Preparation and Modification of Silicalite-2 Membranes.

Silicalite-2 membranes were successfully prepared on tubular α-AlO supports by secondary hydrothermal synthesis, and the pervaporation performance of the membrane was evaluated by separation of a 5 wt% ethanol/HO mixture at 60 °C. The effects of templating agent content, water-silicon ratio and crystallization time on the separation performance of Silicalite-2 membranes were investigated. When the TBAOH/SiO and HO/SiO molar ratios of the precursor synthesis solution were 0.2 and 120, a dense Silicalite-2 membrane could be prepared on the surface of the tubular α-AlO support after 72 h. The silane coupling agent was utilized to treat the Silicalite-2 membranes, and the effects of silane coupling agent dosage on their properties were also explored. The pervaporation performance of the Silicalite-2 membrane was greatly improved with a 5.7 wt% trimethylchlorosilane (TMCS) solution and the flux and separation factor of the membrane reached 1.75 kg·m·h and 22 for separation of 5 wt% EtOH/HO at 60 °C, respectively.