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In this paper, a vanadium dioxide (VO)-based terahertz device is proposed to realize the conversion between broadband absorption and broadband transmission functions, including the VO bottom layer, dielectric layer and VO pattern layer in a three-layer structure. With the change of the VO conductivity, the terahertz metamaterial device can switch between broadband absorption and broadband transmission. When the device exhibits broadband transmission, it has a high transmittance of 90% for terahertz waves in the 5.6 THz to 8.7 THz frequency band. When the device exhibits broadband absorption, it has a high 90% absorption of terahertz waves in the 3.66 THz to 9.98 THz frequency band. Furthermore, with increasing VO conductivity, the peak transmittance of the device decreases from 93.8% to 0% and the absorption increases from 1% to 99.5%. The impedance matching theory is invoked and the physical mechanism of the device is elucidated by analyzing the surface electric field of the device. By studying the absorption characteristics for different incidence and polarization angles, the device is insensitive to polarization and has good absorption performance over large incidence angles. Compared with other absorbers of terahertz metamaterials, the device structure proposed in this study has a unique design and diverse functions and can play an important role in various fields such as communications, electromagnetic stealth, sensors, and thermal emission devices.
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http://dx.doi.org/10.1039/d5dt00153f | DOI Listing |
Chemistry
September 2025
Julius-Maximilians-Universität Würzburg, Institut für Organische Chemie, Würzburg, 97074, Germany.
Photosensitization has emerged as a versatile tool to facilitate access to excited states under mild conditions, allowing for efficient and selective photochemical transformations. Herein, we report a very simple molecule, coronene bisimide (CBI), as a potent visible-light photosensitizer featuring a high extinction coefficient with a broadband absorption spanning from ultraviolet to green region of the visible spectrum, along with a long-lived triplet state generated via efficient intersystem crossing (ISC). Utilizing the triplet-triplet energy transfer (TTEnT) strategy, CBI catalyzes diverse reactions under green light irradiation.
View Article and Find Full Text PDFLangmuir
September 2025
Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson AFB, Dayton, Ohio 45433, United States.
Aluminum nanoparticles (Al NPs) were synthesized via catalyzed thermal reduction of an aluminum precursor in the presence of a capping ligand. A systematic study was conducted to examine the effect of dilution on nanoparticle synthesis by varying the volume of anhydrous toluene across four dilution factors while maintaining constant molar quantities of the aluminum precursor, catalyst, and ligand. This methodology is relevant for scale-up processes, where more dilute conditions can mitigate nanoparticle reactivity and enhance safety.
View Article and Find Full Text PDFACS Sens
September 2025
Department of Mechanical and Automation Engineering, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, 999077, China.
Detecting multicomponent gases over extensive concentration ranges with laser spectroscopy faces challenges of complex configurations, intricate spectral analysis, and reduced accuracy. Neural networks offer transformative potential for advancing laser spectroscopy by facilitating real-time optimization and automation of experimental processes. Here, we report a frequency-modulated continuous-wave (FMCW) spectroscopic system enhanced by a feedforward neural network (FNN) algorithm.
View Article and Find Full Text PDFNanoscale
September 2025
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing 210023, China.
As the demand for renewable energy continues to rise, developing efficient solar energy harvesting technologies has become increasingly important. In this paper, we propose a plasmon absorber utilizing nanocavity arrays to achieve ultra-broadband absorption of solar energy. The results show that the absorber achieves an average absorption rate of 95.
View Article and Find Full Text PDFSci Rep
September 2025
Faculty of Physics, University of Tabriz, Tabriz, 51665-163, Iran.
Recent advances in nanostructured photodetectors have enabled precise control over light absorption while minimizing photon losses. In this work, we demonstrate a plasmonic metamaterial absorber based on two-dimensional MXene (Ti₃C₂Tₓ) featuring geometrically tunable tetragram-shaped arrays. Through finite-difference time-domain (FDTD) simulations and structural optimization, we achieved over 90% photon absorption across the broadband spectral range of 1000-2500 nm, representing a significant enhancement in operational bandwidth.
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