Molecular insight into biomass-burning smoke water-soluble organic matter binding with Cd(II): Comprehensive analysis from fluorescence EEM-PARAFAC, FT-ICR-MS and two-dimensional correlation spectroscopy.

The deposition of biomass-burning smoke water-soluble organic matter (BBS-WSOM) significantly affects the environmental behavior of heavy metals in aqueous environments. However, the interactions between BBS-WSOM and heavy metals at the molecular level remain unknown. This study combined FT-ICR-MS, fluorescence spectrum, FTIR, and two-dimensional correlation spectroscopy to anatomize the molecular characteristics of BBS-WSOM binding with Cd(II).

Biochar-derived organic carbon promoting the dehydrochlorination of 1,1,2,2-tetrachloroethane and its molecular size effects: Synergies of dipole-dipole and conjugate bases.

The environmental effects of biochar-derived organic carbon (BDOC) have attracted increasing attention. Nevertheless, it is unknown how BDOC might affect the natural attenuation of widely distributed chloroalkanes (e.g.

Fractionation of biomass-burning smoke-derived dissolved organic matters on the surface of clay minerals: Variations of molecular properties and components.

Biomass burning (e.g., wildfire) frequently occurs globally, inevitably produces abundant biomass-burning smoke-derived dissolved organic matters (BBS-DOMs) which eventually deposits on the surface environment.

Isolation and characterization of distinctive pyrene-degrading bacteria from an uncontaminated soil.

Considerable efforts that isolate and characterize degrading bacteria for polycyclic aromatic hydrocarbons (PAHs) have focused on contaminated environments so far. Here we isolated three distinctive pyrene (PYR)-degrading bacteria from a paddy soil that was not contaminated with PAHs. These included a novel Bacillus sp.

Biochar improved the solubility of triclocarban in aqueous environment: Insight into the role of biochar-derived dissolved organic carbon.

Biochar as an effective adsorbent can be used for the removal of triclocarban from wastewater. Biochar-derived dissolved organic carbon (BC-DOC) is an important carbonaceous component of biochar, nonetheless, its role in the interaction between biochar and triclocarban remains little known. Hence, in this study, sixteen biochars derived from pine sawdust and corn straw with different physico-chemical properties were produced in nitrogen-flow and air-limited atmospheres at 300-750 °C, and investigated the effect of BC-DOC on the interaction between biochar and triclocarban.

Mobility of antipyretic drugs with different molecular structures in saturated soil porous media.

In the post-COVID-19 era, extensive quantities of antipyretic drugs are being haphazardly released from households into the environment, which may pose potential risks to ecological systems and human health. Identification of the mobility behaviors of these compounds in the subsurface environment is crucial to understand the environmental fate of these common contaminants. The mobility properties of three broad-spectrum antipyretic drugs, including ibuprofen (IBF), indometacin (IMC), and acetaminophen (APAP), in porous soil media, were investigated in this study.

Water-soluble organic carbon (WSOC) from vegetation fire and its differences from WSOC in natural media: Spectral comparison and self-organizing maps (SOM) classification.

Vegetation fire frequently occurs globally and produces two types of water-soluble organic carbon (WSOC) including black carbon WSOC (BC-WSOC) and smoke-WSOC, they will eventually enter the surface environment (soil and water) and participate in the eco-environmental processes on the earth surface. Exploring the unique features of BC-WSOC and smoke-WSOC is critical and fundamental for understanding their eco-environmental effects. Presently, their differences from the natural WSOC of soil and water remain unknown.

Transport of dissolved organic matters derived from biomass-pyrogenic smoke (SDOMs) and their effects on mobility of heavy metal ions in saturated porous media.

Biomass-pyrogenic smoke-derived dissolved organic matter (SDOMs) percolating into the underground environment profoundly impacts the transport and fate of environmental pollutants in groundwater systems. Herein, SDOMs were produced by pyrolyzing wheat straw at 300-900 °C to explore their transport properties and effects on Cu mobility in quartz sand porous media. The results indicated that SDOMs exhibited high mobility in saturated sand.

Pyrolysis Atmospheres and Temperatures Co-Mediated Spectral Variations of Biochar-Derived Dissolved Organic Carbon: Quantitative Prediction and Self-Organizing Maps Analysis.

