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Oil-water emulsions are prevalent in petroleum, chemical, and materials industries, where their rheological properties significantly impact processing efficiency. This review systematically examines the key factors influencing the apparent viscosity of oil-water emulsions, including oil composition, water characteristics, temperature, shear conditions, and emulsifier properties. It traces the evolution of viscosity prediction methodologies, encompassing conventional, complex, and Pickering emulsions, and assesses modeling approaches ranging from early theoretical frameworks to contemporary machine learning techniques. The reliability and applicability of these models are critically evaluated across various industrial contexts. Furthermore, the review identifies key challenges, research gaps, and prospective directions, emphasizing potential advancements in experimental strategies and modeling methodologies. While focusing on petrochemical emulsions, the insights and analytical approaches discussed are applicable to biological, medical, and other industrial systems, offering guidance for future research and practical implementation.
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http://dx.doi.org/10.1111/nyas.70071 | DOI Listing |
Ann N Y Acad Sci
September 2025
College of Chemical Engineering, Fuzhou University, Fuzhou, China.
Oil-water emulsions are prevalent in petroleum, chemical, and materials industries, where their rheological properties significantly impact processing efficiency. This review systematically examines the key factors influencing the apparent viscosity of oil-water emulsions, including oil composition, water characteristics, temperature, shear conditions, and emulsifier properties. It traces the evolution of viscosity prediction methodologies, encompassing conventional, complex, and Pickering emulsions, and assesses modeling approaches ranging from early theoretical frameworks to contemporary machine learning techniques.
View Article and Find Full Text PDFLangmuir
September 2025
College of Petroleum Engineering, Liaoning Petrochemical University, Fushun 113001, Liaoning, China.
In recent years, amino acids have garnered extensive attention as environmentally friendly, small-dose additives for modulating hydrate formation and aggregation behavior. Amino acids, due to their amphiphilic nature, can adsorb at the gas-liquid interface and on hydrate crystal surfaces, thereby modifying interfacial properties and influencing crystal growth patterns. In our measurements, the amino acids displayed a concentration-dependent "double effect".
View Article and Find Full Text PDFFood Chem
September 2025
Nantong Food and Drug Supervision and Inspection Center, Nantong 226001, PR China.
Different starch crystal structures significantly influence meat product quality, though their specific impacts on myofibrillar protein (MP) functionality remain unclear despite industry demand for optimized ingredients. This study compared how potato, corn, mung bean, and pea starches affect MP properties in minced pork. Our findings reveal that starch-protein interactions fundamentally regulate MP gel and emulsion properties through the following mechanisms: First, starch promotes protein aggregation by enhancing hydrophobic interactions and disulfide bond formation, affecting gel network crosslinking.
View Article and Find Full Text PDFChem Asian J
September 2025
Interdisciplinary Research Centre for Membranes and Water Security, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia.
In this study, a silicon carbide (SiC) mixed-matrix membrane for oil-water separation was successfully fabricated within the nanofiltration range. Silicon carbide was synthesized using rice husk ash (RHA), an agricultural waste material, combined with polydimethylsiloxane (PDMS) and subsequently incorporated into a mixed matrix membrane for oil-water separation. Polysulfone (PSF) and polyvinylpyrrolidone (PVP) were employed as polymer supports for fabricating the SiC-based mixed matrix membrane, which was tested in a dead-end filtration setup.
View Article and Find Full Text PDFCarbohydr Polym
November 2025
Tianjin Key Laboratory of Food Biotechnology, College of Biotechnology and Food Science, Tianjin University of Commerce, Tianjin 300134, China; Key Laboratory of Low Carbon Cold Chain for Agricultural Products, Ministry of Agriculture and Rural Affairs, Tianjin 300134, China. Electronic address: wzj
For purpose of overcoming the negative impact of high-dose phenols on meat quality, xanthan gum (XG), a natural anionic polysaccharide, was employed to prevent the undesirable interaction between myofibrillar protein (MP) and gallic acid (GA, 150 μmol/g) and ameliorate the gel and emulsification characteristics of MP. XG dose-dependently alleviated the structural damage of MP caused by GA and reduced protein aggregation, manifested as the decrease in surface hydrophobicity, turbidity and aggregate size (p < 0.05) and increase in α-helix content and intrinsic fluorescence.
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