Liquid Repellence of Phobic Fiber Networks.

The wetting behavior of fiber networks, which are central to many research and industrial applications, can be difficult to predict accurately owing to their complex, heterogeneous structure. The cylindrical pore model, widely used to interpret and predict the forced wetting of hydrophobic porous materials, often does not yield correct results when working with fibrous networks like paper substrates and non-woven fabrics. This is because these materials exhibit variation in pore size, fiber length, and fiber diameter, as well as a reentrant pore geometry.

Programming Semiconductor Nanowire Composition with Sub-100 nm Resolution via the Geode Process.

We demonstrate the vapor-liquid-solid growth of single-crystalline i-Si, i-Si/n-Si, and SiGe/SiGe nanowires via the Geode process. By enabling nanowire growth on the large internal surface area of a microcapsule powder, the Geode process improves the scalability of semiconductor nanowire manufacturing while maintaining nanoscale programmability. Here, we show that heat and mass transport limitations introduced by the microcapsule wall are negligible, enabling the same degree of compositional control for nanowires grown inside microcapsules and on conventional flat substrates.

Thickened Liquids Using Pureed Foods for Children with Dysphagia: IDDSI and Rheology Measurements.

Children with dysphagia, or swallowing disorder, are at an increased risk for developing respiratory compromise, failure to thrive, and aversion. Thickened liquids can be recommended for children with dysphagia, if shown to be effective on instrumental examination and if strategies/interventions with thin liquids are not successful. Thickened liquids have many benefits, including creating a more cohesive bolus, slowing oropharyngeal transit time, and reducing aspiration.

Rheology finds distinct glass and jamming transitions in emulsions.

We study the rheology of monodisperse and bidisperse emulsions with various droplet sizes (1-2 μm diameter). Above a critical volume fraction φc, these systems exhibit solid-like behavior and a yield stress can be detected. Previous experiments suggest that for small thermal particles, rheology will see a glass transition at φc = φg ≈ 0.

Synergistic Reinforcement of Composite Hydrogels with Nanofiber Mixtures of Cellulose Nanocrystals and Chitin Nanofibers.

Simultaneous incorporation of cellulose nanocrystals (CNCs) and chitin nanofibers (ChNFs) into a polyvinyl alcohol (PVA) matrix opens possibilities for customization of more environmentally friendly composite materials. When used in tricomponent composite hydrogels, the opposite surface charges on CNCs and ChNFs lead to the construction of beneficial nanofiber structures. In this work, composite hydrogels containing CNCs, ChNFs, or their mixtures are produced using cyclic freeze-thaw (FT) treatments.

Humidity-tolerant rate-dependent capillary viscous adhesion of bee-collected pollen fluids.

We report a two-phase adhesive fluid recovered from pollen, which displays remarkable rate tunability and humidity stabilization at microscopic and macroscopic scales. These natural materials provide a previously-unknown model for bioinspired humidity-stable and dynamically-tunable adhesive materials. In particular, two immiscible liquid phases are identified in bioadhesive fluid extracted from dandelion pollen taken from honey bees: a sugary adhesive aqueous phase similar to bee nectar and an oily phase consistent with plant pollenkitt.

Solution-Based 3D Printing of Polymers of Intrinsic Microporosity.

Current additive manufacturing methods have significant limitations in the classes of compatible polymers. Many polymers of significant technological interest cannot currently be 3D printed. Here, a generalizable method for 3D printing of viscous tenary polymer solutions (polymer/solvent/nonsolvent) is applied to both "intrinsically porous" (a polymer of intrinsic microporosity, PIM-1) and "intrinsically nonporous" (cellulose acetate) polymers.

Underwater Curvature-Driven Transport between Oil Droplets on Patterned Substrates.

Roughness contrast patterns were generated on copper surfaces by a simple one-step site-selective oxidation process using a felt-tipped ink pen masking method. The patterned surface exhibited strong underwater oil wettability contrast which allows oil droplet confinement. Oil droplets placed on two patterned smooth dots (reservoirs) connected by a patterned smooth channel will spontaneously exchange liquid as a result of Laplace pressure differences until their shapes have reached equilibrium.