Biochar-derived dissolved organic carbon (BDOC), as a highly activated carbonaceous fraction of biochar, significantly affects the environmental effect of biochar. This study systematically investigated the differences in the properties of BDOC produced at 300-750 °C in three atmosphere types (including N and CO flows and air limitation) as well as their quantitative relationship with biochar properties. The results showed that BDOC in biochar pyrolyzed in air limitation (0.

Spectral characteristics coupled with self-organizing maps analysis on different molecular size-fractionated water-soluble organic carbon from biochar.

Biochar-derived water-soluble organic carbon (BWSOC) plays important roles in the environmental effect of biochar. The environmental behavior and fate of BWSOC are closely related to its size distribution and chemical components. However, the molecular size-dependent BWSOC components and properties remain little known.

Influence of pyrolysis atmosphere and temperature co-regulation on the sorption of tetracycline onto biochar: structure-performance relationship variation.

Presently, as the prevalent pyrolysis atmospheres, N is widely used, while air-limitation and CO are rarely considered, to produce biochar to adsorb tetracycline. This study thus used N, CO, and air-limitation to produce various biochars at 300 ∼ 750 °C, and explored their structure-performance relationship for tetracycline sorption. The maximum sorption capacities of biochars produced in CO and air-limitation were 55.

Spectral characteristics of dissolved organic carbon (DOC) derived from biomass pyrolysis: Biochar-derived DOC versus smoke-derived DOC, and their differences from natural DOC.

Biochar-derived dissolved organic carbon (BDOC) and smoke-derived dissolved organic carbon (SDOC) are two different biomass-pyrogenic DOCs. They inevitably enter soil and water, then potentially pose different impacts on the chemistry of these media. This study systemically investigated the emissions and spectral characteristics of BDOC and SDOC as well as their differences from natural DOC.

The composition, energy, and carbon stability characteristics of biochars derived from thermo-conversion of biomass in air-limitation, CO, and N at different temperatures.

This study systemically investigated the characteristics of biochars derived from thermo-conversion of pine sawdust and wheat straw in air-limitation, CO, and N atmospheres at the temperatures of 300-750 °C. Meanwhile, their energy and C stability parameters were also evaluated here. The results showed that biochar produced in air-limitation had less yield, fixed C and bulk C, as well as more volatile matter and inorganic elements than that produced in CO and N.

Spectral characteristics of dissolved organic carbon derived from biomass-pyrogenic smoke (SDOC) in the aqueous environment and its solubilization effect on hydrophobic organic pollutants.

Dissolved organic carbon derived from biomass-pyrogenic smoke (SDOC) can be transported and deposited with atmospheric aerosols, enter aqueous environments, and possibly alter aqueous chemistry and quality. However, the characteristics of SDOC in aqueous environments and their effects on the fate of hydrophobic organic pollutants are poorly understood. In this study, we found that the emitted SDOC is 7.

Biochar-mediated reduction of m-nitrotoluene: Interaction between reduction of m-nitrotoluene and sequestration of contaminants.

Biochar is a highly effective adsorbent for nitroaromatic compounds (NACs), and acts as an electron shuttle that mediates the reduction of NACs. Hence, when biochar is used to mediate NAC reduction, adsorption and reduction will occur simultaneously and affect each other. However, the effect of biochar-mediated NAC reduction on sorption remains unknown.

Difference in characteristics and nutrient retention between biochars produced in nitrogen-flow and air-limitation atmospheres.

The different effects of nitrogen-flow (NF) and air-limitation (AL) pyrolysis on the characteristics and nutrient retention of biochars (BCs) are unclear. Hence, in this study, BCs derived from bamboo, corn straw, and wheat straw were produced in AL and NF atmospheres at various temperatures (300-750 °C), and their different characteristics and nutrient retention rates were compared systematically. Nitrogen-flow pyrolysis facilitates C retention and graphitic C formation, and AL pyrolysis improves the polarity and supports the formation of oxygen-containing groups.

Differential roles of ash in sorption of triclosan to wood-derived biochars produced at different temperatures.

