Tuning Nanofibrous Sensor Performance in Selective Detection of B-VOCs by MIP-NP Loading.

In this study, we investigate the effect of varying the loading of molecularly imprinted polymer nanoparticles (MIP-NPs) on the morphology and sensing performance of electrospun nanofibres for the selective detection of linalool, a representative plant-emitted monoterpene. The proposed strategy combines two synergistic technologies: molecular imprinting, to introduce chemical selectivity, and electrospinning, to generate high-surface-area nanofibrous sensing layers with tuneable architecture. Linalool-imprinted MIP-NPs were synthesized via precipitation polymerization using methacrylic acid (MAA) and ethylene glycol dimethacrylate (EGDMA), yielding spherical particles with an average diameter of ~135 nm.

EU geographical islands as leaders of green energy transition.

This paper reviews how European islands are taking the lead in the European Union (EU) Clean Energy Transition by reviewing the lessons learned in the EU Bridge initiative and in a number of EU co-funded projects such as NESOI, RE-EMPOWERED, REACT, IANOS, LOCALRES, MASTERPIECE, SINNOGENES, SMHYLES, STEPWISE, and ISLET. Islands encounter significant difficulties in the management of their energy systems, including strong seasonal variations in energy demand, high operational costs and GHG emissions for energy production, weak energy grids, lack of technical skills, and difficult access to finance. However, they also have positive features that make them ideal laboratories for energy transition, including high potential for renewables, small-scale and strong community structures, and high energy prices, which make most solutions cost-effective.

An in vivo assessment revealed multiple toxic effects of brake dust on the urban mosquito Aedes albopictus.

Brake dust is a major component of particulate matter (PM) and enriched in potentially toxic elements (PTEs), posing a significant threat to both the environment and health especially in densely populated areas. In this context, an in vivo approach is essential to understand its potential negative effects. Here, we investigated the toxicity of brake dust on Aedes albopictus, a common mosquito species in urban environments.

Sources and characterisation of organic pollutants in airborne particle fractions in an urban area, Bab Ezzaour, Algeria: A focus on n-alkanes and polar substances.

The main objective of this study was to determine the loads, sources and behaviour of n-alkanes and several polar organics, including plasticisers (phthalates, [bis]2-ethylhexyl adipate), psychotropic substances (both legal and illegal) and the mosquito repellent DEET, in the atmosphere of the city of Bab Ezzouar, northern Algeria. Particulate matter was classified into three fractions according to aerodynamic diameter: coarse (PM), fine (PM) and ultrafine (PM) particles. s.

Inhalation of nanoplastics in the mouse model: Tissue bio-distribution and effects on the olfactory system.

The impact of plastic fragments on human health is currently under investigation, with nanoplastics (NPs) being particularly concerning due to their small size. This allows them to be inhaled, pass through blood barriers, and reach various organs. In this study, we evaluated the effects of airborne NPs on the mouse olfactory system, which is a primary target of NPs inhalation.

Cutting-Edge Sensor Design: MIP Nanoparticle-Functionalized Nanofibers for Gas-Phase Detection of Limonene in Predictive Agriculture.

As population growth and climate change intensify pressures on agriculture, innovative strategies are vital for ensuring food security, optimizing resources, and protecting the environment. This study introduces a novel approach to predictive agriculture by utilizing the unique properties of terpenes, specifically S(-)-limonene, emitted by plants under stress. Advanced sensors capable of detecting subtle limonene variations offer the potential for early stress diagnosis and precise crop interventions.

PRA Melting-ICE Project: Svalbard 2022 Expeditions Report.

Arctic regions are among the fastest warming areas of the planet. Increasing average temperatures over the last five decades have deepened the thawing of the upper-most layer of permafrost across the Arctic, which contains significant amounts of organic carbon. The progressive deepening of seasonal thawing releases carbon that is used by active microorganisms which also produce greenhouse gases, potentially onsetting a positive feedback on global warming.

Assessment of oxidative stress induced by atmospheric particulate matter: from acellular and cellular assays to the use of model and experimental organisms.

