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Reflective metasurfaces (RMs) have gained significant attention in optics and electromagnetism for their ability to redirect signals to customized angles, offering cost- and energy-efficient solutions to line-of-sight (LoS) blockages. However, existing RM technologies predominantly rely on metallic ground planes for efficient beam reflection, which imposes several critical limitations, such as restricted angle range and increased dielectric losses. In this work, we develop an innovative approach that eliminates dependence on metallic ground planes. We introduce an open-edge loop structure as the unit cell, where the gap between the loop edges facilitates phase variation while maintaining high reflectivity. Three distinct yet representative open-edge loop-based RMs were examined under varying incidence and reflection angles. Notably, our developed RMs can function as a "wave bender", the first of its kind, capable of transforming an incident wave into an endfire reflected beam (θ = 90°). They achieve a directivity improvement of around 5 dBi in comparison with conventional ground-based designs. Experimental verification confirms beam reflection at the simulated angles in a wide operating bandwidth from 26 to 33 GHz. This work represents the first demonstration of high-performance beam reflection for RMs without reliance on a metallic ground plane.
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http://dx.doi.org/10.1021/acsami.5c06152 | DOI Listing |
Phys Chem Chem Phys
September 2025
Departamento de Física, Universidad Técnica Federico Santa María, Av. España 1680, Casilla 110V, Valparaíso, Chile.
Reversible control of spin-dependent thermoelectricity mechanical strain provides a platform for next-generation energy harvesting and thermal logic circuits. Using first-principles and Boltzmann transport calculations, we demonstrate that monolayer NiI undergoes a strain-driven semiconductor-to-half-metal transition, enabled by the selective closure of its spin-down band gap while preserving a robust ferromagnetic ground state. Remarkably, this transition is accompanied by a giant, non-monotonic violation of the Wiedemann-Franz law, with the Lorenz number enhanced up to 7.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
Institution Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA Nanoscience), Madrid, 28049, Spain.
Achieving magnetic ordering in low-dimensional materials remains a key objective in the field of magnetism. Herein, coordination chemistry emerges as a powerful discipline to promote the stabilization of magnetism at the nanoscale. We present a thorough study of exemplary two-dimensional metal-organic nanoarchitectures synthesized on a Au(111) substrate, which are rationalized by using surface-science techniques and theoretical calculations.
View Article and Find Full Text PDFPhys Rev Lett
August 2025
University of Alberta, Department of Physics, Edmonton, Alberta T6G 2E1, Canada.
Hyperbolic lattices present a unique opportunity to venture beyond the conventional paradigm of crystalline many-body physics and explore correlated phenomena in negatively curved space. As a theoretical benchmark for such investigations, we extend Kitaev's spin-1/2 honeycomb model to hyperbolic lattices and exploit their non-Euclidean space-group symmetries to solve the model exactly. We elucidate the ground-state phase diagram on the {8,3} lattice and find a gapped Z_{2} spin liquid with Abelian anyons, a gapped chiral spin liquid with non-Abelian anyons and chiral edge states, and a Majorana metal whose finite low-energy density of states is dominated by non-Abelian Bloch states.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2025
Institute of Theoretical Chemistry, Faculty of Chemistry, University of Vienna, Währinger Str. 17, Vienna, 1090, Austria.
Density functional theory (DFT) is the standard approach for modeling MIL-101(Fe) and related Fe-based metal-organic frameworks, typically assuming a ferromagnetic high-spin configuration. However, this widely adopted approach overlooks a key electronic feature: Spin frustration in the triangular -O) nodes. Using flip-spin, broken-symmetry DFT, we identify the true ground state as an antiferromagnetic state that standard DFT fails to capture.
View Article and Find Full Text PDFJ Phys Chem A
September 2025
Department of Chemistry, University of Utah, Salt Lake City, Utah 84112-0850, United States.
Resonant three-photon ionization spectroscopy has been used to study the late 4d and 5d transition metal carbides RuC, RhC, OsC, IrC, and PtC. These species, like most diatomic transition metals with open nd subshells, exhibit an exceptionally high density of states near the ground separated atom limit. Spin-orbit and nonadiabatic interactions provide a means for the molecules to rapidly dissociate as soon as the bond dissociation energy (BDE) is exceeded.
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