Surface cationization of cellullose via Fenton oxidation for remedying dye contaminants: Adsorption performance and mechanism.

Targeted modification of cellulose corresponds to the physicochemical characteristics of dyes is advantageous to increase its adsorption capacity, but which is still exclusive. Here, a Fenton oxidation system was applied to fabricate microcrystalline cellulose (MCC) supported iron (Cel@Fe). Physicochemical property analysis elucidated that the incorporation of Fe nanoparticles tuned the surface charge for oxidized MCC.

Understanding Protein Adsorption on Carbon Nanotube Inner and Outer Surfaces by Molecular Dynamics Simulations.

Biomolecules, such as proteins, can form complexes with carbon nanotubes (CNTs), which have numerous applications in nanobiotechnology. Proteins can be adsorbed onto either the inner walls or outer surfaces of CNTs via van der Waals interactions; however, the differences between these two processes remain poorly understood. In this work, we performed classical all-atom molecular dynamics simulations with explicit solvents to investigate the interaction between a model protein, the Yap65 WW domain, and (22,22) CNTs and larger.

Analysis of In Situ Electroporation Utilizing Induced Electric Field at a Wireless Janus Microelectrode.

In situ electroporation, a non-invasive technique for enhancing the permeability of cell membranes, has emerged as a powerful tool for intracellular delivery and manipulation. This method allows for the precise introduction of therapeutic agents, such as nucleic acids, drugs, and proteins, directly into target cells within their native tissue environment. Herein, we introduce an innovative electroporation strategy that employs a Janus particle (JP)-based microelectrode to generate a localized and controllable electric field within a microfluidic chip.

Inhomogeneous Halide Anions Distribution along Out-of-Plane Direction in Wide-Bandgap Perovskite Solar Cells and Its Effect on Open Circuit Voltage Loss and Phase Segregation.

The large open circuit voltage () loss and phase segregation are two main obstacles hindering the development of wide-bandgap perovskite solar cells (PSCs). Even though substantial progress has been made through crystallization regulation and surface modification on perovskite, the mechanism of loss and phase segregation has rarely been studied. In this paper, we first investigate the halide ions distribution along the out-of-plane direction and find the initial inhomogeneous distribution of halide ions during the crystallization process is an important reason.

Complete Stereochemical Assignment of Campechic Acids A and B.

Campechic acids A and B are anti-invasive polyketide antibiotics isolated from Streptomyces sp. CHI93 strain. Herein we describe stereoselective synthesis of the C-16-C-30 fragment of campechic acids A and B via a biosynthesis-inspired epoxide-opening cascade and its NMR spectroscopic comparison with the authentic degradation product, resulting in configurational assignment of the C-21, C-24, C-25, and C-28 stereogenic centers and reassignment of the C-18 stereogenic center.

Campechic acids A and B: anti-invasive polyether polyketides from a soil-derived Streptomyces.

Campechic acids A (1) and B (2), two new polyketides, were isolated from the culture extract of Streptomyces sp., and their structures were determined by NMR and MS spectroscopic analysis. Campechic acids are polyether-polyketides functionalized by two tetrahydrofuran rings, an enolized 1,3-diketone, and multiple methyl substitutions.

Akaeolide, a carbocyclic polyketide from marine-derived Streptomyces.

Akaeolide, a novel polycyclic polyketide, was isolated from the culture extract of a marine-derived actinomycete belonging to the genus Streptomyces. The planar structure of the new compound was elucidated by spectroscopic analysis including NMR and MS, and the absolute configuration was determined by X-ray crystallographic analysis of its chlorinated derivative. Akaeolide possesses a 15-membered carbocyclic framework, apparently derived from the malonate pathway, with a tetrahydrofuran ring and a β-keto-δ-lactone unit.

Jomthonic acid , a modified amino acid from a soil-derived Streptomyces.

Jomthonic acid A (1), a new modified amino acid, was isolated from the culture broth of a soil-derived actinomycete of the genus Streptomyces. The structure and absolute configuration of 1 were determined by spectroscopic analyses and chemical conversion. Jomthonic acid A (1) induced differentiation of preadipocytes into mature adipocytes at 2-50 μM.

Abyssomicin I, a modified polycyclic polyketide from Streptomyces sp. CHI39.

Abyssomicin I (1), a new modified polycyclic polyketide, was isolated from the culture extract of a soil-derived Streptomyces sp. The structure of 1 was elucidated by interpretation of NMR and other spectroscopic data. The stereochemistry of the new compound was assigned by NOE analysis, chemical derivatization, and application of the modified Mosher method.