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Quantum dots (QDs), with the unique merits of narrow and tunable photoluminescence (PL) wavelength, high PL quantum yield, have gained significant interest in fields such as display, solar energy conversion, bioimaging, and encrypted quantum communication. On the other hand, photochromic molecular switches (PMS) can undergo reversible interconversion between (at least) two distinct states at the molecular scale upon light irradiation. When combining QDs and PMS, the resulting hybrid systems exhibit synergistic functionalities and light responsiveness, enabling precise and reversible modulation over PL intensity/color, energy/electron transfer, and motion with high temporal and spatial resolution in a non-invasive manner. This perspective explores the recent advancements in the combination method, light-responsive mechanism, and functions of QD-PMS hybrids. The applications of QD-PMS hybrids are also highlighted as light-responsive materials in bioimaging, information processing, sensing, optoelectrical devices, and discuss future challenges, opportunities, and directions for enhancing performance and exploring applications in next-generation light-responsive materials and smart optoelectronic devices.
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http://dx.doi.org/10.1002/smtd.202500192 | DOI Listing |
Chem Sci
August 2025
State Key Laboratory of Antiviral Drugs, Pingyuan Laboratory, NMPA Key Laboratory for Research and Evaluation of Innovative Drug, School of Chemistry and Chemical Engineering, Henan Normal University 46 Jianshe Road Xinxiang 453007 China +86
The construction of polymer-based photoactivated room-temperature phosphorescence systems remains a prominent research focus, yet the development of ultrafast activated systems under ambient conditions continues to pose a challenge. In this study, cyclized phenothiazine derivatives bearing diverse substituents are synthesized and incorporated into an amorphous polyvinyl alcohol (PVA) matrix, resulting in significantly enhanced dynamic photoactivation characteristics compared with those of their pristine monomeric counterparts. Under ambient conditions and 2 s irradiation, the lifetime and quantum yield of C[4]PTZ-OH@PVA increase by factors of 1.
View Article and Find Full Text PDFCarbohydr Polym
November 2025
Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, Joint International Research Lab of Lignocellulosic Functional Materials, College of Materials Science and Engineering, Nanjing Forestry University, N
Hydrogel actuators show tremendous promise for applications in soft robots and artificial muscles. Nevertheless, developing a stretchable hydrogel actuator combining remote actuation and real-time signal feedback remains a challenge. Herein, a light-responsive hydrogel actuator with self-sensing function is fabricated by employing a localized immersion strategy to incorporate polyacrylamide (PAM) hydrogel network into semi-interpenetrating carbon nanotube/2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-oxidized cellulose nanofiber/poly(N-isopropylacrylamide) (CNT/TOCN/PNIPAM) hydrogel.
View Article and Find Full Text PDFLangmuir
September 2025
Department of Chemistry and Chemical Biology, IIT (ISM), Dhanbad 826004, Jharkhand, India.
The understanding of light-mediated control in advanced materials critically depends on the deployment of highly efficient azobenzene-based photoswitches. A key challenge lies in optimizing their light reactivity and developing water-soluble variants that can function as hydrogel cross-linkers. This study represents the design and synthesis of a water-soluble, cationic azobenzene derivative, which serves as a versatile cross-linker to develop a photoresponsive azobenzene composed of sodium salt of poly-2-acrylamido-2-methylpropanesulfonic acid-based [Azo(+)@pSAMPS(-)] hydrogels.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2025
Department of Applied Biology and Chemical Technology, Research Institute for Future Food, The Hong Kong Polytechnic University, Hong Kong, China; Centre for Eye and Vision Research, 17W Hong Kong Science Park, Hong Kong, China. Electronic address:
Synthetic aqueous supramolecular assemblies mimic the natural biomolecular functions. One of the key material advancements of aqueous supramolecular assemblies is constructing life-like macroscopic materials with photoresponsive molecules via supramolecular strategies. Visible-light controlled indigoid-based aqueous supramolecular assemblies have been reported, but the photocontrolled robotic function and the hydrolytic stability of indigoid systems remain unexplored.
View Article and Find Full Text PDFNat Commun
August 2025
Max Planck Institute for Medical Research, Heidelberg, Germany.
The ability to dynamically shape ultrasound fields is critical for emerging applications in therapeutic ultrasound, particle manipulation and tissue engineering. While existing phased arrays provide beam steering for imaging, these newer applications require higher intensities. This complicates the electrical driving and ultimately limits the array size and spatial complexity of the field.
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