Oriented Crystal Polarization Tuning Bulk Charge and Single-Site Chemical State for Exceptional Hydrogen Photo-Production.

Rapid bulk charge recombination and mediocre surface catalytic sites harshly restrict the photocatalytic activities. Herein, the aforementioned concerns are well addressed by coupling macroscopic spontaneous polarization and atomic-site engineering of CdS single-crystal nanorods for superb H photo-production. The oriented growth of CdS nanorods along the polar axis, vectorially superimposing substantial polar units with orderly arrangement, renders a strong polarization electric field (20.1 times enhancement), which boosts bulk charge separation with an efficiency up to 72.4% (80.4-fold). Remarkably, polarization electric field alters the chemical state of Pt single sites by orderly reducing the binding energy of Pt atom with stepwise polarization enhancement of CdS substrate, which increases the onsite electron density of Pt from 10.232 to 10.261e and *H key intermediates, providing preponderant Volmer-Tafel/Volmer-Heyrovsky reaction pathways with significantly decreased energy barriers for H production. Thus, highly polarized CdS nanorods with atomically dispersed Pt sites perform an outstanding H space-time yield of 118.5 mmol g h and apparent quantum efficiency of 57.7% at λ = 420 nm, and a record-high H turnover frequency of 57798.4 h, being one of the best catalysts for photocatalytic H evolution. This work highlights the function of polarization in manipulating charge separation and catalytic reaction.