Biochar is composed of carbonaceous and inorganic (ash) fractions. The structural properties of carbonaceous fractions and the composition of ash in biochar are both variable with pyrolysis temperature. However, it is unknown whether ash may play different roles in sorption of organic compounds to the carbonaceous fraction of biochars produced at different temperatures.

Insight into the mechanism of low molecular weight organic acids-mediated release of phosphorus and potassium from biochars.

A crucial mechanism for the application of biochar in soil improvement is the direct release of nutrients from biochar. Low molecular weight organic acids (LMWOAs) ubiquitously exist in soil. However, the mechanism of LMWOAs-mediated release of nutrients from biochars remains little known.

[Contents,Sources,and Ecological Risk Assessment of Polycyclic Aromatic Hydrocarbons (PAHs) in Surface Soils of Various Functional Zones in Yangzhou City, China].

The contents and sources of 15 US EPA priority polycyclic aromatic hydrocarbons (PAHs) were analyzed in 59 surface soil samples (0-10 cm depth) collected from six functional zones, including cultural and educational area, park, residential area, vegetable garden, gas station, and industrial area, in Yangzhou City. The toxicity equivalent content of benzo[a]pyrene (TEQ) was adopted to assess PAH risks in soils. The results showed that the contents of Σ15PAHs in soil samples ranged from 21 to 36118 μg·kg, with a median value of 295 μg·kg.

Different effects of N-flow and air-limited pyrolysis on bamboo-derived biochars' nitrogen and phosphorus release and sorption characteristics.

Advantages for biochars used in soil improvement have been proposed to their nutrients release and sorption characteristics which strongly depend on their production conditions. N-flow and air-limited pyrolysis are two different widely-applied oxygen-limited pyrolysis methods for producing biochars, however, their different effects on nutrients release and sorption characteristics of biochars remains unknown. In this study, bamboo derived biochars pyrolyzed in N-flow (BC-N) and air-limited environments (BC-Air) at the temperature of 150~750 °C were used to compare the release and sorption of nitrogen and phosphorous nutrients.

Insights into the roles of the morphological carbon structure and ash in the sorption of aromatic compounds to wood-derived biochars.

Currently, it is still lack of systematic and in-depth knowledge regarding the co-effect of carbon-based fractions and ash in the sorption behavior of biochars. Therefore, pristine wood-derived biochars (PBCs) produced at different temperatures and their corresponding de-ashed versions (DBCs) were used to determine the roles of carbon's morphological structure and ash in sorption of aromatic compounds (toluene, m-toluidine, and m-nitrotoluene) to biochars. The results showed that biochars produced at 300-400 °C (mainly uncarbonized organic matter, UCOM) and 900 °C (turbostratic carbon, TC) may have stronger partition effect and pore filling effect with π-π interaction, respectively, and thus have greater sorption coefficients (Lg K) than biochars produced at 600 °C (pyrogenic amorphous carbon, PAC), which are probably dominated by surface hydrophobic effect.

Characteristics of wood-derived biochars produced at different temperatures before and after deashing: Their different potential advantages in environmental applications.

Ash in biochar has great influence on the characteristics of biochars. This study systematically compared the differences in physico-chemical properties between pristine biochars (PBCs) and deashed biochars (DBCs) produced at different temperatures (300-900 °C), and specifically analyzed their different advantages in environmental applications. In terms of all the PBCs and DBCs, PBC of 900 °C and the corresponding DBC have the highest degree of graphitization that is recalcitrant in environment, they are benefit for carbon sequestration.

Charge-assisted hydrogen bonding as a cohesive force in soil organic matter: water solubility enhancement by addition of simple carboxylic acids.

Weak bonds between molecular segments and between separate molecules of natural organic matter (OM) govern OM solubility, adsorption, supramolecular association in solution, and complexation with metal ions and oxides. We tested the hypothesis that especially strong hydrogen bonds, known as (negative) charge-assisted hydrogen bonds, (-)CAHB, contribute significantly to OM cohesion and play a role in the water solubility of solid-phase OM. The (-)CAHB, exemplified by structures such as (-CO2HO2C-)- and (-CO2HO-)-, may form between weak acids with similar proton affinity, and is shorter, more covalent, and much stronger than ordinary hydrogen bonds.