrogel based electrodes have been applied in the field of bioelectronics, which is of great significance for constructing a robust human-computer interface. However, achieving both reliable conductivity and tissue matching mechanical properties remains challenging. Here, we report a synergistic strategy for constructing a hydrogel electrode for bioelectronic interface with tissue modulus and high conductivity by bacterial cellulose (BC) template induced growth polypyrrole (PPy) electrical percolation network combining a polymethacryloyloxyethyl trimethyl ammonium chloride (PDMC) hydrophilic network.

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Osmotic energy conversion based on bio-inspired layered membranes has garnered significant interest. However, traditional biomass ion-selective membranes suffer from complex preparation, uneconomic nature, poor selectivity, and low power density. Here, we introduce scalable one-step in situ culture for nanofluidic membrane materials (GO/C-BC) composed of graphene oxide (GO), carboxymethyl cellulose sodium salt (CMC), and bacterial cellulose (BC).

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Utilizing the thermogalvanic effect, flexible thermoelectric materials present a compelling avenue for converting heat into electricity, especially in the context of wearable electronics. However, prolonged usage is hampered by the limitation imposed on the thermoelectric device's operational time due to the evaporation of moisture. Deep eutectic solvents (DESs) offer a promising solution for low-moisture gel fabrication.

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Bacterial cellulose (BC) hydrogels are promising medical biomaterials that have been widely used for tissue repair, wound healing and cartilage engineering. However, the high water content of BC hydrogels increases the difficulty of storage and transportation. Moreover, they will lose their original hydrogel structure after dehydration, which severely limits their practical applications.

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Article Synopsis
  • - Fiber crossbars are an emerging technology in smart textiles, with increasing demand for sensitive sensors in wearable electronics.
  • - A new strategy enhances the sensitivity of these sensors by over 20 times without relying on complicated microstructures, combining air capacitance and equipotential bodies.
  • - The robust design of core-sheath fibers ensures low hysteresis (2.33%) and excellent stability, making these sensors capable of capturing weak signals like pulses, which can be used for personalized health monitoring systems.
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Article Synopsis
  • The emergence of the Omicron BF.7 variant has raised concerns about a new wave of COVID-19, particularly in Hohhot, Inner Mongolia, highlighting the need for risk assessment of patients needing management.
  • The study analyzed individual data like age, sex, symptoms, and vaccination status of COVID-19 patients to evaluate the severity of the disease among those infected with BF.7.
  • Findings showed that patients with severe symptoms had significantly different clinical indicators compared to mild cases, emphasizing the importance of monitoring these indicators for better patient management.
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Interface solar water evaporation is a mean of rapidly evaporating water using solar energy. However, it is still a challenge to obtain solar evaporators with simple assembly, durability and high photothermal performance. Here, we demonstrated an effective post foaming strategy for treating nitrogen-doped reduced graphene oxide/bacterial cellulose film (F-NRGO@BC) prepared by a simple in situ culture method.

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  • Soft capacitive pressure sensors are in high demand for flexible wearable technology, but traditional fiber sensors are limited to low-pressure sensitivity and require preloading.
  • The study introduces hybrid response fiber pressure sensors (HFPSs) with a three-layer design, improving sensitivity through model analysis and experiments, addressing the limits of traditional sensors.
  • HFPSs show impressive features like quick response, low hysteresis, and durability, allowing them to monitor pulse signals effectively across a broad preload range of 0 to 22.7 kPa, which enhances their practical applications.
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Skin wounds need an appropriate wound dressing to help prevent bacterial infection and accelerate wound closure. Bacterial cellulose (BC) with a three-dimensional (3D) network structure is an important commercial dressing. However, how to effectively load antibacterial agents and balance the antibacterial activity is a lingering issue.

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Conductive polyzwitterionic hydrogels with good adhesion properties show potential prospect in implantable electrodes and electronic devices. Adhesive property of polyzwitterionic hydrogels in humid environments can be improved by the introduction of catechol groups. However, common catechol modifiers can usually quench free radicals, resulting in a contradiction between long-term tissue adhesion and hydrogel toughness.

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Biocompatible hydrogels with versatile functions are highly desired for demanding the complicated tissue issues, including irregular site and motional wound. Herein, a bio-based hydrogel with multifunctional properties is designed based on quaternized chitosan and dialdehyde bacterial cellulose. As a functional wound dressing, the hydrogel shows rapid self-healing performance and injectable behaviors due to dynamic Schiff-base interactions and presents superior antibacterial activity against E.

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With the booming development of flexible wearable sensing devices, flexible stretchable strain sensors with crack structure and high sensitivity have been widely concerned. However, the narrow sensing range has been hindering the development of crack-based strain sensors. In addition, the existence of the crack structure may reduce the interface compatibility between the elastic matrix and the sensing material.

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Liquid sensors for detecting water and body fluids are crucial in daily water usage and health monitoring, but it is challenging to combine sensing performance with high tensile deformation and multifunctional applications. Here, a substrate-free, self-stretchable bacterial cellulose (BC)/carbon nanotube (CNT) helical fiber liquid sensor was prepared by the solution spinning and coiling process using BC as the water-sensitive matrix and CNTs as the active sensing materials. The BC/CNT (BCT) fiber sensor has a high stretch ratio of more than 1000% and a rapid response for a current change rate of 10% within 1 s, which is almost unaffected under washing and various stretching or knotting deformations.

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At present, the orderly assembly of bio-cellulose nanofibers (CNFs) with excellent mechanical properties in a simple and continuous manner still remains a challenge. Here, we propose a strategy of combining a wet spinning process with a self-made grading-stretching device to realize the continuous preparation of high-performance bacterial cellulose (BC) macrofibers. The macrofiber obtained by one-stage stretching at the optimum stretching ratio of 40% achieves the Young's modulus of 19.

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By using the low loading of the conductor filler to achieve high conductivity is a challenge associated with electrically conductive adhesion. In this study, we show an assembling of nickel-coated polystyrene (Ni@PS) microspheres into 3-dimensional network within the epoxy resin with the assistance of an electric field. The morphology evolution of the microspheres was observed with optical microscopy and scanning electron microscopy (SEM).

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Gas-responsive nanochannels have great relevance for applications in many fields. Inspired by CO-sensitive ion channels, herein we present an approach for designing solid-state nanochannels that allow controlled regulation of ion transport in response to alternate CO/N stimuli. The pillar[5]arene () bearing diethylamine groups can convert into the water-soluble host , containing cationic tertiary ammonium salt groups after absorbing CO.

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