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Article Abstract
Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters, [NbO@Ag(PrS)(CHCOO)] (Ag) and (HO)[NbO@AgKSO(HO)(PrS)(CHCOO)] (Ag), were synthesized using a facile one-pot solvothermal approach. Single crystal X-ray diffraction analyses revealed the presence of a classical Lindqvist-type [NbO] anion template, with PrS and CHCOO surface-protecting ligands in both silver clusters, which can further form two-dimensional Ag assembly and one-dimensional Ag chain packing structures. Both Ag and Ag clusters exhibited intriguing photothermal conversion properties and temperature-dependent emission behavior.
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