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Reinforced concrete structures are prone to the corrosion of steel bars when exposed to chloride-rich environments, which can severely impact their durability. To address this issue, a comprehensive understanding of the factors influencing chloride ion diffusion in concrete is essential. This paper provides a summary of recent domestic and foreign research on chloride ion transport in concrete, focusing on six key factors: water-binder ratio, additive content, crack width, ambient temperature, relative humidity, and dry-wet cycles. The findings show that the diffusion coefficient of chloride ions in concrete increases with a higher water-binder ratio and decreases with increased additive content. Additionally, wider cracks result in a greater diffusion of chloride ions. The permeability resistance of concrete to chloride ions decreases with rising temperature and humidity, and dry-wet cycles further accelerate the diffusion of chloride ions. The article concludes by discussing various anti-corrosion measures, such as the use of corrosion inhibitors, surface coatings, and electrochemical treatments, to ensure the longevity of the structure. Finally, directions for future research are proposed.
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http://dx.doi.org/10.3390/ma17133296 | DOI Listing |
Mol Ther
September 2025
Center for Single-Cell Omics, School of Public Health, Shanghai Jiao Tong University School of Medicine, Shanghai, China; State Key Laboratory of Systems Medicine for Cancer, Shanghai Jiao Tong University School of Medicine, Shanghai, China; Pancreatic Cancer Heterogeneity, Candiolo Cancer Institute
Pancreatic ductal adenocarcinoma (PDAC) is an aggressive cancer with poor prognosis, partly due to cancer stem cells (CSCs) that drive progression and treatment resistance. We explored the therapeutic potential of inducing cuproptosis, a copper-dependent regulated cell death, in CSC-enriched PDAC models. Using human and murine PDAC models, we evaluated elesclomol, a copper transport enhancer.
View Article and Find Full Text PDFChem Commun (Camb)
September 2025
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & State Key Laboratory of Silicate Materials for Architectures & School of Chemistry, Chemical Engineering and Life Sciences & School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, 430070
Photocatalytic seawater splitting (PSWS), which utilizes abundant solar and ocean resources, is one of the most promising technologies for sustainable hydrogen production. However, the complex composition of seawater significantly limits the durability and activity of photocatalysts. In this review, we first identify the primary factors that contribute to photocatalyst deactivation during PSWS, including chloride induced corrosion and loss of active sites, and light shielding caused by precipitation of metal cation salts.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health, Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control, Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006, China.
Low molecular weight amines promote sulfate (SO and HSO) formation through acid-base reactions, contributing to fine particulate matter (PM). Heterogeneous ozonation converts nontoxic amine salts into highly toxic products, yet the ozonation activation mechanism is unclear. This work reveals a sulfate-dominant ozonation mechanism of amine salts in fine PM by combining advanced mass spectrometry and ab initio calculation methods.
View Article and Find Full Text PDFBeilstein J Org Chem
August 2025
Department of Chemistry, Institute of Natural Sciences, Federal University of Lavras, 37200-900, Lavras, MG, Brazil.
Cyclopropane is a significant alicyclic motif, widely utilized in medicinal chemistry, while fluorination serves as a powerful tool to modulate properties that enhance the performance of pharmaceuticals and materials. This quantum-chemical study explores the energetic implications of fluorinating cyclopropane, providing insights into molecular characteristics arising from the polar C-F bond. Isodesmic reactions revealed that the conversion of cyclopropane and methyl fluoride into mono-, di-, tri-, tetra-, penta-, and hexafluorinated cyclopropanes is exothermic, except for the all--1,2,3-trifluorocyclopropane ().
View Article and Find Full Text PDFEnviron Res
September 2025
School of Resources and Safety Engineering, University of Science and Technology Beijing, Beijing 100083, China; Key Laboratory of Safe and Green Mining of Metal Mines with Cemented Paste Backfill, National Mine Safety Administration, University of Science and Technology Beijing, Beijing 100083, Chi
Cemented paste backfill has made outstanding contributions to the large-scale consumption of phosphogypsum (PG), but poor water resistance significantly weakens the mechanical strength, promotes the leaching of total soluble phosphate (TP) and fluoride ions (F), and reduces its attractiveness in mine engineering. This research synthesized a curing agent (CA) using sodium methylsilicate, sodium silicate, and polyaluminum chloride (PAC). PG produced from Deyang Haohua Qingping Phosphate Mine Co.
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