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To promote the stability and functionality of native starch from colored highland barley (CHBS), the cross-linked modifications with sodium trimetaphosphate (STMP)/sodium tripolyphosphate (STPP) and citric acid were conducted to prepare CHB resistant starches (CHRSs), whose physicochemical characteristics, digestibility, and lipolysis inhibitory potential were also assessed. Results showed that the resistant starch amounts in CHBS were significantly increased after cross-linking and differed slightly among CHRSs. Citric acid modification of CHBS resulted in significantly higher amylose amounts, solubilities, swelling powers, and water-binding capacities than those under STMP/STPP modification within the cultivars (p < 0.05), with their crystalline patterns of A-type (white and blue) and C-type (black). STMP/STPP modified CHBS exhibited higher degrees of crystalline regions with B-type crystalline patterns. Due to the differences in structural properties and structure-based morphology, STMP/STPP cross-linked CHBS showed lower digestibility and citric acid cross-linked CHBS exhibited higher lipolysis inhibitory activities. Besides, the cross-linked modifications demonstrated more enhancements in functionalities of starches from white and blue cultivars than black cultivar.
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http://dx.doi.org/10.1016/j.foodres.2023.113493 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
Research Center for Materials Nanoarchitectonics, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044, Japan.
Sustainable and chemically resilient hydrogels are critically needed in biointerface engineering, particularly for 3D cell culture systems and surface modification under physiological to mildly alkaline conditions. However, physically cross-linked cellulose nanofiber (CNF) hydrogels─despite their renewable origin and biocompatibility─typically disintegrate at pH > 8, limiting their use in polydopamine (PDA)-based surface functionalization. Here, we present a simple and scalable physical treatment strategy to fabricate alkali-resistant, physically cross-linked hydrogels from carboxymethyl cellulose nanofibers (CMCF).
View Article and Find Full Text PDFCureus
July 2025
Department of Medicine and Surgery, University of Parma, Parma, ITA.
Hyaluronic acid is an endogenous molecule that acts by regulating several cellular processes, including proliferation, migration, and morphogenesis. The positive effect of this molecule on hard tissue and soft tissue regeneration is well-documented in the literature, as it actively participates in the process of tissue inflammation, thereby minimizing the damaging effects of the immune cell response on tissues. The cross-linked form of hyaluronic acid, obtained through modifications of the chemical structure of the native form, is characterized by a high capacity to resist mechanical stress and slow biodegradation, improving the clinical performance of this molecule.
View Article and Find Full Text PDFJ Compos Mater
October 2025
Innovations Institute in Ecomaterials, Ecoproducts and Ecoenergies, Biomass-based (I2E3), Université du Québec à Trois-Rivières (UQTR), Trois-Rivières, QC, Canada.
The mechanical characteristics of natural fibre composites (NFCs) are closely linked to fibre-matrix and fibre-fibre interactions. This work investigates the improvement of tensile properties of a flax/epoxy composite through the application of click chemistry reaction to a unidirectional-mat (UDM) reinforcement with modifications made on the short fibre mat and unidirectional flax fibre phases of the reinforcement. The surface of short flax fibres was fibrillated to increase the accessibility of hydroxyl groups for all preliminary reactions and the final click chemistry cross-linking, which creates stable covalent triazole bonds between azide and alkyne groups.
View Article and Find Full Text PDFIn Vivo
August 2025
Clinic and Policlinic for Dermatology and Venereology, University Medical Center Rostock, Rostock, Germany;
Background/aim: The aim of the present research is a comprehensive evaluation of a fish-collagen based wound membrane using established and methodologies. A porcine pericardium membrane served as control material.
Materials And Methods: Scanning electron microscopy (SEM) and attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR) analysis were initially used to analyze the structure and collagen molecular structure.
Gels
August 2025
National Institute for Laser, Plasma and Radiation Physics, 409 Atomistilor St., 077125 Magurele, Romania.
Prolonged drought and soil degradation severely affect soil fertility and limit crop productivity. Superabsorbent hydrogels offer an effective solution for improving water retention in soil and supporting plant growth. In this work, we examined the performance of superabsorbent hydrogels based on sodium alginate, acrylic acid (AA), and poly (ethylene oxide) (PEO) cross-linked with 12.
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