Microwave Heating of Superparamagnetic Iron-Oxide Nanoparticles Toward Environmental Hyperthermia-Based Applications.

This article reports the effect of spherical particle size (4-30 nm) on magnetic properties and microwave (MW) reactivity of superparamagnetic iron oxide nanoparticles (SPIONs) toward environmental hyperthermia-based applications. For this, silica-coated, single domain iron oxide nanoparticles (IONPs@silica) were precisely synthesized via thermal decomposition and subsequently coated by a reverse microemulsion. Transmission electron microscopy and X-ray diffraction confirmed the formation of spherical, monodisperse, single continuous layer silica-coated magnetite nanoparticles.

Analyzing the Release of Per- and Polyfluoroalkyl Substances from Spent Granular Activated Carbons by Standard Leaching Procedures.

The recent national primary drinking water regulation for per- and polyfluoroalkyl substances (PFAS) is expected to drive a nationwide increase in granular activated carbon (GAC) usage in water treatment facilities across the United States. Proper management of PFAS-laden GAC waste streams is essential to prevent potential recontamination. This study systematically evaluates PFOA and PFOS leaching from four commercial GACs using three standard batch leaching procedures.

Interplay of surface oxygen content and pore water during thermal regeneration of granular activated carbons.

This study aims at unraveling the interplay between thermal regeneration and granular activated carbon (GAC) properties. First, twelve commercially available, unused, and thoroughly characterized GACs were pyrolyzed without per- and polyfluoroalkyl substances (PFAS) using a thermogravimetric analyzer at a 25 ºC/min heating rate up to 750 ºC under nitrogen. GACs with elevated oxygen content showed substantial weight loss due to the decomposition of acidic functional groups, leading to the formation of larger pores but a decrease in specific surface area and physical hardness.

Disruption of the Conjugated π-Electron System of Graphene Oxides Diminishes Their Microwave Reactivity.

Graphenes and graphene-based adsorbents have the potential to be thermally regenerated by microwave irradiation due to their electronic mobility and propensity to absorb microwaves. This article investigates the effect of oxidation on their ability to heat during microwave irradiation in conjunction with their ability to adsorb a polycyclic aromatic hydrocarbon. For this, a series of graphene oxides (GOs) were synthesized, and their chemical properties and surface structures were analyzed systematically.

Permeation of per- and polyfluoroalkyl substances (PFAS)-laden leachate in landfills as an outcome of puncture failures of high-density polyethylene geomembranes.

In response to growing environmental concerns regarding the presence of per- and polyfluoroalkyl substances (PFAS) in landfills, this study explores PFAS permeation through pinhole defects of high-density polyethylene (HDPE) geomembranes (GMs) experimentally. Specifically, this study aims to: (i) investigate the adsorption of PFAS onto HDPE GMs, (ii) evaluate the effectiveness of GMs experimentally in retaining PFAS-laden leachate in the event of a puncture failure, (iii) assess the critical conditions leading to puncture failure of GM using mechanical characterization testing with complementary finite element method (FEM) analyses with the input data from mechanical characterization. Our findings show limited intermolecular attractive interactions between PFAS and GMs, and surfactant properties of PFAS contribute to higher leachate permeation through pinholes.

Nanobubble applications in aquaculture industry for improving harvest yield, wastewater treatment, and disease control.

The ever-growing demand for aquaculture has led the industry to seek novel approaches for more sustainable practices. These attempts aim to increase aquaculture yield by increasing energy efficiency and decreasing footprint and chemical demand without compromising animal health. For this, emerging nanobubbles (NBs) aeration technology gained attention.

Unlocking the Potential of Nanobubbles: Achieving Exceptional Gas Efficiency in Electrogeneration of Hydrogen Peroxide.

The electrogeneration of hydrogen peroxide (H O ) via the oxygen reduction reaction is a crucial process for advanced water treatment technologies. While significant effort is being devoted to developing highly reactive materials, gas provision systems used in these processes are receiving less attention. Here, using oxygen nanobubbles to improve the gas efficiency of the electrogeneration of H O is proposed.

Management of per- and polyfluoroalkyl substances (PFAS)-laden wastewater sludge in Maine: Perspectives on a wicked problem.

