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Two-temperature induced phase separation (2-TIPS) is a phenomenon observed in mixtures of active and passive particles modeled by scalar activity where the temperature of the particle is proportional to its activity. The binary mixture of "hot" and "cold" particles phase separates when the relative temperature difference between hot and cold particles, defined as activity χ, exceeds a density-dependent critical value. The study of kinetics in 2-TIPS, a nonequilibrium phase separation, is of fundamental importance in statistical physics. In this paper, we investigate 2-TIPS kinetics using molecular dynamics (MD) and coarse-grained (CG) modeling in three and two dimensions. The coarse-grained model couples two passive model B equations for hot and cold particles, with coupling terms emulating the energy transfer between them by raising the temperature of cold particles and lowering that of hot particles, a key observation from the MD simulations. MD simulations reveal that, at high densities, phase separation begins immediately after the quench, forming bicontinuous domains rich in hot or cold particles, similar to spinodal decomposition in passive systems. These interconnected domains are also observed in the coarse-grained model for the mixture's critical composition. Both MD and CG models show dynamic scaling of the correlation function, indicating self-similar domain growth. Regardless of dimensionality, both methods report algebraic growth in domain length with a growth exponent of 1/3, known as the Lifshitz-Slyozov exponent, widely observed in passive systems. Our results demonstrate that the universality of phase-separation kinetics observed in passive systems also extends to the nonequilibrium binary mixture undergoing 2-TIPS.
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http://dx.doi.org/10.1103/1c8b-hmxv | DOI Listing |
Adv Mater
September 2025
Key Laboratory for Intelligent Nano Materials and Devices of Ministry of Education, and International Institute for Frontier Science, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, China.
Transmission-type radiative cooling textiles represent a vital strategy for personal thermal management. However, traditional preparation methods based on heat-induced phase separation face significant challenges regarding cost, environmental impact, and optical performance. Herein, a novel preparation method is devloped by blending mid-IR transparent solid styrene ethylene butylene styrene (SEBS) with solid polyethylene (PE), enabling the creation of pores through dissolving SEBS.
View Article and Find Full Text PDFMagn Reson Med
September 2025
Department of Biomedical Engineering, University of Wisconsin-Madison, Madison, Wisconsin, USA.
Purpose: Gadoxetic acid-enhanced hepatobiliary phase T-weighted (Tw) MRI is effective for the detection of focal liver lesions but lacks sufficient T contrast to distinguish benign from malignant lesions. Although the addition of T, diffusion, and dynamic contrast-enhanced Tw imaging improves lesion characterization, these methods often do not provide adequate spatial resolution to identify subcentimeter lesions. This work proposes a high-resolution, volumetric, free-breathing liver MRI method that produces colocalized fat-suppressed, variable Tw images from a single acquisition, thereby improving both lesion detection and characterization.
View Article and Find Full Text PDFJ Sep Sci
September 2025
Programa de Pós-Graduação em Ciências Farmacêuticas, Universidade Federal do Rio Grande do Sul, Porto Alegre, RS, Brazil.
Nifurtimox (NFX) is a chiral drug used for the treatment of Chagas Disease. Little attention has been paid to the enantioselective properties of chiral drugs used for neglected tropical diseases, highlighting the need for further studies in this area. In this work, the enantioselective properties of NFX were carefully investigated by HPLC using different chiral stationary phases (CSPs) and chromatographic modes.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Surface Science Laboratory, Department of Materials and Geosciences, Technical University of Darmstadt, Peter-Grünberg-Straße 4, 64287 Darmstadt, Germany.
The performance of NiO-based electrocatalysts for the oxygen evolution reaction (OER) is strongly influenced by the interface between the metal support (current collector) and the catalyst layer, which modulates electronic properties and electrochemical activity. This study systematically investigates the solid-solid interface behavior of NiO thin films prepared by reactive magnetron sputtering on Pt, Au, and Ni, followed by electrochemical characterization. Stepwise NiO deposition and X-ray photoelectron spectroscopy reveal distinct band alignment and electronic structure differences at the metal-catalyst interface.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Department of Chemical and Biomolecular Engineering, Department of Chemistry, Department of Materials Science and Engineering, Beckman Institute for Advanced Science and Technology, University of Illinois Urbana-Champaign,Urbana, Illinois 61801, United States.
Spontaneous chiral symmetry breaking remains a fascination in chemistry, biology, materials science, and even astronomy. Chiral symmetry breaking usually requires intrinsic molecular chirality or extrinsic chiral sources but remains rare in nonchiral systems. Here, we reveal a ubiquitous, entropy-driven chiral symmetry breaking mechanism observed in 22 out of 35 conjugated polymers in the absence of any chiral source─a phenomenon overlooked for decades.
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