Permeation of per- and polyfluoroalkyl substances (PFAS)-laden leachate in landfills as an outcome of puncture failures of high-density polyethylene geomembranes.

In response to growing environmental concerns regarding the presence of per- and polyfluoroalkyl substances (PFAS) in landfills, this study explores PFAS permeation through pinhole defects of high-density polyethylene (HDPE) geomembranes (GMs) experimentally. Specifically, this study aims to: (i) investigate the adsorption of PFAS onto HDPE GMs, (ii) evaluate the effectiveness of GMs experimentally in retaining PFAS-laden leachate in the event of a puncture failure, (iii) assess the critical conditions leading to puncture failure of GM using mechanical characterization testing with complementary finite element method (FEM) analyses with the input data from mechanical characterization. Our findings show limited intermolecular attractive interactions between PFAS and GMs, and surfactant properties of PFAS contribute to higher leachate permeation through pinholes. In general, highly fluorinated, short chain PFAS exhibit increased permeation rates, which was attributed to their size and greater propensity to align at the water-air interface. This study underlines the environmental implications of PFAS-laden leachates especially when there are no proper liner systems or leachate collection systems in place underscoring the necessity for modern landfill design and management practices to mitigate environmental risks associated with PFAS.