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Superlubricity holds transformative potential for alleviating the global energy and environmental crisis. While liquid superlubricity has made considerable advancements over the past 30 years, a significant gap remains in realizing industrial applications. This review examines the most recent developments in liquid superlubricity, emphasizing the various liquid superlubricity systems and their mechanisms for achieving superlubricity. The breakthroughs of liquid superlubricity are explicated according to the different types of lubricants; particularly, the discussion on oil-based lubricants is underscored concerning their varying molecular structures. A comprehensive review of mechanisms is presented with the integration of novel findings from recent years, including molecular dependence superlubricity, graphene-like superlubricity, and solid-like superlubricity. The constructive ideas to overcome the limitations of liquid superlubricity are proposed, aimed at promoting the development of liquid superlubricity beyond the laboratory and further contributing to the prosperity of green tribology.
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http://dx.doi.org/10.1016/j.cis.2025.103585 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China.
Near-zero wear on engineering steel surfaces is a promising solution to extend the service life of mechanical equipment. However, most existing strategies offer only limited low wear under particular conditions and friction pairs. To address this, we design a polymer-based proton ionic liquid (PPILs) lubricant, leveraging the proton exchange between polyethylenimine, which is rich in active nitrogen groups, and bis(2-ethylhexyl) phosphate.
View Article and Find Full Text PDFAdv Colloid Interface Sci
October 2025
State Key Laboratory of Tribology in Advanced Equipment, Tsinghua University, Beijing 100084, China.
Superlubricity holds transformative potential for alleviating the global energy and environmental crisis. While liquid superlubricity has made considerable advancements over the past 30 years, a significant gap remains in realizing industrial applications. This review examines the most recent developments in liquid superlubricity, emphasizing the various liquid superlubricity systems and their mechanisms for achieving superlubricity.
View Article and Find Full Text PDFLangmuir
July 2025
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China.
Carbon-based coatings combined with ricinoleic acid exhibit exceptional lubrication and macroscale superlubricity, yet the influence of the water content remains insufficiently explored. In this paper, a tungsten-doped amorphous carbon coating/ricinoleic acid composite system was prepared, and superlubricity was achieved by controlling the water content in ricinoleic acid. When the water content is 13.
View Article and Find Full Text PDFPolymers (Basel)
May 2025
School of Materials Science and Engineering, Hubei University, Wuhan 430062, China.
Poly-ether-ether-ketone (PEEK) is widely used in dynamic sealing applications due to its excellent properties. However, its tribological performance as a sealing material still has limitations, as its relatively high friction coefficient may lead to increased wear of sealing components, affecting sealing effectiveness and service life. To optimize its lubrication performance, this study employs surface modification techniques to synthesize a thin polyimide (PI) film on the surface of PEEK.
View Article and Find Full Text PDFNano Lett
June 2025
Beijing Key Laboratory of Solid State Battery and Energy Storage Process, State Key Laboratory of Mesoscience and Engineering, CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China.
Superlubricity, a state of near-zero friction, offers transformative potential for minimizing energy dissipation and mechanical wear. However, realizing stable superlubricity has remained challenging due to difficulties in sustaining reliable lubricant structures. In this work, we present a feasible and straightforward strategy that integrates ionic liquids with trace amounts of low-surface-energy perfluorocarbon, yielding a robust and highly ordered monolayer film.
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