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Perovskite solar cells show great potential application prospects in the field of solar cells due to their promising properties. However, most perovskite solar cells that exhibit excellent photovoltaic performance typically require a carrier transport layer that necessitates a high-temperature annealing process. This greatly restricts the scalability and compatibility of perovskite solar cells in flexible electronics. In this paper, SnO nanoparticles with high crystallinity, good dispersibility and uniform particle size distribution are first prepared using a solvothermal method and dispersed in n-butanol solution. SnO electron transport layers are then prepared by a low-temperature spin coating method, and the photovoltaic characteristics of perovskite solar cells prepared with different SnO nanoparticles/n-butanol concentrations are studied. Results indicate that the rigid perovskite solar cell achieves the highest power conversion efficiency of 15.61% when the concentration of SnO nanoparticles/n-butanol is 15 mg mL. Finally, our strategy is successfully applying on flexible perovskite solar cells with a highest PCE of 14.75%. Our paper offers a new possibility for large-scale preparation and application of perovskite solar cells in flexible electronics in the future.
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http://dx.doi.org/10.3389/fchem.2024.1361275 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
Advanced Photovoltaics Research Center, Korea Institute of Science and Technology (KIST), Seoul 02792, Republic of Korea.
NiO is a p-type semiconductor widely used as a hole transport material in perovskite solar cells (PSCs), yet the impact of fabrication methods on its interfacial properties and the underlying mechanisms remains unclear. This study investigates how the fabrication process─nanoparticle precursor (NP NiO) and sputtering deposition (SP NiO)─and interfacial space charge effects influence charge transport and device performance in NiO/perovskite systems. SP NiO exhibits a higher Ni/Ni ratio and greater conductivity but induces significant hole depletion and band bending at the interface, leading to reduced open-circuit voltage and efficiency.
View Article and Find Full Text PDFAdv Mater
September 2025
Hoffmann Institute of Advanced Materials, Shenzhen Polytechnic University, 7098 Liuxian Boulevard, Shenzhen, 518055, China.
Phase segregation remains one of the most critical challenges limiting the performance and long-term operational stability of wide-bandgap perovskite solar cells (PSCs). This issue is especially pronounced in 1.84 eV wide-bandgap (WBG) perovskites, where severe halide phase segregation leads to compositional heterogeneity and accelerated device degradation.
View Article and Find Full Text PDFSmall Methods
September 2025
Department of Materials Science and Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, Republic of Korea.
Monolithic perovskite/silicon tandem (PST) solar cells are rapidly emerging as next-generation solar cells with significant potential for commercialization. This study presents a proof of concept for a silicon diffused junction-based PST cell, utilizing a passivated emitter rear contact (PERC) cell with a low-temperature (<200 °C) laser-fired contact process to minimize thermal damage. By introducing amorphous silicon to the emitter surface of PERC bottom cell, the open circuit voltage (V) improve from 0.
View Article and Find Full Text PDFAdv Mater
September 2025
Graduate School of Carbon Neutrality, Ulsan National Institute of Science and Technology (UNIST), UNIST-gil 50, Ulsan, 44919, Republic of Korea.
Spiro-OMeTAD has remained the benchmark hole-transporting material (HTM) in state-of-the-art perovskite solar cells, owing to its favorable energy level alignment and excellent interfacial compatibility. However, its practical implementation is critically hindered by the intrinsic instabilities introduced by conventional dopants such as lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and 4-tert-butylpyridine (tBP). While these dopants enhance electrical conductivity, they concurrently initiate multiple degradation pathways-including ionic migration, radical deactivation, and moisture/thermal-induced morphological failure-thereby compromising device longevity and reproducibility.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Institute of Chemistry of OrganoMetallic Compounds (ICCOM), National Research Council of Italy (CNR), Via G. Moruzzi 1, 56124 Pisa, Italy.
Mixed-halide perovskites of formula MAPb(BrI), where MA is methylammonium, are of great interest for optoelectronic applications (particularly high-efficiency solar cells) due to their finely tunable bandgap, which enables precise control over light absorption. However, their stability remains a critical challenge, notably due to reversible photoinduced halide segregation. Under continuous illumination, this process leads to the formation of Br- and I-rich domains, which lower device performance by introducing low-bandgap regions that trap charge carriers.
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