Oxidative stress is considered one of the major mechanisms by which atmospheric particulate matter (PM) can induce adverse effects on living systems. Recently, the assessment of PM-induced oxidative stress effects has gained importance, and many efforts have been invested in identifying the most suitable techniques for evaluating PM toxicological potential. This paper briefly resumes the current knowledge and criticisms related to the application of the OP and cellular assays and systematically reviews the studies focused on the assessment of PM-induced oxidative stress using model or experimental organisms.

Twenty years of studying the origins and fate of atmospheric mercury over the Mediterranean Sea.

This study provides a review of 13 oceanographic campaigns between 2000 and 2017 to measure Hg in the Mediterranean, highlighting major findings from measurement and modelling activities during the Med-Oceanor program. The initial campaigns showed that high concentrations of RGM could be found far from industrial source regions and the observed daily variation in concentration, with peaks at midday and lower concentrations during darkness gave the first indications that photochemically mediated oxidation reactions were producing RGM in the MBL. Later atmospheric chemistry modelling studies showed the feasibility of Hg oxidation by bromine containing oxidants, which are released as a result of the acidification of sea salt aerosols in the Marine Boundary Layer (MBL).

Three-Dimensionally Printed Mini Air Scrubbing Cartridges Based on Nano-Graphite for Air Pollution Monitoring.

Ecosystems and environments are impacted by atmospheric pollution, which has significant effects on human health and climate. For these reasons, devices for developing portable and low-cost monitoring systems are required to assess human exposure during daily life. In the last decade, the advancements of 3D printing technology have pushed researchers to exploit, in different fields of applications, the advantages offered, such as rapid prototyping and low-cost replication of complex sample treatment devices.

Achieving synergistic enhancement in the anaerobic digestion of corn straw by (CH + CO) nanobubbles in conjunction with optimized particle sizes.

Nanobubbles (NBs) technology has been proven to promote methane production from anaerobic digestion (AD). In this study, the synergistic effects of (CH + CO)-nanobubble water ((CH + CO)-NBW) combined with varying particle sizes of corn straw on the AD were investigated. As findings, adding (CH + CO)-NBW effectively promoted the methane production from AD of corn straw with different particle sizes.

Evaluating microplastic emission from takeaway containers: A Micro-Raman approach across diverse exposure scenarios.

Based on inconsistencies observed in literature regarding microplastic levels released by takeaway plastic containers, this study investigates the release from takeaway containers composed of polypropylene (PP), polystyrene (PS), and polyethylene terephthalate (PET). To simulate real-world conditions, experiments were conducted using Milli-Q water at room temperature, 100 °C, and at pH 4.5.

Sphagnum moss and peat comparative study: Metal release, binding properties and antioxidant activity.

Peat is the main constituent of cultivation substrates and a precious non-renewable fossil material. Peatlands provide important ecosystem services and allow the absorption and storage of carbon. Protecting peatlands helps tackle climate change and contributes to biodiversity conservation.

Route to chaos and resonant triads interaction in a truncated rotating nonlinear shallow-water model.

The route to chaos and the phase dynamics of the large scales in a rotating shallow-water model have been rigorously examined through the construction of an autonomous five-mode Galerkin truncated system employing complex variables, useful in investigating how large/meso-scales are destabilized and how their dynamics evolves and transits to chaos. This investigation revealed two distinct transitions into chaotic behaviour as the level of energy introduced into the system was incrementally increased. The initial transition manifests through a succession of bifurcations that adhere to the established Feigenbaum sequence.

Modelling the anthropogenic Hg pollution fingerprint on the marine fishery production worldwide: A preliminary exposure assessment for people living in countries having different income levels.

Mercury is a toxic pollutant that poses risks for the human population, mainly by eating contaminated fish. Mercury is released into the atmosphere from a variety of anthropogenic activities, with levels of emissions and under policy controls that largely vary across the world, leading thus to different relative contributions to the environmental matrices. Establishing the exact sources of this contaminant in the environment is crucial to optimising the policies aimed at mitigating the exposure risks for specific populations or ecosystems.

