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The two-dimensional kagome lattice is an experimental playground for novel physical phenomena, from frustrated magnetism and topological matter to chiral charge order and unconventional superconductivity. A newly identified kagome superconductor, TaVSi has recently gained attention for possessing a record high critical temperature, = 7.5 K for kagome metals at ambient pressure. In this study we conducted a series of muon spin rotation measurements to delve deeper into understanding the superconducting and normal state properties of TaVSi. We demonstrate that TaVSi is a bulk superconductor with either a s+s-wave or anisotropic s-wave gap symmetry, and has an unusual paramagnetic shift in response to external magnetic fields in the superconducting state. Additionally, we observe an exceptionally low superfluid density - a distinctive characteristic of unconventional superconductivity - which remarkably is comparable to the superfluid density found in hole-doped cuprates. In its normal state, TaVSi exhibits a significant increase in the zero-field muon spin depolarisation rate, starting at approximately 150 K, which has been observed in other kagome-lattice superconductors, and therefore hints at possible hidden magnetism. These findings characterise TaVSi as an unconventional superconductor and a noteworthy new member of the vanadium-based kagome material family.
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http://dx.doi.org/10.1038/s43246-024-00666-2 | DOI Listing |
Nanoscale
September 2025
School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, People's Republic of China.
The potential of hafnia-based ferroelectric materials for Ferroelectric Random Access Memory (FeRAM) applications is limited by the imprint effect, which compromises readout reliability. Here, we systematically investigate the asymmetric imprint behavior in W/HfZrO/W ferroelectric capacitors, demonstrating that the imprint direction correlates directly with the ferroelectric polarization state. Notably, a pre-pulse of specific polarity can temporarily suppress the imprint effect.
View Article and Find Full Text PDFChembiochem
September 2025
Chemistry Department, Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow, 119991, Russia.
Nucleic acid aptamers are artificial recognition elements with great potential in biotechnology. For their effective integration into nanodevices, rational strategies for optimizing aptamer affinity and regulating activity are essential. Artificial nucleotide analogs offer versatile tools for both fundamental and applied research in the aptamer field.
View Article and Find Full Text PDFOrg Lett
September 2025
State Key Laboratory of Chemical Biology, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.
The coupling of -acyl-'-substituted hydrazines with (hetero)aryl bromides and chlorides is efficiently catalyzed by CuI/4-hydroxy picolinamide and Cu(OAc)/6-hydroxy picolinohydrazide, respectively. Under these conditions, a broad range of (hetero)aryl halides and -acyl-'-substituted hydrazines react smoothly at 80-120 °C, affording the corresponding products in good to excellent yields in most cases.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Key Laboratory of Quantum Materials and Devices of Ministry of Education, School of Physics, Southeast University, Nanjing 211189, China.
Tailoring the crystalline structure and facet orientation of T-NbO anode electrodes is pivotal for optimizing the Li transport kinetics. Herein, a crystallization engineering strategy is employed to synthesize urchin-like T-NbO microspheres composed of single-crystalline whiskers growing along the (001) orientation. These whiskers are characterized by nearly 100% exposed vertical (001) facets that accelerate Li diffusion.
View Article and Find Full Text PDFNano Lett
September 2025
Institute of Energy Materials Science, University of Shanghai for Science and Technology, Shanghai 200093, P. R. China.
Ampere-level electrocatalytic nitrate reduction to ammonia (eNRA) offers a carbon-neutral alternative to the Haber-Bosch process. However, its energy efficiency is critically hampered by the inherent conflict between the reaction and diffusion. Herein, we propose a reaction-diffusion-coupled strategy implemented on a well-tailored CuCoNiRuPt high-entropy alloy aerogel (HEAA) to simultaneously realize energy barrier homogenization and accelerate mass transport, endowing ampere-level eNRA with a high energy efficiency.
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