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According to Noether's theorem, symmetries in a physical system are intertwined with conserved quantities. These symmetries often determine the system topology, which is made ever more complex with increased dimensionality. Quasicrystals have neither translational nor global rotational symmetry, yet they intrinsically inhabit a higher-dimensional space in which symmetry resurfaces. Here, we discovered topological charge vectors in four dimensions (4D) that govern the real-space topology of 2D quasicrystals and reveal their inherent conservation laws. We demonstrate control over the topology in pentagonal plasmonic quasilattices, mapped by both phase-resolved and time-domain near-field microscopy, showing that their temporal evolution continuously tunes the 2D projections of their distinct 4D topologies. Our work provides a route to experimentally probe the thermodynamic properties of quasicrystals and topological physics in 4D and above.
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http://dx.doi.org/10.1126/science.adt2495 | DOI Listing |
J Mol Graph Model
September 2025
Department of Physics, Patan Multiple Campus, Tribhuvan University, Patandhoka, Lalitpur, 44700, Bagmati, Nepal; Department of Physics, St. Xavier's College, Maitighar, Bagmati, 44600, Kathmandu, Nepal. Electronic address:
The bioactive organosulfur compound diallyl sulfide (DAS), found in garlic and onions, was analyzed using density functional theory (DFT). DAS exhibits antimicrobial and anticancer properties, making it a potential candidate for drug discovery. Geometry optimization revealed bond lengths and angles consistent with electron delocalization.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
State Key Laboratory of Advanced Fiber Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China. Electronic address:
Polyimide (PI) faces significant challenges in highly integrated and high-frequency electronic devices due to its inherently low thermal conductivity and relatively high dielectric constant (D). In this study, topologically micro-crosslinked PI films were synthesized by incorporating highly conjugated multi-amino polydiacetylene (MAPDA) into a fluorinated PI matrix. The unique alkene-alkyne alternating conjugated structure of MAPDA, combined with the strong electron-withdrawing trifluoromethyl groups in the matrix, promotes charge redistribution and reduces the dipole moment and polarizability.
View Article and Find Full Text PDFPhys Rev Lett
August 2025
Weizmann Institute of Science, Department of Physics of Complex Systems, Rehovot 761001, Israel.
The coupling of lasers plays an important role in a variety of research activities, from generating high-power lasers to investigating out-of-equilibrium coupled systems. This Letter presents our investigations of Hermitian coupling in arrays of lasers, where it is possible to control both the amplitude and phase of the coupling and generate artificial gauge fields. The Hermitian coupling is demonstrated in three laser array geometries: a square array of 100 lasers with controlled laser coupling for obtaining continuous control over the phase-locked state, a triangular array of 130 lasers with controlled chirality of the lasers, and a ring array of eight lasers with a controlled topological charge.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
University of Ljubljana, Faculty of Pharmacy, Aškerčeva 7, 1000, Ljubljana, Slovenia. Electronic address:
Monoclonal antibodies (mAb) have transformed modern medicine, offering targeted therapies for cancer, autoimmune disorders, and infectious diseases. To enhance patient convenience, subcutaneous administration is increasingly prioritized, requiring highly concentrated formulations. However, high viscosity of these formulations hinders manufacturability, injectability, and stability.
View Article and Find Full Text PDFChem Commun (Camb)
September 2025
Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Key Laboratory of Precision and Intelligent Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, China.
Solar-driven hydrogen peroxide (HO) production offers a green and sustainable alternative to the energy-intensive anthraquinone process, utilizing water and oxygen as feedstock and solar energy as the sole input. Covalent organic frameworks (COFs), owing to their well-defined crystalline structures and tunable electronic properties, have emerged as a compelling platform for photocatalytic HO synthesis. However, the efficiency of HO photosynthesis remains limited by sluggish charge separation and rapid carrier recombination.
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