This article discusses the challenges and potential solutions for managing wastewater sludge that contains per- and polyfluoroalkyl substances (PFAS), using the experience in Maine as a guide toward addressing the issue nationally. Traditional wastewater treatment, designed to remove excess organic waste and nutrients, does not eliminate persistent toxic pollutants like PFAS, instead partitioning the chemicals between discharged effluent and the remaining solids in sludge. PFAS chemistry, the molecular size, the alkyl chain length, fluorine saturation, the charge of the head group, and the composition of the surrounding matrix influence PFAS partitioning between soil and water.

Increasing bromide removal by graphene-silver nanocomposites: Nanoparticulate silver enhances bromide selectivity through direct surface interactions.

Bromide forms toxic brominated disinfection by-products during disinfection. Current bromide removal technologies are often non-specific and costly due to naturally occurring competing anions. A silver-impregnated graphene oxide (GO) nanocomposite is reported here that reduced the amount of Ag needed for Br removal by increasing its selectivity towards Br.

Modified linear solvation energy relationships for adsorption of perfluorocarboxylic acids by polystyrene microplastics.

Microplastics (MPs) could act as vectors of organic pollutants such as per- and polyfluoroalkyl substances (PFAS). Therefore, understanding adsorptive interactions are essential steps towards unraveling the fate of PFAS in the natural waters where MPs are ubiquitous. Linear solvation energy relationships (LSER)-based predictive models are utilitarian tools to delineate the complexity of adsorption interactions.

Biodegradation of petroleum hydrocarbons in a weathered, unsaturated soil is inhibited by peroxide oxidants.

Field-weathered crude oil-containing soils have a residual concentration of hydrocarbons with complex chemical structure, low solubility, and high viscosity, often poorly amenable to microbial degradation. Hydrogen peroxide (HO)-based oxidation can generate oxygenated compounds that are smaller and/or more soluble and thus increase petroleum hydrocarbon biodegradability. In this study, we assessed the efficacy of HO-based oxidation under unsaturated soil conditions to promote biodegradation in a field-contaminated and weathered soil containing high concentrations of total petroleum hydrocarbons (25200 mg TPH kg) and total organic carbon (80900 mg TOC kg).

Effect of air nanobubbles on oxygen transfer, oxygen uptake, and diversity of aerobic microbial consortium in activated sludge reactors.

Nanobubbles have the potential to curtail the loss of oxygen during activated sludge aeration due to their extensive surface areas and lack of buoyance in solution. In this study, nanobubble aeration was explored as a novel approach to enhance aerobic activated sludge treatment and benchmarked against coarse bubble aeration at the lab scale. Nanobubble aerated activated sludge reactors achieved greater dissolved oxygen levels at faster rates.

Elucidating CO nanobubble interfacial reactivity and impacts on water chemistry.

Hypothesis: Carbon dioxide nanobubbles can increase effective gas-transfer to solution and enhance buffering capacity given the stable suspension in water of CO gas within nanobubbles and the existence of larger gas/water interface.

Experiments: The physico-chemical properties and responses of CO nanobubbles were recorded at different generation times (10, 30, 50, and 70 min) and benchmarked against traditional macrobubbles of CO for the same amount of delivered gas. Effective concentration of CO was evaluated by measuring the buffer capacity (β).

Effect of superfine pulverization of powdered activated carbon on adsorption of carbamazepine in natural source waters.

The purpose of this study is to investigate adsorptive removal of carbamazepine from natural source waters by superfine pulverized powdered activated carbon. Superfine pulverization is becoming an increasingly attractive approach to decrease the diffusion path of a target adsorbate molecule and improve the overall the kinetics of activated carbon adsorption. Here we report the impact of pulverization on powdered activated carbon characteristics, and carbamazepine adsorption behavior in distilled and deionized water and natural organic matter solutions.

Thermal Regeneration of Spent Granular Activated Carbon Presents an Opportunity to Break the Forever PFAS Cycle.

Extensive use of per- and polyfluoroalkyl substances (PFAS) has caused their ubiquitous presence in natural waters. One of the standard practices for PFAS removal from water is adsorption onto granular activated carbon (GAC); however, this approach generates a new waste stream, i.e.

Nano-scale applications in aquaculture: Opportunities for improved production and disease control.

Aquaculture is the fastest growing food-production sector and is vital to food security, habitat restoration and endangered species conservation. One of the continued challenges to the industry is our ability to manage aquatic disease agents that can rapidly decimate operations and are a constant threat to sustainability. Such threats also evolve as microbes acquire resistance and/or new pathogens emerge.

Photocatalytic activity of micron-scale brass on emerging pollutant degradation in water: mechanism elucidation and removal efficacy assessment.

