The rigid-flexible balanced molecular crosslinking network transition interface: An effective strategy for improving the performance of bamboo fibers/poly(butadiene succinate-co-butadiene adipate) biocomposites.

Int J Biol Macromol

Key Laboratory of Wood Material Science and Application, Beijing Forestry University, Ministry of Education, Beijing 100083, China; Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing 100083, China. Electronic address:

Published: September 2024


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Article Abstract

The poor interfacial compatibility of natural fiber-reinforced polymer composites has become a major challenge in the development of industry-standard high-performance composites. To solve this problem, this study constructs a novel rigid-flexible balanced molecular crosslinked network transition interface in composites. The interface improves the interfacial compatibility of the composites by balancing the stiffness and strength of the fibers and the matrix, effectively improving the properties of the composites. The flexural strength and flexural modulus of the composites were enhanced by 38 % and 44 %, respectively. Water absorption decreased by 30 %. The initial and maximum thermal degradation temperatures increased by 20 °C and 16 °C, respectively. The maximum storage modulus increased by 316 %. Furthermore, the impact toughness was elevated by 41 %, attributed to the crosslinked network's efficacy in absorbing and dissipating externally applied energy. This innovative approach introduces a new theory of interfacial reinforcement compatibility, advancing the development of high-performance and sustainable biocomposites.

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http://dx.doi.org/10.1016/j.ijbiomac.2024.133786DOI Listing

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