Dual-Functional One-Pot Synthesized Au-Y-TMA MOF Hybrid: an Electrode Modifier for High-Performance Symmetric Supercapacitor and Kanamycin Aptasensor for Spiked Milk Samples.

In this study, a one-pot hydrothermal synthesis method was used to synthesize a novel gold-yttrium trimesic acid metal-organic framework (Au-Y-TMA MOF), demonstrating significant improvements over conventional single-metal MOFs, that is, yttrium trimesic acid (Y-TMA), in both supercapacitor applications and electrochemical antibiotic detection. The X-ray diffraction patterns of Au-Y-TMA confirmed the presence and impact of Au in the Y-TMA matrix, while field emission scanning electron microscopy (FE-SEM) images revealed a heterogeneous combination of gold nanoparticles (AuNPs) and Y-TMA, suggesting a nonuniform distribution and possible interaction. The developed half-cell supercapacitor exhibited a remarkable capacitance value of 1836 F/g at a current density of 5 A/g by galvanostatic charging-discharging (GCD) measurement.

Effects of substrate temperature and precursor separation on the morphology of ReSnanoflakes prepared by chemical vapor deposition.

Rhenium disulfide (ReS) is a 2-dimensional transitional metal dichalcogenides that exhibits unique properties such as a direct band gap irrespective of thickness, weak interlayer coupling, and exceptional anisotropic properties, making it a promising material for optoelectronics applications. In this work, we synthesized ReSnanoflakes on SiO/Si substrates using chemical vapor deposition (CVD). The effects of Re precursor-substrate distance () and growth temperature on flakes morphology were systematically investigated.

A low-cost broadband photodetector based on CsPbBrquantum dots/transfer-free eco-friendly graphene heterostructures for fast photoresponse.

We have successfully demonstrated CsPbBrperovskite quantum dots (QDs)/transfer-free eco-friendly (TFEF) graphene heterostructures with broadband and fast photoresponse. At first, the TFEF graphene is grown directly on the SiO/Si substrates in an atmospheric pressure chemical vapor deposition (APCVD) system with the copper-foil wrapping methods and camphor precursors. Raman mapping image (15 × 15m) showed TFEF graphene with high coverage across the surface (∼65% single-layer graphene, ∼15% bilayer graphene, and ∼20% multilayer graphene).

Fast, Highly Stable, and Low-Bandgap 2D Halide Perovskite Photodetectors Based on Short-Chained Fluorinated Piperidinium as a Spacer.

Ruddlesden-Popper (RP) two-dimensional (2D) halide perovskite (HP), with attractive structural and optoelectronic properties, has shown great potential in optoelectrical devices. However, the relatively wide bandgap () and stability, which cause inferior efficiency, prevent its feasibility from further applications. To tackle these issues, for the first time, a novel fluorine-containing piperidinium spacer, (3-HCFCFCHOCH-PPH), abbreviated as (4FH-PPH), has been designed for the stable and efficient = 1 2D HPs.

Growth of Wafer-Scale Single-Crystal 2D Semiconducting Transition Metal Dichalcogenide Monolayers.

Due to extraordinary electronic and optoelectronic properties, large-scale single-crystal two-dimensional (2D) semiconducting transition metal dichalcogenide (TMD) monolayers have gained significant interest in the development of profit-making cutting-edge nano and atomic-scale devices. To explore the remarkable properties of single-crystal 2D monolayers, many strategies are proposed to achieve ultra-thin functional devices. Despite substantial attempts, the controllable growth of high-quality single-crystal 2D monolayer still needs to be improved.

Highly stable, substrate-free, and flexible broadband halide perovskite paper photodetectors.

In this work, we aim to fabricate a highly stable and flexible perovskite paper photodetector based on a Zn-doped MAFAPbI perovskite and CNC. The paper photodetector has been successfully synthesized by the vacuum filtration method and deposited with interdigitated electrodes. The paper photodetector exhibits a significant photoresponse with a responsivity of 0.

Perovskite-Nanocrystal-Doped Cellulose Nanocrystal Ligands for Electrospun Nanofibers with Excellent Stability.

Because of their exceptional physical and thermal properties, cellulose nanocrystals (CNCs) are a highly promising bio-based material for reinforcing fillers. Studies have revealed that some functional groups from CNCs can be used as a capping ligand to coordinate with metal nanoparticles or semiconductor quantum dots during the fabrication of novel complex materials. Therefore, through CNCs ligand encapsulation and electrospinning, perovskite-NC-embedded nanofibers with exceptional optical and thermal stability are demonstrated.

High sensitivity carbon monoxide detector using iron tetraphenyl porphyrin functionalized reduced graphene oxide.

The detection of pollutant and toxic gases has attracted extensive attention due to the growing environmental issues. In the present investigation, free-based tetraphenyl porphyrin (TPP) and iron tetraphenyl porphyrin (FeTPP) are used to functionalize thermally reduced graphene oxide (rGO) and further used for the detection of carbon monoxide (CO). TPP and FeTPP functionalized rGO (FeTPP@rGO) sensors are fabricated on a glass substrate with thermally coated copper electrodes.

The growth mechanism and intriguing optical and electronic properties of few-layered HfS.

Due to electronic properties superior to group VIB (Mo and W) transition metal dichalcogenides (TMDs), group IVB (Hf and Zr) TMDs have become intriguing materials in next-generation nanoelectronics. Therefore, the growth of few-layered hafnium disulfide (HfS) on -plane sapphire as well as on a SiO/Si substrate has been demonstrated using chemical vapour deposition (CVD). The structural properties of HfS were investigated by recording X-ray diffraction patterns and Raman spectra.

