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Colloidal crystals reflecting interference-based structural colors have been reported in many organisms, but many are yet to be accurately described. Herein, the bright, iridescent scales of green and blue beetles are investigated using optical and ultrastructural techniques. The ultrastructural studies based on focused ion-beam scanning electron microscopy and synchrotron small-angle X-ray scattering data reveal the origin of the colors to stem from previously undocumented hexagonal-close-packed colloidal crystals within their scales. The optical properties of various colloidal structures are investigated using full-wave optical simulations. The results highlight the need for further research regarding the development of structural color in beetles.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11935839 | PMC |
http://dx.doi.org/10.1002/smsc.202200114 | DOI Listing |
Angew Chem Int Ed Engl
September 2025
Shaanxi Key Laboratory of New Concept Sensors and Molecular Materials, Key Laboratory of Applied Surface and Colloids Chemistry, Department of Chemistry and Chemical Engineering, ShaanXi Normal University, Xi'an, 710062, P.R. China.
Rhodamine derivatives exhibiting inverted open-closed form fluorescence behavior redefines conventional photochemical paradigms while illuminating new structure-property relationships and fascinating application potentials. Herein, we report a donor-acceptor engineering strategy that activates closed form emission in rhodamines, achieving unprecedented Stokes shifts (>280 nm) while overcoming aggregation-caused quenching. The new class of rhodamines with inverted open-close form emission behavior are created through simultaneous substitution of N,N-diethyl groups with indole (donor) and conversion of spiro-lactam to benzene sulfonamide (acceptor).
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650093, China.
Encapsulation of non-noble bimetallic nanoparticles within a zeolite framework can improve the stability and accessibility of active sites, but the single microporous structure and poor metal stability decreased the catalytic performance of the catalyst. Here, 3D hierarchical ZSM-5 zeolite encapsulated NiCo nanoparticles (NiCo@3DHZ5) were synthesized by Bottom-up confined steam-assisted crystallization (SAC) one-pot hydrothermal method and applied to the hydrodeoxygenation of vanillin. A series of characterizations showed that highly stable alloyed NiCo nanoparticles were encapsulated in a framework of 3DHZ5, the strong metal-zeolite interactions resulted in highly dispersed NiCo nano-alloys facilitated hydrogen adsorption and spillover of active hydrogen atoms, and the 3D hierarchical structure promoted oxygenated substrate diffusion, the synergy interaction between the alloy particles confined in the 3DHZ5 pores and the acidic sites on the zeolite surface promoted the selective conversion of vanillin.
View Article and Find Full Text PDFLangmuir
September 2025
Federal University of São Paulo, Laboratory of Hybrid Materials, Diadema, São Paulo 09913-030, Brazil.
This study demonstrates the successful fabrication of nanostructured Langmuir-Blodgett (LB) films combining the conjugated copolymer poly(9,9-dioctylfluorene--3,4-ethylenedioxythiophene) (PDOF--PEDOT) with spherical and triangular silver nanoparticles (AgNP). The LB technique allowed precise control over the molecular arrangement and distribution of the nanoparticles at the air-water interface, resulting in compact, reproducible and structurally ordered nanocomposite films. The structural and morphological properties of the interfacial monolayers and LB films were investigated using surface pressure-area isotherms, Brewster angle microscopy, polarization modulation infrared reflection-absorption spectroscopy (PM-IRRAS) and quartz crystal microbalance.
View Article and Find Full Text PDFDalton Trans
September 2025
Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 87-100 Toruń, Poland.
This study comprehensively analyses two new ruthenium(III) complexes, [RuCl(Nic)][(CH)NH]DMF, 1, and [RuCl(3-HPA)][3-HHPA](EtOH), 2, (where Nic = nicotinic acid (vitamin B3), 3-HPA = anion of a 3-hydroxypicolinic acid), as potential antimicrobial agents, highlighting their physicochemical properties, nanoparticle formation, and cytotoxic activity. The complexes were fully characterised by a single crystal X-ray diffraction technique, Fourier-transform infrared, energy-dispersive X-ray, and electron paramagnetic resonance spectroscopies. The synthesis of micro- and nanoparticles (NPs) of these complexes was performed using the liquid anti-solvent crystallisation method.
View Article and Find Full Text PDFFood Res Int
November 2025
Department of Food Science and Technology, College of Agricultural and Environmental Sciences, University of Georgia, Griffin, GA 30223, USA. Electronic address:
Turmeric-derived curcumin offers various health benefits but has poor bioavailability due to low water solubility and rapid gastrointestinal degradation. A recently proposed raw-to-nano strategy enables the direct formulation of turmeric nanoparticles from raw turmeric, using inherent biopolymers to encapsulate and protect curcumin. However, it remains unclear how these nanoparticles enhance gastrointestinal bioavailability and how food matrices influence this process.
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