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A rapid and accurate photoalignment technique was proposed for the fabrication of liquid crystal Pancharatnam-Berry phase diffractive optical elements (LC PB-DOEs). The in-plane orientation of LCs was precisely manipulated through the polarized illumination of an optimized liquid crystal on silicon (LCOS) device. LCOS and thereafter spatial light modulator (SLM) can generate polarization patterns at pixel level at will. The quality of such alignment was improved significantly by minimizing the phase flicker of the phase-only LCOS SLM. This was confirmed by the increase of the measured quality of the holographic images reconstructed using our DOE in terms of structural similarity (SSIM) and peak signal-to-noise ratio (PSNR) at 30% and 5%, respectively. Furthermore, a bi-focal LC PB-lens was fabricated and used as a high quality Fourier lens in holographic display to validate the usefulness of such LC PB-DOEs. This work illustrated a ubiquitous approach of fabricating different types of lightweight and thin form factor DOEs of random phase patterns at pixel level with low cost and high throughput.
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http://dx.doi.org/10.1364/AO.539986 | DOI Listing |
Adv Sci (Weinh)
September 2025
Department Chemie- und Bioingenieurwesen, Lehrstuhl für Chemische Reaktionstechnik (CRT), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Egerlandstr. 3, 91058, Erlangen, Germany.
The supported catalytically active liquid metal solution (SCALMS) concept is based on catalytically active metals dissolved in a low-melting-point liquid metal matrix. These solid alloy particles, deposited over a high area support, transform into a liquid alloy under reaction conditions. In this work, GaPt SCALMS materials of varying composition are investigated and focus on the change in the alloy composition during preheating, the actual high temperature propane dehydrogenation at 823 K, and after cool-down.
View Article and Find Full Text PDFDalton Trans
September 2025
Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 87-100 Toruń, Poland.
This study comprehensively analyses two new ruthenium(III) complexes, [RuCl(Nic)][(CH)NH]DMF, 1, and [RuCl(3-HPA)][3-HHPA](EtOH), 2, (where Nic = nicotinic acid (vitamin B3), 3-HPA = anion of a 3-hydroxypicolinic acid), as potential antimicrobial agents, highlighting their physicochemical properties, nanoparticle formation, and cytotoxic activity. The complexes were fully characterised by a single crystal X-ray diffraction technique, Fourier-transform infrared, energy-dispersive X-ray, and electron paramagnetic resonance spectroscopies. The synthesis of micro- and nanoparticles (NPs) of these complexes was performed using the liquid anti-solvent crystallisation method.
View Article and Find Full Text PDFLangmuir
September 2025
College of Petroleum Engineering, Liaoning Petrochemical University, Fushun 113001, Liaoning, China.
In recent years, amino acids have garnered extensive attention as environmentally friendly, small-dose additives for modulating hydrate formation and aggregation behavior. Amino acids, due to their amphiphilic nature, can adsorb at the gas-liquid interface and on hydrate crystal surfaces, thereby modifying interfacial properties and influencing crystal growth patterns. In our measurements, the amino acids displayed a concentration-dependent "double effect".
View Article and Find Full Text PDFNat Commun
September 2025
Center for Advancing Electronics Dresden & Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Dresden, Germany.
The synthesis of thin crystalline two-dimensional polymers (2DPs) typically relies on reversible dynamic covalent reactions. While substantial progress has been made in solution-based and interfacial syntheses, achieving 2DPs through irreversible carbon-carbon coupling reactions remains a formidable challenge. Herein, we present an on-liquid surface (a mixture of N,N-dimethylacetamide and water, DMAc-HO) synthesis method for constructing diyne-linked 2DP (DY2DP) crystals via Glaser coupling, assisted by a perfluoro-surfactant (PFS) monolayer.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
September 2025
Department of Materials Science and Engineering, City University of Hong Kong, Kowloon, Hong Kong 999077, China.
Solid-state electrolytes (SSEs) are being extensively researched as replacements for liquid electrolytes in future batteries. Despite significant advancements, there are still challenges in using SSEs, particularly in extreme conditions. This study presents a hydrated metal-organic ionic cocrystal (HMIC) solid-state ion conductor with a solvent-assisted ion transport mechanism suitable for extreme operating conditions.
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