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Yb:YAG thin disk lasers can deliver high average power, high-energy pulses of fundamental mode. To achieve spatially homogeneous spectral broadening of the pulses in a compact setup, we propose utilizing a thin-film compression (TFC) scheme following beam shaping via field mapping optics. In our proof-of-principle experiment, the pulse from a Yb:YAG laser was converted from a Gaussian beam to a nearly flat-top beam by a π-shaper. The spectral width of the pulse was broadened from 3.1 nm to 6.6 nm after accumulating nonlinear phase shift in a YAG crystal. This technique resulted in high spectral homogeneity and mitigated degradation of focusability typically observed after spectral broadening. We believe this approach offers a promising solution for the post-compression of high-energy Yb lasers within a compact setup.
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http://dx.doi.org/10.1364/OL.550055 | DOI Listing |
Phys Chem Chem Phys
September 2025
Nantes Université, CNRS, CEISAM UMR 6230, F-44000 Nantes, France.
Owing to their unique combination of magnetic and optical properties, luminescent polychlorinated radicals are promising candidates for advanced applications in both optoelectronics and quantum technologies. In this study, we employ the lineshape formalism within a computational protocol based on time-dependent density functional theory (TD-DFT) to investigate the excited-state properties of six representative members of this family presenting different sizes and excited-state characters. We explore a wide range of density functionals, applying or not the Tamm-Dancoff approximation (TDA), combined with different vibronic models, namely, the vertical gradient (VG), vertical Hessian (VH), and adiabatic Hessian (AH), as well as dipole moment expansions using the Franck-Condon (FC) and Herzberg-Teller (HT) approximations.
View Article and Find Full Text PDFACS Omega
August 2025
Chemical Pathology Department, Cairo University Hospital, Cairo University, Giza 12613, Egypt.
Hydrazono-[1,3,4]-thiadiazoles have a prominent position among the heterocyclic compounds due to their broadening aspects of biological activities. In the current study, a neoteric series of [1,3,4]-thiadiazoles tethered to alkoxyaryl hydrazone has been formulated via the treatment of methyl 2-[3-(pentyloxy)-benzylidene]-hydrazine-1-carbodithioate and hydrazonoyl chlorides in ethanolic solution under thermal conditions. DABCO, as an environmentally nontoxic material, was utilized as a superior basic catalyst for the latter reaction.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
September 2025
Molecular Physiology Laboratory, Pioneering Research Institute, RIKEN, Wako, Saitama 351-0198, Japan.
Digital bioanalysis enables highly sensitive detection of biomolecules at the single-molecule level, making it a widely used technique in biomedical research. However, conventional approaches typically rely on fluorescence detection of single-enzyme reactions, which limits molecular selectivity and the ability to analyze multiple targets simultaneously. To address these limitations, we developed a digital bioanalysis platform based on surface-enhanced Raman scattering spectroscopy and microchamber arrays decorated with silver nanoparticles.
View Article and Find Full Text PDFJ Chem Phys
September 2025
College of General Education, Chung-Ang University, Seoul 06973, South Korea.
Isotope-edited infrared (IR) spectroscopy is a powerful tool for probing site-specific structures and dynamics within proteins. However, the interpretation is often complicated by spectral congestion and environmental heterogeneity. In this study, vibrational exciton models combined with molecular dynamics simulations are employed to examine the frequency distributions and IR spectra of isotope-labeled local modes (ILMs) in parallel coiled-coil dimers.
View Article and Find Full Text PDFSensors (Basel)
August 2025
College of Engineering, China Agricultural University, Beijing 100083, China.
Accurate and timely land monitoring is crucial for addressing global environmental, economic, and societal challenges, including climate change, sustainable development, and disaster mitigation. While single-source remote sensing data offers significant capabilities, inherent limitations such as cloud cover interference (optical), speckle noise (radar), or limited spectral information (LiDAR) often hinder comprehensive and robust characterization of land surfaces. Recent advancements in synergistic harmonization technology for land monitoring, along with enhanced signal processing techniques and the integration of machine learning algorithms, have significantly broadened the scope and depth of geosciences.
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