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Transition-metal dichalcogenides (TMDCs), as emerging optoelectronic materials, necessitate the establishment of an experimentally viable system to study their interaction with light. In this study, we propose and analyze a WS/PMMA/Ag planar Fabry-Perot (F-P) cavity, enabling the direct experimental measurement of WS absorbance. By optimizing the structure, the absorbance of A exciton of WS up to 0.546 can be experimentally achieved, which matches well with the theoretical calculations. Through temperature and thermal expansion strain induced by temperature, the absorbance of the A exciton can be tuned in situ. Furthermore, temperature-dependent photocurrent measurements confirmed the consistent absorbance of the A exciton under varying temperatures. This WS/PMMA/Ag planar structure provides a straightforward and practical platform for investigating light interaction in TMDCs, laying a solid foundation for future developments of TMDC-based optoelectronic devices.
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http://dx.doi.org/10.1364/OL.522089 | DOI Listing |
J Chem Phys
September 2025
Quantum Chemistry Division, Yokohama City University, Seto 22-2, Kanazawa-Ku, Yokohama 236-0027, Kanagawa, Japan.
Perovskite-silicon tandem solar cells have attracted considerable attention owing to their high power conversion efficiency (PCE), which exceeds the limits of single-junction devices. This study focused on lead-free tin-based perovskites with iodine-bromine mixed anions. Bromide perovskites have a wide bandgap; therefore, they are promising light absorbers for perovskite-silicon tandem solar cells.
View Article and Find Full Text PDFNano Lett
September 2025
Department of Chemistry, Ghent University, 9000 Gent, Belgium.
Optical amplification in CdSe nanoplatelets (NPLs) has been linked to biexcitons with a large binding energy Δ, preventing dissociation at room temperature. While the exciton binding energy Δ has been studied extensively, Δ in colloidal NPLs is typically inferred using the 2D Haynes rule, Δ = 0.228·Δ.
View Article and Find Full Text PDFNat Photonics
May 2025
Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Zürich, Switzerland.
The absorption of light via interband optical transitions plays a key role in nature and applied technology, enabling efficient photosynthesis and photovoltaic cells, fast photodetectors or sensitive (quantum) light-matter interfaces. In many such photonic systems, enhancing the light absorption strength would be beneficial for yielding higher device efficiency and enhanced speed or sensitivity. So far, however, cavity-free light absorbers feature poorly engineerable absorption rates, consistent with the notion that the coupling strength between the initial and final states is an intrinsic material parameter.
View Article and Find Full Text PDFJ Chem Theory Comput
August 2025
Department of Complex Systems Science, Graduate School of Informatics, Nagoya University, Nagoya 464-8601, Japan.
The light-harvesting complex 2 (LH2) of the purple bacteria absorbs sunlight and transfers energy to the RC with high efficiency. To achieve a microscopic understanding of the energy transfer process, theoretical analysis of the excited states of the bacteriochlorophyll pigment aggregates is effective. In particular, not only the locally excited (LE) states of pigments but also the charge transfer (CT) states between pigments play a significant role in the excited states of the B850 ring, where the pigments are in close proximity to each other.
View Article and Find Full Text PDFLayered materials such as graphene and transition metal dichalcogenides (TMDs) are excellent candidates as saturable absorbers. However, the saturable absorption of few-layer TMDs is usually measured at the typical wavelengths of lasers, away from the exciton resonances. In this work, we study the saturable absorption effects in one, two, and three-layer WS and WSe, around the A-exciton resonance, using a tunable pulsed laser.
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