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The traditional von Neumann architecture continues to limit the development of artificial intelligence. Memristors have become one of the most promising devices for breaking through the traditional von Neumann architecture. In this work, an optoelectronic synapse based on the CuInGaSe (CIGS)/ Al-doped ZnO (AZO) p-n heterojunction is prepared by radio-frequency (RF) magnetron sputtering. And the Au/CIGS/AZO/ITO p-n heterojunction artificial synapse has been utilized to simulate various synaptic behaviors as well as the learning-forgetting-relearning process of the human brain. Furthermore, employing a convolutional neural network (CNN) architecture with an enhanced stochastic gradient descent algorithm, the recognition accuracy for the MNIST and Fashion-MNIST datasets is achieved at 97.36% and 83%, respectively, demonstrating the potential application of Au/CIGS/AZO/ITO p-n heterojunction artificial synapse in neuromorphic computing and providing a feasible method for the development of high-performance optoelectronic devices based on CIGS/AZO p-n heterojunctions.
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http://dx.doi.org/10.1002/smll.202507129 | DOI Listing |
ACS Nano
September 2025
School of Microelectronics, University of Science and Technology of China, Hefei, Anhui 230026, China.
Superlinear photodetectors hold significant potential in intelligent optical detection systems, such as near-field imaging. However, their current realization imposes stringent requirements on photosensitive materials, thereby limiting the flexibility of the device integration for practical applications. Herein, a tunable superlinear GaO deep-ultraviolet gate-all-around (GAA) phototransistor based on a p-n heterojunction has been proposed.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
Precise Synthesis and Function Development Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637002, PR China.
Herein, CuBiO microspheres were first deposited on TiO nanotube arrays to develop a p-n CuBiO/TiO heterojunction by a facile hydrothermal protocol. The variations in the photoinduced open-circuit potential, photocurrent, and electrochemical parameters of the nickel-plated magnesium alloy (Mg/Ni) demonstrated the remarkably strengthened photoelectrochemical efficiency and photocathodic protection (PCP) capability caused by the CuBiO modification. This enhancement is attributed to establishing a built-in electric field and intensified light absorption in a broadened wavelength spectrum, confirmed by the valence band XPS and ultraviolet-visible spectra.
View Article and Find Full Text PDFMikrochim Acta
September 2025
School of Chemical Science and Technology, Yunnan University, Kunming, 650500, China.
A CuFeO/NiCo-LDH heterojunction electrochemical sensor (LDH: layered double hydroxide) was developed for the sensitive detection of tetracycline (TC). The sensor was constructed by integrating ZIF-67-derived nanocage NiCo-LDH on nickel foam with CuFeO, forming a p-n heterojunction that enhanced electron transfer and TC adsorption. The sensor exhibited bilinear detection ranges (0.
View Article and Find Full Text PDFJ Mater Chem B
September 2025
School of Chemistry and Chemical Engineering, NanChang University, NanChang, Jiangxi, 330031, P. R. China.
Photocatalytic antibacterial therapy is a promising method for wound disinfection and treatment. However, the weak photocatalytic antibacterial activity of ZnO stimulated by visible light limits its applications. In this study, porous CuO@ZnO heterojunctions with enhanced visible light response are successfully synthesized by coupling ZnO and CuO using a one-pot water bath method.
View Article and Find Full Text PDFACS Sens
September 2025
School of Chemical Engineering, Zhengzhou University, Zhengzhou, 450001, China.
Chemiresistive gas sensors have emerged as a promising technology for gas detection, due to their real-time response, low costs, high sensitivity, excellent stability, and facile fabrication. However, the full realization of their potential is currently constrained by the scarcity of sensing materials capable of delivering high selectivity and ultrafast response. In this study, we prepared a three-dimensional inverse opal macroporous SnO doped with NiO (3DIO NiO-SnO).
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