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This paper presents a dual-objective optimization method to tackle the low diffraction efficiency and high angular sensitivity of traditional double-layer diffractive optical elements (DLDOEs) in broadband and wide-angle scenarios. By developing a mean-standard deviation dual-objective diffraction efficiency evaluation model (MSDODE) and incorporating material library matching constraints based on dispersion characteristics, we achieve a globally coordinated optimization of DLDOE substrate material selection and microstructure height. The optimized design attains an average diffraction efficiency of 0.9614 within the 0.4∼1.0μm wavelength range and 0∼30° incident angle range, outperforming conventional designs. The average diffraction efficiency at 30° decreases by a mere 0.08% compared to that at 0°. When applied to a wide-spectrum annular-aperture lens (AFL) system, the design demonstrates excellent chromatic aberration correction, with the system modulation transfer function (MTF) exceeding 0.36 at 166lp/mm. The average MTF reduction due to diffraction efficiency impact is minimal, at just 0.045%.
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http://dx.doi.org/10.1364/OE.567140 | DOI Listing |
Environ Monit Assess
September 2025
School of Geological Survey, China University of Geosciences, Wuhan, 430074, China.
Cadmium (Cd) contamination in water poses a critical global challenge. A novel nanocomposite, montmorillonite (Mt)-supported nanoscale zero-valent iron (Mt-nZVI), synthesized by liquid phase reduction, offers a promising method for effectively removing Cd. The material underwent characterization through various techniques, including X-ray diffraction (XRD) and Scanning Electron Microscope(SEM).
View Article and Find Full Text PDFChemosphere
September 2025
Department of Materials Design and Innovation, University at Buffalo, NY, 14260, USA. Electronic address:
Bioremediation offers a sustainable strategy for mitigating heavy metal contamination in soil, but is often constrained by slow removal kinetics, limited uptake efficiency, and high implementation costs. This study investigates dried mycelium membranes, rich in surface-bound proteins and high surface area, as a promising biosorbent for in situ Pb(II) remediation in urban soils. Untreated mycelium membranes buried in soil achieved Pb(II) removal efficiencies of ∼70 % and ∼40 % at initial lead soil concentrations of 100 mg/kg and 1500 mg/kg, respectively, within eight days.
View Article and Find Full Text PDFDalton Trans
September 2025
Department of Chemistry, Jadavpur University, Kolkata - 700032, India.
An interesting ruthenium(III) complex, -[Ru(HL)Cl(PPh)], has been synthesized using a redox-active tetradentate bis-azo diamine ligand (HL). This complex represents the first example of a structurally robust, air- and moisture-stable coordination compound featuring a redox non-innocent ligand that provides a unique N4 donor set comprising both strong π-acidic (azo) and σ-donating (amido) groups. The complex has been comprehensively characterized by elemental analysis, various spectroscopic techniques, and single-crystal X-ray diffraction (SCXRD) studies.
View Article and Find Full Text PDFPest Manag Sci
September 2025
Department of Chemistry, Northeast Agricultural University, Harbin, China.
Background: Diniconazole (DCZ) is a poorly water-soluble triazole fungicide. However, the water solubility of DCZ can be significantly enhanced by inclusion complexation with cyclodextrins. In order to improve the properties and bioavailability of pesticide fungicides DCZ, a new system of nanofibers was prepared by electrospinning and cyclodextrin encapsulation.
View Article and Find Full Text PDFFood Res Int
November 2025
School of Pharmacy, Jiangsu University, Zhenjiang 212013, People's Republic of China; School of Food and Biological Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China. Electronic address:
Intense pulsed light (IPL) is an emerging surface antimicrobial technology characterized by prominent efficiency but the performance in the decontamination of granular foods is yet to be improved. Using S. Enteritidis as a model bacterium, this article attempted to resolve the confusion on bactericidal mechanism of IPL treatment on spice products.
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