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A quantum spin liquid (QSL) is an exotic insulating phase with emergent gauge fields and fractionalized excitations. However, the unambiguous demonstration of the existence of a QSL in a "nonengineered" microscopic model (or in any material) remains challenging. Here, using numerically exact sign-problem-free quantum Monte Carlo simulations, we show that a QSL arises in a nonengineered electron-phonon model. Specifically, we investigate the ground-state phase diagram of the bond Su-Schrieffer-Heeger model on a 2D triangular lattice at (one electron per site), which we show includes a QSL phase which is fully gapped, exhibits no symmetry-breaking order, and supports deconfined fractionalized holon excitations. This suggests promising routes for finding QSLs in realistic materials and high- superconductivity by lightly doping them.
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http://dx.doi.org/10.1073/pnas.2426111122 | DOI Listing |
Nano Lett
September 2025
Key Laboratory of Micro & Nano Photonic Structures, Department of Optical Science and Engineering, College of Future Information Technology, Fudan University, Shanghai 200433, China.
The separation and propagation of spin are vital to understanding spin-orbit coupling (SOC) in quantum systems. Exciton-polaritons, hybrid light-matter quasiparticles, offer a promising platform for investigating SOC in quantum fluids. By utilization of the optical anisotropy of materials, Rashba-Dresselhaus SOC (RDSOC) can be generated, enabling robust polariton spin transport.
View Article and Find Full Text PDFJ Chem Phys
September 2025
Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA.
We present a self-consistent algorithm for optimal control simulations of many-body quantum systems. The algorithm features a two-step synergism that combines discrete real-time machine learning (DRTL) with Quantum Optimal Control Theory (QOCT) using the time-dependent Schrödinger equation. Specifically, in step (1), DRTL is employed to identify a compact working space (i.
View Article and Find Full Text PDFChem Sci
August 2025
School of Physics, Nanjing University of Science and Technology Nanjing 210094 China
The role of electronic spin in electrocatalysis has led to the emerging field of "spin-dependent electrocatalysis". While spin effects in individual active sites have been well understood, spin coupling among multiple sites remains underexplored in electrocatalysis, which will bring forth new active sites and mechanisms. In this work, we propose a general theory to understand the spin coupling in electrocatalysis.
View Article and Find Full Text PDFMagn Reson Lett
November 2024
Sorbonne Université, CNRS, Laboratoire de Chimie de la Matière Condensée de Paris, LCMCP, UMR 7574, 75005 Paris, France.
Elastomer blends, among which natural rubber (NR) and butadiene rubber (BR), are involved in many components of the automotive/tire industry. A comprehensive understanding of their mechanical behavior requires, among other features, a detailed description of the cross-link density in these mixtures. In the case of vulcanized immiscible blends, the distribution of the cross-link density within each of the NR- and BR-rich domains is key information, but difficult to determine using the conventional approaches used for one-component cross-linked elastomers.
View Article and Find Full Text PDFJ Chem Theory Comput
September 2025
School of Materials, Sun Yat-sen University, Shenzhen, Guangdong 518107, China.
Simulating non-Markovian open quantum dynamics is crucial for understanding complex quantum systems, yet it poses significant challenges for standard quantum hardware. These challenges stem from the non-Hermitian nature of such dynamics, which results in nonunitary evolution, as well as constraints imposed by limited quantum resources. To address this, we propose a hybrid quantum-classical algorithm designed for simulating dissipative dynamics in systems coupled to non-Markovian environments.
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