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Perovskite quantum dots (QDs) and organic materials have great research potential in the field of optoelectronic devices. In this paper, MEH-PPV/CsPbBrheterojunction photodetectors (PDs) are prepared by spin coating method based on the good photoelectric properties of CsPbBrperovskite QDs and MEH-PPV. The MEH-PPV/CsPbBrheterojunction improves the energy level arrangement, and CsPbBrQDs can passivate the surface defects of MEH-PPV films to achieve effective charge separation and transfer, thus inhibiting the dark current and improving the photoelectric performance of the device. Under 532 nm laser irradiation, the responsivity () of MEH-PPV/CsPbBrheterojunction PD is 11.98 A W, the specific detectivity (*) is 6.98 × 10Jones, and the response time is 15/16 ms. This work provides experience for the study of perovskite QDs and organic materials heterojunction optoelectronic devices.
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http://dx.doi.org/10.1088/1361-6528/ad4654 | DOI Listing |
Anal Chem
September 2025
School of Agricultural Engineering, Key Laboratory of Modern Agricultural Equipment and Technology (Ministry of Education), Jiangsu University, Zhenjiang, Jiangsu 212013, PR China.
To balance the "detection sensitivity" and "device stability" of the organic photoelectrochemical transistor (OPECT) aptasensors, it has become an urgent challenge for achieving effective signal modulation under low ascorbic acid (AA) conditions. To address this, our work proposed a collaborative optimization strategy by coupling heterojunction engineering with interfacial molecular modulation, to endow a high current gain of OPECT with low-AA -dependence. First, a CdZnS-SnInS heterojunction gate was constructed by in situ growth of CdZnS quantum dots (QDs) on SnInS nanoflowers, which enhanced the light trapping ability and photoelectric conversion efficiency of the photoactive gate.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Department of Applied Chemistry for Environment, Kwansei Gakuin University, 1 Gakuen Uegahara, Sanda, Hyogo 669-1330, Japan.
Colloidal semiconductor quantum dots (QDs) can generate multiple excitons (MXs) within a single QD. Owing to their large absorption cross-section, efficient utilization of MX is anticipated for the development of light-harvesting systems. However, MXs typically undergo nonradiative decay via Auger recombination (AR).
View Article and Find Full Text PDFAnal Chim Acta
November 2025
The Associated Laboratory for Green Chemistry (LAQV) of the Network of Chemistry and Technology (REQUIMTE) - the Portuguese Research Centre for Sustainable Chemistry, Department of Chemical Sciences, Faculty of Pharmacy, University of Porto, 4050-313, Porto, Portugal. Electronic address:
Background: When using semiconductor quantum dots (QDs) for single-analyte sensing, recognition is commonly achieved through interactions with capping ligands attached to the QDs surface. These ligands form an organic layer that provides stability in solution and assures selectivity by binding the target analyte via surface functional groups. However, a common analytical challenge arises in the subsequent stage of the QD-based sensing scheme.
View Article and Find Full Text PDFMikrochim Acta
September 2025
Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing, 400714, China.
A novel ternary synergistic photoelectrochemical (PEC) probe is presented utilizing metal-organic framework (MOF)-templated Pd/CdS@CoS nanocages for sensing chlorpyrifos (CPF) using chronoamperometry under an applied bias of - 65 mV with 465-nm LED illumination. Derived from ZIF-67 via in situ sulfidation, the hollow nanocage architecture integrated CdS nanoparticles with CoS to form a direct Z-scheme heterojunction, while decorating Pd quantum dots (QDs) created a Schottky barrier, implementing a crucial dual charge-transfer enhancement strategy. Density functional theory (DFT) simulations confirmed a 0.
View Article and Find Full Text PDFNat Commun
September 2025
Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing, China.
Perovskite quantum dot light-emitting diodes have rapidly achieved high external quantum efficiencies of over 25%; however, hindered by limited operating stability originating from surface defects or ion migration in quantum dots. Here, we design a lattice-matched anchoring molecule, tris(4-methoxyphenyl)phosphine oxide (TMeOPPO-p), to anchor the multi-site defects and stabilise the lattice. The target quantum dots exhibit high exciton recombination features with near-unity photoluminescence quantum yields (97%), and the as-fabricated quantum dot light-emitting diodes present a maximum external quantum efficiency of up to 27% at 693 nm, a low efficiency roll-off (over 20% at a current density of 100 mA cm for the typical device) and an operating half-life of over 23,000 h.
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