Alloys or smelted metal mixtures have served as cornerstones of human civilization. The advent of smelted copper and tin, , bronze, in the 4 millennium B.C.

Microplastic particle versus fiber generation during photo-transformation in simulated seawater.

Microplastic particles and fibers are increasingly being detected in our surface and ground waters as well as within a wide range of aquatic species. Their presence in the environment is largely due to in situ generation from physical and chemical weathering of larger plastics, and thus has left environmental community concerned in the post-banned era of microbead use in personal care products through the passage of Microbead-Free Waters Act in the United States. To improve understanding of secondary microplastic formation, accelerated weathering has been conducted on four materials (high-density polyethylene, high impact polystyrene, nylon 6, and polypropylene) under ultraviolet radiation (equivalent to 44 days in full sun) in simulated seawater.

Adsorption kinetics of synthetic organic contaminants onto superfine powdered activated carbon.

Superfine powdered activated carbon (S-PAC) is an adsorbent material with the promise of properties that allow for rapid adsorption of small molecule contaminants. To explore the potential for rapid adsorption among varying activated carbon types, seven commercially available activated carbons were obtained and pulverized to produce S-PAC particles less than 1 μm in diameter. The carbons were chosen to include several types of common carbons produced from coal precursors as well as a wood-based carbon and a coconut shell-based carbon.

Transformation potential of cannabinoids during their passage through engineered water treatment systems: A perspective.

Cannabinoids are incipient contaminants with limited literature in the context of water treatment. With increasing positive public opinion toward legalization and their increasing use as a pharmaceutical, cannabinoids are expected to become a critical class of pollutant that requires attention in the water treatment industry. The destructive removal of cannabinoids via chlorination and other oxidation processes used in drinking water and wastewater treatment requires careful investigation, because the oxidation and disinfection byproducts (DBPs) may pose significant risks for public health and the environment.

Adsorption kinetics and aggregation for three classes of carbonaceous adsorbents in the presence of natural organic matter.

In this study, adsorption kinetics of phenanthrene (PNT) and trichloroethylene (TCE) by a graphene nanosheet (GNS), a graphene oxide nanosheet (GO), a single-walled carbon nanotube (SWCNT), a multi-walled carbon nanotube (MWCNT), and two coal based activated carbons (ACs) (F400 and HD3000) were examined in distilled and deionized water (DDW) and under natural organic matter (NOM) preloading conditions. The results showed the times needed for the adsorption of PNT and TCE to reach apparent equilibrium (i.e.

Nanobubble Technologies Offer Opportunities To Improve Water Treatment.

Since first hypothesizing the existence of nanobubbles (NBs) in 1994, the empirical study of NB properties and commercialization of NB generators have rapidly evolved. NBs are stable spherical packages of gas within liquid and are operationally defined as having diameters less than 1000 nm, though they are typically in the range of 100 nm in one dimension. While theories still lack the ability to explain empirical evidence for formation of stable NBs in water, numerous NB applications have emerged in different fields, including water and wastewater purification where NBs offer the potential to replace or improve efficiency of current treatment processes.

Predictive models for adsorption of organic compounds by Graphene nanosheets: comparison with carbon nanotubes.

The Linear Solvation Energy Relationships (LSER) technique was applied in the present study for predicting models of organic compounds (OCs) adsorption by Graphene and Graphene oxide (GO), and the results were compared with those of multi-walled carbon nanotube (MWCNT) and single-walled carbon nanotube (SWCNT). Adsorption database of 38 OCs (28 aromatic and 10 aliphatic) for Graphene and 69 OCs (59 aromatic and 10 aliphatic) for GO were collected from the literature and our laboratory. The r of the LSER models on the adsorption of aromatic OCs by Graphene and GO at three different equilibrium concentrations gradually increased up to OC molecular weight of 400 g/mol, after which a declining trend was observed for GO, while there was no visible change for Graphene.

Adsorption of organic contaminants by graphene nanosheets: A review.

Graphene nanosheets (GNS) such as graphenes and graphene oxides (GOs) have been widely investigated as next-generation adsorbents in both water and wastewater treatment processes due to their unique physicochemical properties and their affinity towards different classes of organic contaminants (OCs). In the last five years, more than 40 articles investigating adsorption of different classes of OCs by graphene and GO were published in peer-reviewed journals. Adsorption mechanisms were controlled by molecular properties of OCs (e.