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Five-axis sweep scanning measurement technology, as a novel contact measurement technology, offers excellent reachability and high measurement efficiency for complex parts. However, deviations between the measurement instructions based on the model and the workpiece exist, leading to mismatches between the intended and actual sweep scanning areas, which manifest as displacements of the scanning boundaries and subsequently impact the acquisition of sampling points. When these sampling points are utilized to evaluate the machining quality of workpieces, the accuracy and reliability of the assessment results are compromised. Therefore, by focusing on the phenomenon of boundary displacement in a five-axis sweep scanning measurement, the sampling principle has been analyzed, the constrained sector for the probe tip trajectory in a five-axis scanning measurement has been defined, and the concept of the trajectory constrained sector effect has been proposed for the first time. The constrained sector effect reveals how deviations affect the scanning boundary positions and acquisition of sampling points. Based on the constrained sector effect, the influence of deviations on boundary displacement and sampling point acquisition in single-patch and multiple-patch measurement scenarios is discussed. Furthermore, practical engineering recommendations are provided, aiming to reduce the impact of deviations on the completeness of sampling point acquisition.
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http://dx.doi.org/10.3390/mi16070759 | DOI Listing |
Phys Chem Chem Phys
September 2025
China-UK Low Carbon College, Shanghai Jiao Tong University, Shanghai 200240, China.
Accurate evaluation of oxygen reduction reaction (ORR) catalysts, especially transition metal oxides, requires careful control of testing parameters. Here, we report a potential-window-dependent ORR activity for spinel manganese ferrite (MnFeO). The ORR activity exhibits a volcano-shaped dependence on the lower potential limit during cathodic scans.
View Article and Find Full Text PDFGels
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College of Notoginseng Medicine and Pharmacy, Wenshan University, Wenshan 663099, China.
Notoginsenoside Rb1 (Rb1), a bioactive saponin from exerts cardio-cerebrovascular protective, anti-inflammatory, antioxidant, and glucose homeostasis-regulating effects. However, its oral bioavailability is limited by gastric degradation and poor intestinal permeability. This study presents a food-grade bigel system for encapsulating Rb1 to enhance its stability and controlled-release performance.
View Article and Find Full Text PDFBMC Chem
August 2025
Faculty of Science, Department of Chemistry-Giza, Cairo University, Giza, Egypt.
The development of low-cost, efficient and stable electrocatalysts for oxygen reduction reaction is critical for advancing energy conversion and storage technologies. The oxygen reduction reaction (ORR) is a key electrochemical process in energy conversion systems, particularly in fuel cells, where it governs the overall efficiency of the device. This study explores the electrochemical performance of a novel carbon paste electrode (CPE) modified with silica fume (SF), polyaniline (PANi), and iron nanoparticles (FeNPs) for potential application in fuel cells and supercapacitors.
View Article and Find Full Text PDFCommun Biol
August 2025
Sanya Institute, Hainan Academy of Agricultural Sciences, Sanya, China.
Durio zibethinus Murr. is a tropical fruit crop of growing global importance, prized for its unique flavor and nutritional value. Yet only a narrow genetic base has been utilized in breeding efforts.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
August 2025
Molecular Science Institute, School of Chemistry, University of the Witwatersrand, Johannesburg 2050, South Africa.
This study investigated the electrocatalytic performance of Pd-based catalysts supported on onion-like carbon (OLC) for isopropanol (IPA) oxidation in alkaline media (a direct isopropanol fuel cells (DIFC)). The synthesized and evaluated catalysts included PdNi/OLC, Pd/CeO/OLC, and PdNi/CeO/OLC, all of which demonstrated performances comparable to that of commercial Pd/C. These samples are characterized by physicochemical analytical methods such as X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) coupled with energy-dispersive X-ray (EDX), high resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS).
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