Atmospheric bulk depositions: state-of-the-art and European legislative framework with focus on Italy.

The determination of total atmospheric deposition (bulk) is an essential tool to assess the state of environmental contamination and the consequent exposure of the population to persistent organic pollutants (POPs) through the intake of contaminated food. Over the past 20 years, international authorities and the European Union through various pieces of legislation have emphasised the importance of conducting monitoring and studies on depositions to better understand their impact on the environment and human health without setting reference values. Despite the absence of such values, several European countries, through national laws, have adopted limit values and/or guideline values for the deposition fluxes of some organic (dioxins, furans, polychlorinated biphenyls and polycyclic aromatic hydrocarbons) and inorganic persistent pollutants (metals).

Syntaxonomical Remarks on the Garrigues from Apulia (S Italy) and Neighboring Territories.

In this study, the garrigues occurring in Apulia and neighboring territories (southern Italy) were surveyed in order to clarify their syntaxonomical arrangement. Many contributions previously focused on this vegetation type, often adopting different and sometimes contrasting treatments from both the nomenclature and syntaxonomical aspects. Our investigations are supported by the multivariate analysis of a dataset containing 292 phytosociological relevés, whose resulting cluster dendrogram highlights the hierarchical relationships between the examined plant communities.

Nanofibrous Conductive Sensor for Limonene: One-Step Synthesis via Electrospinning and Molecular Imprinting.

Detecting volatile organic compounds (VOCs) emitted from different plant species and their organs can provide valuable information about plant health and environmental factors that affect them. For example, limonene emission can be a biomarker to monitor plant health and detect stress. Traditional methods for VOC detection encounter challenges, prompting the proposal of novel approaches.

High-Resolution Mass Spectrometry for Human Exposomics: Expanding Chemical Space Coverage.

In the modern "omics" era, measurement of the human exposome is a critical missing link between genetic drivers and disease outcomes. High-resolution mass spectrometry (HRMS), routinely used in proteomics and metabolomics, has emerged as a leading technology to broadly profile chemical exposure agents and related biomolecules for accurate mass measurement, high sensitivity, rapid data acquisition, and increased resolution of chemical space. Non-targeted approaches are increasingly accessible, supporting a shift from conventional hypothesis-driven, quantitation-centric targeted analyses toward data-driven, hypothesis-generating chemical exposome-wide profiling.

Improving Aerosol Characterization Using an Optical Particle Counter Coupled with a Quartz Crystal Microbalance with an Integrated Microheater.

Aerosols, as well as suspended particulate matter, impact atmospheric pollution, the climate, and human health, directly or indirectly. Particle size, chemical composition, and other aerosol characteristics are determinant factors for atmospheric pollution dynamics and more. In the last decade, low-cost devices have been widely used in instrumentation to measure aerosols.

There's Something in What We Eat: An Overview on the Extraction Techniques and Chromatographic Analysis for PFAS Identification in Agri-Food Products.

Per- and polyfluorinated alkyl substances (PFASs) are a group of anthropogenic chemicals used in a range of industrial processes and consumer products. Recently, their ubiquitous presence in the environment as well as their toxicological effects in humans have gained relevant attention. Although the occurrence of PFASs is widely investigated in scientific community, the standardization of analytical method for all matrices still remains an important issue.

A Polyvinylpyrrolidone Nanofibrous Sensor Doubly Decorated with Mesoporous Graphene to Selectively Detect Acetic Acid Vapors.

An original approach has been proposed for designing a nanofibrous (NF) layer using UV-cured polyvinylpyrrolidone (PVP) as a matrix, incorporating mesoporous graphene carbon (MGC) nanopowder both inside and outside the fibers, creating a sandwich-like structure. This architecture is intended to selectively adsorb and detect acetic acid vapors, which are known to cause health issues in exposed workers. The nanocomposite MGC-PVP-NFs layer was fabricated through electrospinning deposition onto interdigitated microelectrodes (IDEs) and stabilized under UV-light irradiation.