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Traditionally, manipulation of spatiotemporal coupling (STC) of the ultrafast light fields can be actualized in the space-spectrum domain with some 4-f pulse shapers, which suffers usually from some limitations, such as spectral/pixel resolution and information crosstalk associated with the 4-f pulse shapers. This work introduces a novel mechanism for direct space-time manipulation of ultrafast light fields to overcome the limitations. This mechanism combines a space-dependent time delay with some spatial geometrical transformations, which has been experimentally proved by generating a high-quality STC light field, called light spring (LS). The LS, owing a broad topological charge bandwidth of 11.5 and a tunable central topological charge from 2 to -11, can propagate with a stable spatiotemporal intensity structure from near to far fields. This achievement implies the mechanism provides an efficient way to generate complex STC light fields, such as LS with potential applications in information encryption, optical communication, and laser-plasma acceleration.
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http://dx.doi.org/10.1038/s41467-024-46802-x | DOI Listing |
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September 2025
Institute of Thin Film Physics and Applications, Shenzhen Key Laboratory of Advanced Thin Films and Applications, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, State Key Laboratory of Radio Frequency Heterogeneous Integration, College of Physic
Antimony selenide (SbSe), a narrow-bandgap semiconductor with strong light absorption, exhibits photoresponse up to ≈1050 nm due to its intrinsic 1.15 eV bandgap. To extend detection into the near-infrared (NIR, 700-1350 nm), Bi-alloyed (BiSb)Se is developed via vacuum sputtering and postselenization.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, U.K.
The electron-deficient oxidant 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) has recently emerged as a promising visible-light photoredox catalyst. However, its excited-state behavior remains poorly understood. Here, we investigate the ultrafast dynamics of photoexcited DDQ in acetonitrile using transient electronic and infrared absorption spectroscopy, supported by quantum chemical calculations.
View Article and Find Full Text PDFPlant Cell Physiol
September 2025
Biostructural Mechanism Laboratory, RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148, Japan.
Phycobilisome (PBS) is a water-soluble light-harvesting supercomplex found in cyanobacteria, glaucophytes, and rhodophytes. PBS interacts with photosynthetic reaction centers, specifically photosystems II and I (PSII and PSI), embedded in the thylakoid membrane. It is widely accepted that PBS predominantly associates with PSII, which functions as the initial complex in the linear electron transport chain.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2025
Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China; Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China. Electronic address:
The utilization of synergistic multivalent active sites holds potential in addressing the inherent sluggish kinetics of electrocatalytic reactions. Herein, we prepared au uNPs/Ni-NDC (NDC = 1,4-Naphthalenedicarboxylic acid) and leveraged the localized surface plasmon resonance (LSPR) effect to drive hot electron transfer from au nanoparticles to the Ni substrate, thereby generating multivalent active sites to boost the urea oxidation reaction (UOR). Under exciting light, au uNPs/Ni-NDC exhibited a twofold increase in UOR current accompanied by a significant negative shift in onset potential.
View Article and Find Full Text PDFInorg Chem
September 2025
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China.
Photocatalysis has emerged as a promising strategy to address water pollution caused by heavy metals and antibiotics. Zeolites exhibit significant potential in petrochemical catalysis; however, the development of zeolite-based photocatalysts remains a critical challenge for researchers. Herein, a novel Z-scheme heterojunction was designed and fabricated on the titanium-silicon zeolite TS-1 by modifying g-CN via a simple calcination process.
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