98%
921
2 minutes
20
Based on the demand of marine soft clay treatment, it is still urgent to seek green cementitious materials. Meanwhile, knowledge gaps exist regarding the application of waste tile powder (WTP)-calcium carbide residue (CCR) geopolymer into marine soft clay. This research explores the mechanical properties and freeze-thaw durability of WTP-clay-CCR system. Experimental results of unconfined compressive strength demonstrate that the strength is 1832.77 kPa after the incorporation of 13% CCR and 15% WTP. However, it is reduced to 474.69 kPa after 4 freeze-thaw cycles. The stability index (SI) is 0.422 after 2 freeze-thaw cycles but it is improved after the incorporation of CCR and WTP. The strength calculation model containing freeze-thaw cycles is proposed. The failure strain of sample is 1.0-2.0%. The peak strain energy and secant modulus are 18.53 kJ/m and 138.44 MPa after the incorporation of 13% CCR and 18% WTP. Finally, the pore characteristics and microstructure are revealed by scanning electron microscope and mercury intrusion porosimetry tests. The stabilization and freeze-thaw mechanism are analyzed. It reveals that the pore filling, gelling material and ion exchange are responsible for the mechanical property improvement. The micro-cracks formation and cracks development result in strength reduction of CCR-WTP-clay under freeze-thaw cycles.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC12214496 | PMC |
http://dx.doi.org/10.1038/s41598-025-05980-4 | DOI Listing |
Int J Biol Macromol
September 2025
College of Pharmacy, Guangxi University of Chinese Medicine, Nanning 530200, China. Electronic address:
Conductive hydrogels have emerged as promising materials for flexible wearable electronics; however, their facile fabrication remains challenging. This study presents an antifreeze, antibacterial, and conductive hydrogel constructed from biomacromolecules sodium carboxymethylcellulose (CMCNa) and polyvinyl alcohol (PVA). The hydrogel was synthesized via a simple one-pot method in an ethylene glycol/water (EG/H₂O) binary solvent system, incorporating lithium chloride (LiCl) and clove essential oil (CEO), followed by a single freeze-thaw cycle.
View Article and Find Full Text PDFFood Chem
September 2025
The Engineering Technological Center of Mushroom Industry, School of Biological Science and Biotechnology, Minnan Normal University, Zhangzhou 363000, PR China; Food Science Research Institute of Zhangzhou, Minnan Normal University, Zhangzhou 363000, China. Electronic address:
An ultra-low temperature (-5 °C) enzymatic method was employed to prepare glycine-amidated pectin (Gly-Pe) and evaluate its physicochemical properties and freeze-thaw protection mechanism in surimi. After glycine grafting (12.77 %), amide bonds disrupted pectin's crystalline structure and enhanced molecular chain flexibility.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
September 2025
Civil and Environmental Engineering Department, King Fahd University of Petroleum & Minerals, 31261, Dhahran, Saudi Arabia.
Concrete production significantly contributes to CO emissions and depletion of natural resources, leading to substantial environmental concerns. The integration of polymers into concrete has emerged as a promising innovative solution aimed at overcoming inherent limitations of traditional concrete, including brittleness, susceptibility to tracking, environmental degradation, and substantial ecological impacts. This systematic review thoroughly investigates the properties, sustainability implications, and practical challenges associated with polymer-based concrete (PBC), particularly focusing on polymer concrete composites (PCC) and polymer-modified concrete (PMC) detailing their composition, mechanical behavior, and durability.
View Article and Find Full Text PDFBioorg Med Chem Lett
September 2025
Department of Chemistry, Taras Shevchenko National University of Kyiv, Kyiv 01601, Ukraine. Electronic address:
Phospholipid-derived nanocarriers represent a versatile and chemically customizable class of drug delivery systems that self-assemble into bilayered vesicles due to their intrinsic amphiphilicity. These systems can encapsulate both hydrophilic and hydrophobic drugs through non-covalent interactions and manipulation of lipid phase behavior. This review examines the molecular and supramolecular principles underlying the formation, stability, and functional performance of key phospholipid-based nanocarriers-including liposomes, transferosomes, ethosomes, invasomes, phytosomes, pharmacosomes, and virosomes.
View Article and Find Full Text PDFWater Res
September 2025
State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, PR China. Electronic address:
Freezing enhancing the photochemistry of dissolved organic matter (DOM), yet the mechanism of reactive intermediate (RIs) generation influenced by DOM property and structure remain elusive. Here, we demonstrate that freezing induces exceptional amplification of RIs, with steady-state concentrations in ice (-10 °C) surpassing aqueous solutions by 5-41 times. Laser scanning confocal microscopy first visualized cryo-concentration of DOM and RIs in liquid-like regions (LLR).
View Article and Find Full Text PDF