Sustainable and long-time 'rejuvenation' of biomimetic water-repellent silica coating on polyester fabrics induced by rough mechanical abrasion.

The economical use of water-repellent coatings on polymeric materials in commercial and industrial applications is limited by their mechanical wear robustness and long-term durability. In this study, we demonstrate that polyethylene terephthalate (PET) fabric modified with inorganic, methyltrimethoxysilane (MTMS)-based coatings shows excellent resistance against various types of wear damage, thereby mimicking superhydrophobic biological materials. These features were facilitated by the rational design of coating processing that also enabled tunable hierarchical surface structure.

Inhibition of Bacterial Adhesion on Nanotextured Stainless Steel 316L by Electrochemical Etching.

Bacterial adhesion to stainless steel 316L (SS316L), which is an alloy typically used in many medical devices and food processing equipment, can cause serious infections along with substantial healthcare costs. This work demonstrates that nanotextured SS316L surfaces produced by electrochemical etching effectively inhibit bacterial adhesion of both Gram-negative and Gram-positive , but exhibit cytocompatibility and no toxicity toward mammalian cells in vitro. Additionally, the electrochemical surface modification on SS316L results in formation of superior passive layer at the surface, improving corrosion resistance.

Underwater Oil Droplet Splitting on a Patterned Template.

Underwater oil droplets stretched and pinned by dual-dot oleophilic patterns on a superoleophobic substrate have been split into two nearly equal-volume daughter droplets using an underwater superoleophobic blade at substantially lower cutting speeds than reported in previous studies. A "liquid exchange model" based on Laplace pressure-driven liquid transport has been proposed to explain the mechanism of the underwater droplet split process. The dependence of droplet geometrical shape (curvature) and liquid properties (surface tension, viscosity) on the critical cutting speed that allows equal-volume split was investigated.

Process Principles for Large-Scale Nanomanufacturing.

Nanomanufacturing-the fabrication of macroscopic products from well-defined nanoscale building blocks-in a truly scalable and versatile manner is still far from our current reality. Here, we describe the barriers to large-scale nanomanufacturing and identify routes to overcome them. We argue for nanomanufacturing systems consisting of an iterative sequence of synthesis/assembly and separation/sorting unit operations, analogous to those used in chemicals manufacturing.

Two-Step Process To Create "Roll-Off" Superamphiphobic Paper Surfaces.

Surface modification of cellulose-based paper, which displays roll-off properties for water and oils (surface tension ≥23.8 mN·m) and good repellency toward n-heptane (20.1 mN·m), is reported.

Postprandial lymphatic pump function after a high-fat meal: a characterization of contractility, flow, and viscosity.

Dietary lipids are transported from the intestine through contractile lymphatics. Chronic lipid loads can adversely affect lymphatic function. However, the acute lymphatic pump response in the mesentery to a postprandial lipid meal has gone unexplored.

Design and fabrication of superamphiphobic paper surfaces.

Cellulose-based paper remains a vital component of modern day society; however, its use is severely limited in certain applications because of hydrophilic and oleophilic properties. In this manuscript we present a novel method to create superamphiphobic paper by combining the control of fiber size and structure with plasma etching and fluoropolymer deposition. The heterogeneous nature of the paper structure is drastically different from that of artificially created superamphiphobic surfaces.

Creation of superhydrophobic stainless steel surfaces by acid treatments and hydrophobic film deposition.

In this work, we present a method to render stainless steel surfaces superhydrophobic while maintaining their corrosion resistance. Creation of surface roughness on 304 and 316 grade stainless steels was performed using a hydrofluoric acid bath. New insight into the etch process is developed through a detailed analysis of the chemical and physical changes that occur on the stainless steel surfaces.

Control of microfluidic flow in amphiphilic fabrics.

Woven textile fabrics were designed and constructed from hydrophilic and hydrophobic spun yarns to give planar substrates containing amphiphilic microchannels with defined orientations and locations. Polypropylene fibers were spun to give hydrophobic yarns, and the hydrophilic yarns were spun from a poly(ethylene terephthalate) copolyester. Water wicking rates into the fabrics were measured by video microscopy from single drops, relevant for point-of-care microfluidic diagnostic devices, and from reservoirs.

