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The daunting effects of persistent organic pollutants on humans, animals, and the environment cannot be overemphasized. Their fate, persistence, long-range transport, and bioavailability have made them an environmental stressor of concern which has attracted the interest of the research community. Concerted efforts have been made by relevant organizations utilizing legislative laws to ban their production and get rid of them completely for the sake of public health. However, they have remained refractive in different compartments of the environment. Their bioavailability is majorly a function of different anthropogenic activities. Landfilling and incineration are among the earliest classical means of environmental remediation of waste; however, they are not sustainable due to the seepage of contaminants in landfills, the release of toxic gases into the atmosphere and energy requirements during incineration. Other advanced waste destruction technologies have been explored for the degradation of these recalcitrant pollutants; although, some are efficient, but are limited by high amounts of energy consumption, the use of organic solvents and hazardous chemicals, high capital and operational cost, and lack of public trust. Thus, this study has systematically reviewed different contaminant degradation technologies, their efficiency, and feasibility. Finally, based on techno-economic feasibility, non-invasiveness, efficiency, and environmental friendliness; radiation technology can be considered a viable alternative for the environmental remediation of contaminants in all environmental matrices at bench-, pilot-, and industrial-scale.
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http://dx.doi.org/10.1016/j.jhazmat.2024.133830 | DOI Listing |
Turk J Pediatr
September 2025
Department of Child and Adolescent Psychiatry, Ankara Bilkent City Hospital, Faculty of Medicine, Ankara Yıldırım Beyazıt University, Ankara, Türkiye.
Background: Intractable paroxysmal sneezing is a rare and diagnostically challenging condition in children, often mimicking organic diseases. While it is often addressed as psychogenic in the literature, our case presented findings suggestive of a tic disorder, highlighting the need for a broader diagnostic perspective.
Case Presentation: An 11-year-old girl was referred to the child and adolescent psychiatry clinic with a one-year history of persistent and fluctuating sneezing episodes.
Acc Chem Res
September 2025
Department of Chemistry, FRQNT Centre for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke Street W, Montréal, Québec H3A 0B8, Canada.
ConspectusMolecular photochemistry, by harnessing the excited states of organic molecules, provides a platform fundamentally distinct from thermochemistry for generating reactive open-shell or spin-active species under mild conditions. Among its diverse applications, the resurgence of the Minisci-type reaction, a transformation historically reliant on thermally initiated radical conditions, has been fueled by modern photochemical strategies with improved efficiency and selectivity. Consequently, the photochemical Minisci-type reaction ranks among the most enabling methods for C()-H functionalizations of heteroarenes, which are of particular significance in medicinal chemistry for the rapid diversification of bioactive scaffolds.
View Article and Find Full Text PDFEnviron Res
September 2025
School of Environmental Science and Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan, Hubei, 430074, China; Hubei Provincial Engineering Laboratory of Solid Waste Treatment, Disposal and Recycling, 1037 Luoyu Road, Wuhan, Hubei, 430074, China. Electronic address: ho
The activation of peroxymonosulfate (PMS) by biochar has shown promising potential for the efficient degradation and detoxification of antibiotics in wastewater. However, the underlying mechanisms are not fully understood. In this study, Fenton-conditioned sludge-derived biochar (FSBC) was prepared by microwave pyrolysis to activate PMS for the efficient degradation and detoxification of sulfamethoxazole (SMX).
View Article and Find Full Text PDFChemSusChem
September 2025
Institute of Organic Chemistry, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
Organic battery electrode materials represent a sustainable alternative compared to most inorganic electrodes, yet challenges persist regarding their energy density and cycling stability. In this work, a new organic electrode material is described, which is obtained via ionothermal polymerization of low-cost starting materials, melem (2,5,8-triamino-tri-s-triazine) and perylenetetracarboxylic dianhydride (PTCDA). The resulting networked polymer Melem-PDI exhibits favorable thermal and electrochemical properties, prompting investigation into its performance as a positive electrode material in rechargeable lithium and magnesium batteries.
View Article and Find Full Text PDFInt J Nanomedicine
September 2025
Department of Plastic Surgery, The Quzhou Affiliated Hospital of Wenzhou Medical University, Quzhou People's Hospital, Quzhou, 324000, People's Republic of China.
Diabetic infected wounds represent a formidable clinical challenge characterized by persistent hyperglycemia-induced pathological cascades that disrupt normal healing processes through multiple mechanisms including chronic inflammation, oxidative stress, and microvascular dysfunction. As prototypical chronic wounds, they exhibit severely impaired tissue regeneration due to this multifaceted dysfunction in both skin architecture and biological function. Metal-organic frameworks (MOFs) have emerged as promising next-generation therapeutic platforms owing to their exceptional structural tunability, multifunctional properties, and precise spatiotemporal drug delivery capabilities.
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