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Decommissioning of nuclear facilities can be performed in stages. One of the stages and processes in decontamination is the decontamination process before dismantling or facility area recovery activities. Decontamination can be performed using various methods, primarily physical and chemical. One chemical method involves using a gel made of polymers for decontamination. In this study, a gel consisting of a mixture of 15 g polyvinyl alcohol (PVA), 15 mL of glycerol, and 2 g Na-EDTA was dissolved in 100 mL. The three materials were dissolved in hot conditions until they dissolved, and a gel was formed. The formed gel was applied to the material contaminated by Co-60 with a radioactivity of 81 µCi, as much as 5 µL. The decontamination radioactive efficiency test results range from 53% to 98%, with the highest decontamination efficiency observed on glass media. This study also showed that higher EDTA concentrations can increase the ability of the PVA-glycerol gel to absorb and bind Co. This study also found that decontamination efficiency was influenced by the type of contaminated material and the concentration of EDTA. It can be concluded that gels with a composition of PVA, glycerol, and EDTA can reduce the level of contamination on the surface of materials made of glass, ceramics, and metal plates.
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http://dx.doi.org/10.3390/gels11010056 | DOI Listing |
Polymers (Basel)
August 2025
College of Science and Engineering, Flinders University, Adelaide, SA 5042, Australia.
In this study, a bio-nanocomposite integrating calcium caseinate, modified starch, and bentonite nanoclay was formulated and synthesized into film form via solution casting. Glycerol was incorporated for plasticization, and polyvinyl alcohol (PVA) was used to enhance the structural and chemical attributes of the material. The addition of PVA and bentonite notably improved the mechanical strength of the casein-based matrix, showing up to a 30% increase in tensile strength compared to similar biopolymer formulations.
View Article and Find Full Text PDFPolymers (Basel)
August 2025
Food Technology Department, Federal University of Viçosa, Viçosa 36570-900, Brazil.
The objective of this study was to evaluate the physical, chemical, mechanical, thermal, and topological properties of polyvinyl alcohol (PVA) and gelatin (GL) films after incorporating three different fractions of blueberry extract: crude extract (EB, without purification), phenolic portion (EF), and concentrated anthocyanins (EA). Additionally, the study aimed to analyze the efficiency of these colorimetric indicator films in monitoring the freshness quality of shrimp. The experiment followed a completely randomized design with one factor-different types of films-studied at six levels: film incorporated with crude blueberry extract (FB), film incorporated with phenolic extract (FF), and film incorporated with anthocyanin extract (FA), in addition to the control films: the plasticized blend containing glycerol, PVA, and GL (FC), the pristine gelatin film (FG), and the pristine PVA film (FPVA).
View Article and Find Full Text PDFGels
August 2025
Key Laboratory of High Efficiency and Clean Mechanical Manufacture of Ministry of Education, School of Mechanical Engineering, Shandong University, Jinan 250061, China.
Traditional hydrogel preparation methods typically require multiple steps and certain external stimuli. In this study, rapid and stable gelation of polyvinyl alcohol (PVA)-tannic acid (TA)-based hydrogels was achieved through the regulation of hydrogen bonds. The cross-linking between PVA and TA is triggered by the evaporation of ethanol.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
August 2025
Institutes of Physical Science and Information Technology, School of Materials Science and Engineering, Leibniz International Joint Research Centre of Materials Sciences of Anhui Province, Anhui University, Hefei, 230601, China.
Four-electron aqueous zinc-iodine batteries (4eAZIBs) with the successful I/I/I redox couples have emerged as a promising alternative for large-scale energy storage due to their high energy density. However, the practical application of these batteries, particularly in harsh environments, is hindered by the poor reversibility of Zn plating/stripping processes and the instability of I species in conventional aqueous electrolytes. Here, we design a multi-component hybrid electrolyte composed of Zn(ClO), ZnCl, glycerol (Gly), and polyvinyl alcohol (PVA) to enable highly reversible operation of 4eAZIBs across a wide temperature range.
View Article and Find Full Text PDFACS Omega
August 2025
College of Chemistry and Chemical Engineering, Xinjiang Agricultural University, Urumqi 830000, Xinjiang, China.
Traditional plastic films have caused serious environmental issues due to "white pollution". This study isolates lignin from cottonseed hulls to explore alternatives to plastic films. Using both cottonseed hull lignin and commercially sourced white lignin as raw materials, we performed hydroxy-methylation modification via physical and chemical cross-linking to obtain hydroxy-methylated cottonseed hull lignin and hydroxy-methylated white lignin, resulting in hydroxy-methylated lignin with improved hydrophilicity.
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