Microscopic structural relaxation in a sheared supercooled colloidal liquid.

The rheology of dense amorphous materials under large shear strain is not fully understood, partly due to the difficulty of directly viewing the microscopic details of such materials. We use a colloidal suspension to simulate amorphous materials and study the shear-induced structural relaxation with fast confocal microscopy. We quantify the plastic rearrangements of the particles in several ways.

Patterning of superhydrophobic paper to control the mobility of micro-liter drops for two-dimensional lab-on-paper applications.

Superhydrophobic paper substrates were patterned with high surface energy black ink using commercially available desktop printing technology. The shape and size of the ink islands were designed to control the adhesion forces on water drops in two directions, parallel ('drag-adhesion') and perpendicular ('extensional-adhesion') to the substrate. Experimental data on the adhesion forces shows good agreement with classical models for 'drag' (Furmidge equation) and 'extensional' adhesion (modified Dupré equation).

Physical aging and phase behavior of multiresponsive microgel colloidal dispersions.

Quantitative microscopy measurements have been made on poly(N-isopropylacrylamide-co-acrylic acid) (pNIPAm-AAc) microgel dispersions as a function of time, temperature, pH, and volume fraction. These studies reveal an extreme degree of complexity in the physical aging and phase behavior of the dispersions; this complexity arises from a convolution of the system energetics at the colloidal, polymer-chain, and molecular scales. Superficially, these dispersions display the classic colloidal phases observed for spherical particles (i.

Three-dimensional in situ temperature measurement in microsystems using Brownian motion of nanoparticles.

We report an in situ method for three-dimensionally resolved temperature measurement in microsystems. The temperature of the surrounding fluid is correlated from Brownian diffusion of suspended nanoparticles. We use video-microscopy in combination with image analysis software to selectively track nanoparticles in the focal plane.

Fabrication of "roll-off" and "sticky" superhydrophobic cellulose surfaces via plasma processing.

Most of the artificial superhydrophobic surfaces that have been fabricated to date are not biodegradable, renewable, or mechanically flexible and are often expensive, which limits their potential applications. In contrast, cellulose, a biodegradable, renewable, flexible, inexpensive, biopolymer which is abundantly present in nature, satisfies all the above requirements, but it is not superhydrophobic. Superhydrophobicity on cellulose paper was obtained by domain-selective etching of amorphous portions of the cellulose in an oxygen plasma and subsequently coating the etched surface with a thin fluorocarbon film deposited via plasma-enhanced chemical vapor deposition using pentafluoroethane as a precursor.

Phase behavior in highly concentrated assemblies of microgels with soft repulsive interaction potentials.

Microgel particles with a soft repulsive interaction potential are investigated with particle tracking methods to study the phase behavior of soft-sphere systems. The use of poly(N-isopropylacrylamide) particles allows the effective volume fraction of a sample to be tuned via thermal modulation without altering the particle number density. This allows for investigation of the phase behavior of an assembly as a function of its initial packing density.

Crystallization behavior of soft, attractive microgels.

The equilibrium phase behavior and the dynamics of colloidal assemblies composed of soft, spherical, colloidal particles with attractive pair potentials have been studied by digital video microscopy. The particles were synthesized by precipitation copolymerization of N-isopropylacrylamide (NIPAm), acrylic acid (AAc), and N,N'-methylene bis(acrylamide) (BIS), yielding highly water swollen hydrogel microparticles (microgels) with temperature- and pH-tunable swelling properties. It is observed that in a pH = 3.

Rational design of a reversible pH-responsive switch for peptide self-assembly.

Peptide TZ1H, based on the heptad sequence of a coiled-coil trimer, undergoes fully reversible, pH-dependent self-assembly into long-aspect-ratio helical fibers. Substitution of isoleucine residues with histidine at the core d-positions of alternate heptads introduces a mechanism by which self-assembly is coupled to the protonation state of the imidazole side chain. Circular dichroism spectroscopy, transmission electron microscopy, and microrheology techniques revealed that the self-assembly of TZ1H coincides with a distinct coil-helix conformational transition that occurs within a narrow pH range near the pKa of the imidazole side chains of the core histidine residues.