Formation of Iron-Helium Compounds under High Pressure.

We report the formation of fcc and distorted hcp iron-helium compounds with x in FeHe_{x} up to 0.13 and 0.48, respectively, based on experiments at 5-54 GPa and ∼1000-2820  K.

Core origin of seismic velocity anomalies at Earth's core-mantle boundary.

Seismic studies have found fine-scale anomalies at the core-mantle boundary (CMB), such as ultralow velocity zones (ULVZs) and the core rigidity zone. ULVZs have been attributed to mantle-related processes, but little is known about a possible core origin. The precipitation of light elements in the outer core has been proposed to explain the core rigidity zone, but it remains unclear what processes can lead to such precipitation.

Iron-rich Fe-O compounds at Earth's core pressures.

Oxygen and iron are the most abundant elements on Earth, and their compounds are key planet-forming components. While oxygen is pervasive in the mantle, its presence in the solid inner core is still debatable. Yet, this issue is critical to understanding the co-evolution and the geomagnetic field generation.

Strain-Modulated Interlayer Charge and Energy Transfers in MoS/WS Heterobilayer.

Excitonic properties in 2D heterobilayers are closely governed by charge transfer (CT) and excitonic energy transfer (ET) at van der Waals interfaces. Various means have been employed to modulate the interlayer CT and ET, including electrical gating and modifying interlayer spacing, but with limited extent in their controllability. Here, we report a novel method to modulate these transfers in the MoS/WS heterobilayer by applying compressive strain under hydrostatic pressure.

Tungsten Hexanitride with Single-Bonded Armchairlike Hexazine Structure at High Pressure.

WN_{6} phase discovered at 126-165 GPa after heating of W in nitrogen. XRD refinements reveal a unit cell in space group R3[over ¯]m which is consistent with the WN_{6} structure with armchairlike hexazine (N_{6}) rings, while strong A_{1g} Raman mode confirms its N─N single bonds. Density functional theory (DFT) calculations reveal balanced contributions of attractive interactions between W and covalent N_{6} rings, and repulsions between N_{6} rings that make WN_{6} ultrastiff and tough.

Elasticity of a Pseudoproper Ferroelastic Transition from Stishovite to Post-Stishovite at High Pressure.

Elastic moduli (C_{ij}) of single-crystal stishovite and post-stishovite are determined using Brillouin light scattering, impulsive stimulated light scattering, and x-ray diffraction up to 70 GPa. The C_{12} of stishovite converges with the C_{11} at ∼55  GPa, where the transverse wave V_{S1} propagating along [110] also vanishes. Landau modeling of the C_{ij}, B_{1g} optic mode, and lattice parameters reveals a pseudoproper type ferroelastic post-stishovite transition.

Thermal Conductivity Enhancement in MoS_{2} under Extreme Strain.

Because of their weak interlayer bonding, van der Waals (vdW) solids are very sensitive to external stimuli such as strain. Experimental studies of strain tuning of thermal properties in vdW solids have not yet been reported. Under ∼9% cross-plane compressive strain created by hydrostatic pressure in a diamond anvil cell, we observed an increase of cross-plane thermal conductivity in bulk MoS_{2} from 3.

Abnormal Elasticity of Single-Crystal Magnesiosiderite across the Spin Transition in Earth's Lower Mantle.

Brillouin light scattering and impulsive stimulated light scattering have been used to determine the full elastic constants of magnesiosiderite [(Mg_{0.35}Fe_{0.65})CO_{3}] up to 70 GPa at room temperature in a diamond-anvil cell.