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Vanadium dioxide (VO) has garnered significant attention as a material for actively tunable infrared (IR) modulators due to its reversible and responsive modulation effect on IR radiation, which is accompanied by its intrinsic insulator-metal phase transition (IMT). Here, we propose a multilayer device structure that integrates VO film with microheater and interdigitated electrodes for cooperative thermal-electric field control of IMT. Our results demonstrate that while intense electric fields can trigger abrupt IMT, deep modulation of IR radiation requires energy integration through Joule heating, which limits the response time of IR transmission controlled by electric field. Thus, cooperative thermal-electric field control, which provides a constant, uniform temperature field while electrically switching the IMT, is more effective for achieving a faster response time and retaining the intrinsic modulation depth of VO-based IR modulators. Our findings offer valuable insights for the development of VO-based IR modulators with improved performance.
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http://dx.doi.org/10.1021/acsomega.3c02469 | DOI Listing |
Small Methods
September 2024
Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, School of Materials Science and Engineering, Peking University, Beijing, 100871, P. R. China.
The high thermal storage density of phase change materials (PCMs) has attracted considerable attention in solar energy applications. However, the practicality of PCMs is often limited by the problems of leakage, poor solar-thermal conversion capability, and low thermal conductivity, resulting in low-efficiency solar energy storage. In this work, a new system of MXene-integrated solid-solid PCMs is presented as a promising solution for a solar-thermal energy storage and electric conversion system with high efficiency and energy density.
View Article and Find Full Text PDFACS Omega
December 2023
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 610054, China.
Vanadium dioxide (VO) has garnered significant attention as a material for actively tunable infrared (IR) modulators due to its reversible and responsive modulation effect on IR radiation, which is accompanied by its intrinsic insulator-metal phase transition (IMT). Here, we propose a multilayer device structure that integrates VO film with microheater and interdigitated electrodes for cooperative thermal-electric field control of IMT. Our results demonstrate that while intense electric fields can trigger abrupt IMT, deep modulation of IR radiation requires energy integration through Joule heating, which limits the response time of IR transmission controlled by electric field.
View Article and Find Full Text PDF