A Natural Oxygen-Harvesting Electrode Enables Aeration-Free Electrochemical Advanced Oxidation for In Situ Water Remediation.

Electro-Fenton treatment through the two-electron oxygen reduction reaction (2e ORR) offers an effective approach for degrading persistent organic pollutants (POPs) in water; however, aeration is always required to overcome the low solubility of oxygen in water, ensuring adequate oxygen availability for the 2e ORR to generate HO and facilitate its transport for activation into hydroxyl radicals. The aeration energy consumption can reach tens of times higher than the energy required for the electrochemical reactions themselves. To address this, we developed an aeration-free dual-cathode system featuring a natural oxygen-harvesting electrode (NOHE).

Surface Oxygen Vacancy Engineering for Enhanced Volatile Organic Compounds Removal in Solar-Interfacial Water Evaporation.

Solar-interfacial water-vapor conversion has emerged as a promising method for clean water production, particularly in water-scarce regions, but a major challenge is the volatile organic compounds (VOCs) along with water vapor, leading to polluted condensed water. This study introduces a novel design strategy that leverages surface oxygen vacancies (OVs) in photocatalysts to maximize both oxygen (O) utilization from the air and photocarrier efficiency at the air-water interface, building upon previous research that demonstrated that oxygen concentration at the interface can be significantly higher than that in bulk water. By enhancing oxygen adsorption and facilitating charge carrier separation, OVs significantly improve reactive oxygen species (ROS, including ·O and ·OH) generation and overall photocatalytic activity.

An in-depth study of integrating cascaded photocatalytic HO generation and activation with solar-driven interfacial evaporation for in-situ organic contaminant remediation.

Integrating cascaded photocatalytic HO generation and subsequent activation of HO (into ·OH radicals) with solar-driven interfacial evaporation techniques offers an effective and sustainable approach for in-situ treating water contaminated with organic substances. Unlike traditional water-dispersed catalysts, the interfacial evaporation approach presents unique challenges in photocatalytic reactions. We explored these dynamics using an AgI/PPy/MF interfacial photothermal set, achieving HO production efficiency (approximately 1.

Diosmetin ameliorates psoriasis-associated inflammation and keratinocyte hyperproliferation by modulation of PGC-1α / YAP signaling pathway.

Psoriasis, characterized by aberrant epidermal keratinocyte proliferation and differentiation, is a chronic inflammatory immune-related skin disease. Diosmetin (Dios), derived from citrus fruits, exhibits anti-inflammatory and anti-proliferative properties. In this study, IL-17A-induced HaCaT cell model and Imiquimod (IMQ)-induced mouse model were utilized to investigate the effects of Dios against psoriasis.

Decoupled oxidation process enabled by atomically dispersed copper electrodes for in-situ chemical water treatment.

In-situ wastewater treatment has gained popularity due to cost and energy savings tailored to water sources and user needs. However, this treatment, particularly through advanced oxidation processes (AOPs), poses ecological risks due to the need for strong oxidizing agents. Here, we present a decoupled oxidation process (DOP) using single-atom copper-modified graphite felt electrodes.

Reconstruction of a Soil Microbial Network Induced by Stress Temperature.

The microbial community is viewed as a network of diverse microorganisms connected by various interspecific interactions. While the stress gradient hypothesis (SGH) predicts that positive interactions are favored in more stressful environments, the prediction has been less explored in complex microbial communities due to the challenges of identifying interactions. Here, by applying a nonlinear time series analysis to the amplicon-based diversity time series data of the soil microbiota cultured under less stressful (30°C) or more stressful (37°C) temperature conditions, we show how the microbial network responds to temperature stress.

Synthesis and anti-inflammatory activity of paeonol derivatives with etherized aryl urea by regulating TLR4/MyD88 signaling pathway in RAW264.7 cell.

Thirty-three novel paeonol etherized aryl urea derivatives (PEUs) were synthesized via a bromination-Williamson Ether Synthesis-deprotection-nucleophilic addition reaction sequence. The structures of PEUs were characterized by LC-MS, HRMS, H NMR and C NMR spectra. The levels of nitric oxide (NO), tumor necrosis factor-alpha (TNF-α) and interleukin-1 beta (IL-1β) in lipopolysaccharide (LPS)-induced RAW264.

[Identification of chemical constituents in Yangxue Qingnao granule by UPLC-Q-TOF/MS~E].

In order to clarify the chemical constituents in Yangxue Qingnao granule, we established a rapid ultra-performance liquid chromatography/orthogonal acceleration time-of-flight mass spectrometry (UPLC-Q-TOF/MS(E)) method. According to the high resolution MS spectra data, fragmentation ion information and retention time,142 peaks were identified or tentatively presumed by comparison with reference standards data and literature reports. The herbal sources of these peaks were assigned.