Adsorbed Water Promotes Chemically Active Environments on the Surface of Sodium Chloride.

Gas-particle interfaces are chemically active environments. This study investigates the reactivity of SO on NaCl surfaces using advanced experimental and theoretical methods with a NHCl substrate also examined for cation effects. Results show that NaCl surfaces rapidly convert to NaSO with a new chlorine component when exposed to SO under low humidity. In contrast, NHCl surfaces have limited SO uptake and do not change significantly. Depth profiles reveal transformed layers and elemental ratios at the crystal surfaces. The chlorine species detected originates from Cl expelled from the NaCl crystal structure, as determined by atomistic density functional theory calculations. Molecular dynamics simulations highlight the chemically active NaCl surface environment, driven by a strong interfacial electric field and the presence of sub-monolayer water coverage. These findings underscore the chemical activity of salt surfaces and the unexpected chemistry that arises from their interaction with interfacial water, even under very dry conditions.