A Facile, Fabric Compatible, and Flexible Borophene Nanocomposites for Self-Powered Smart Assistive and Wound Healing Applications.

Smart fabrics that can harvest ambient energy and provide diverse sensing functionality via triboelectric effects have evoked great interest for next-generation healthcare electronics. Herein, a novel borophene/ecoflex nanocomposite is developed as a promising triboelectric material with tailorability, durability, mechanical stability, and flexibility. The addition of borophene nanosheets enables the borophene/ecoflex nanocomposite to exhibit tunable surface triboelectricity investigated by Kelvin probe force microscopy.

Metal-Free Perovskite Piezoelectric Nanogenerators for Human-Machine Interfaces and Self-Powered Electrical Stimulation Applications.

Single crystal metal-free halide perovskites have received great attention in recent years owing to their excellent piezoelectric and ferroelectric properties. However, the nanotoxicity and piezoelectricity within the nanoscale of such materials have yet been reported for the demonstration of practical applications. In this work, the observation of intrinsic piezoelectricity in metal-free perovskite (MDABCO-NH I ) films using piezoresponse force microscopy (PFM) is reported.

Prospects of Metal-Free Perovskites for Piezoelectric Applications.

Metal-halide perovskites have emerged as versatile materials for various electronic and optoelectronic devices such as diodes, solar cells, photodetectors, and sensors due to their interesting properties of high absorption coefficient in the visible regime, tunable bandgap, and high power conversion efficiency. Recently, metal-free organic perovskites have also emerged as a particular class of perovskites materials for piezoelectric applications. This broadens the chemical variety of perovskite structures with good mechanical adaptability, light-weight, and low-cost processability.

Barrier Properties and Hydrophobicity of Biodegradable Poly(lactic acid) Composites Reinforced with Recycled Chinese Spirits Distiller's Grains.

Adding natural biomass to poly(lactic acid) (PLA) as a reinforcing filler is a way to change the properties of PLA. This paper is about preparing PLA/biomass composites by physically melting and blending Chinese Spirits distiller's grains (CSDG) biomass and PLA to optimize the composite performance. Composites of modified PLA (MPLA) with varying amounts of CSDG were also prepared by the melt-mixing method, and unmodified PLA/CSDG composites were used as a control group for comparative analysis.

Highly UV Resistant Inch-Scale Hybrid Perovskite Quantum Dot Papers.

Halide perovskite quantum dots (PQDs) are promising materials for diverse applications including displays, light-emitting diodes, and solar cells due to their intriguing properties such as tunable bandgap, high photoluminescence quantum yield, high absorbance, and narrow emission peaks. Despite the prosperous achievements over the past several years, PQDs face severe challenges in terms of stability under different circumstances. Currently, researchers have overcome part of the stability problem, making PQDs sustainable in water, oxygen, and polar solvents for long-term use.

Camphor-Based CVD Bilayer Graphene/Si Heterostructures for Self-Powered and Broadband Photodetection.

This work demonstrates a self-powered and broadband photodetector using a heterojunction formed by camphor-based chemical vaper deposition (CVD) bilayer graphene on p-Si substrates. Here, graphene/p-Si heterostructures and graphene layers serve as ultra-shallow junctions for UV absorption and zero bandgap junction materials ( View Article and Find Full Text PDF

Charge carrier injection and transport engineering in two-dimensional transition metal dichalcogenides.

Ever since two dimensional-transition (2D) metal dichalcogenides (TMDs) were discovered, their fascinating electronic properties have attracted a great deal of attention for harnessing them as critical components in novel electronic devices. 2D-TMDs endowed with an atomically thin structure, dangling bond-free nature, electrostatic integrity, and tunable wide band gaps enable low power consumption, low leakage, ambipolar transport, high mobility, superconductivity, robustness against short channel effects and tunneling in highly scaled devices. However, the progress of 2D-TMDs has been hampered by severe charge transport issues arising from undesired phenomena occurring at the surfaces and interfaces.

A Nanostructuring Method to Decouple Electrical and Thermal Transport through the Formation of Electrically Triggered Conductive Nanofilaments.

Transforming thermal energy into electric energy and vice versa needs the decoupling of electrical transport from thermal transport. An innovative strategy is proposed by forming/disrupting electrically triggered conductive nanofilaments within semiconducting thin films to switch thermoelectric properties between two states without further material modification and manufacturing processes. It can also controllably adjust the degree of decoupling, providing a potential resolution and performance adjustability for heat/coldness control or power consumption reduction on demand.

Optimization of monochromated TEM for ultimate resolution imaging and ultrahigh resolution electron energy loss spectroscopy.

The performance of a monochromated transmission electron microscope with Wien type monochromator is optimized to achieve an extremely narrow energy spread of electron beam and an ultrahigh energy resolution with spectroscopy. The energy spread in the beam is improved by almost an order of magnitude as compared to specified values. The optimization involves both the monochromator and the electron energy loss detection system.

Single Atomically Sharp Lateral Monolayer p-n Heterojunction Solar Cells with Extraordinarily High Power Conversion Efficiency.

The recent development of 2D monolayer lateral semiconductor has created new paradigm to develop p-n heterojunctions. Albeit, the growth methods of these heterostructures typically result in alloy structures at the interface, limiting the development for high-efficiency photovoltaic (PV) devices. Here, the PV properties of sequentially grown alloy-free 2D monolayer WSe -MoS lateral p-n heterojunction are explores.