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This study aims to explore the effects of Thermoplastic Polyurethane (TPU) content on the weld line properties of Polypropylene (PP) and Acrylonitrile Butadiene Styrene (ABS) blends. In PP/TPU blends, increasing the TPU content results in a significant decrease in the PP/TPU composite's ultimate tensile strength (UTS) and elongation values. Blends with 10 wt%, 15 wt%, and 20 wt% TPU and pure PP outperform blends with 10 wt%, 15 wt%, and 20 wt% TPU and recycled PP in terms of UTS value. The blend with 10 wt% TPU and pure PP achieves the highest UTS value of 21.85 MPa. However, the blend's elongation decreases due to the poor bonding in the weld line area. According to Taguchi's analysis, the TPU factor has a more significant overall influence on the mechanical properties of PP/TPU blends than the recycled PP factor. Scanning electron microscope (SEM) results show that the TPU area has a dimple shape on the fracture surface due to its significantly higher elongation value. The 15 wt% TPU sample achieves the highest UTS value of 35.7 MPa in ABS/TPU blends, which is considerably higher than other cases, indicating good compatibility between ABS and TPU. The sample containing 20 wt% TPU has the lowest UTS value of 21.2 MPa. Furthermore, the elongation-changing pattern corresponds to the UTS value. Interestingly, SEM results present that the fracture surface of this blend is flatter than the PP/TPU blend due to a higher compatibility rate. The 30 wt% TPU sample has a higher rate of dimple area than the 10 wt% TPU sample. Moreover, ABS/TPU blends gain a higher UTS value than PP/TPU blends. Increasing the TPU ratio mainly reduces the elastic modulus of both ABS/TPU blends and PP/TPU blends. This study reveals the advantages and disadvantages of mixing TPU with PP or ABS to ensure that it meets the requirements of the intended applications.
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http://dx.doi.org/10.3390/polym15102321 | DOI Listing |
RSC Adv
August 2025
School of Pharmacy, Henan University Kaifeng China
: To synthesize and evaluate the function of antibacterial and anticoagulant properties of amphiphilic carbonaceous particle (ACP) derived polyurethane composite membranes TPU/ACPs-CS-PVS-Ag/ACPs-CS-Hep. : ACPs, ACPs-CS, ACPs-CS-PVS-Ag, ACPs-CS-Hep and ACPs-CS-PVS-Ag/ACPs-CS-Hep were prepared and mixed with a TPU matrix, to assess the dispersibility respectively. The blank TPU, TPU/ACPs, TPU/ACPs-CS, TPU/ACPs-CS-PVS-Ag, TPU/ACPs-CS-Hep and TPU/ACPs-CS-PVS-Ag/ACPs-CS-Hep membranes were prepared.
View Article and Find Full Text PDFMacromol Rapid Commun
August 2025
Department of Industrial and Mechanical Engineering, Rochester Institute of Technology, Dubai, United Arab Emirates.
4D printing of shape memory polymers (SMPs) offers transformative potential for patient-specific medical devices, yet current SMPs often face a trade-off between mechanical toughness and low-temperature activation. This study presents a novel PLA/APHA/TPU blend filament for 3D printing that overcomes this limitation by combining high strength and flexibility with low-temperature shape memory activation-features not previously achieved in PLA-based SMPs. The uniform dispersion of TPU and APHA in the PLA matrix creates a composite with enhanced tensile strength, modulus, and elongation, addressing the brittleness typical of neat PLA.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2025
State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China.
The synthesis and optimization of antibacterial agents for thermoplastic polyurethane (TPU) matrices is highly imperative for the development of antibacterial TPUs, especially for applications in biomedical devices. Macromolecular or polymer-based antimicrobials are extremely appealing for their environmental compatibility, low toxicity toward host cells, and low-leachable characteristic, making them ideal additives for antibacterial materials. Herein, quaternary ammonium salt (QAS)-containing copolyesters of P(MBL-N-CL) were designed and synthesized as polymeric antimicrobials via ring-opening copolymerization (ROCP) of α-methylene-γ-butyrolactone (MBL) and ε-caprolactone (ε-CL) followed by selective post-functionalization via the thiol-ene "click" reaction to introduce cationic moieties.
View Article and Find Full Text PDFAnalyst
July 2025
Faculty of Science and Engineering, Manchester Metropolitan University, Dalton Building, Chester Street, M1 5GD, Great Britain.
Rapid, on-site analysis of environmental contaminants necessitates the use of cost-effective and straightforward apparatus to encourage widespread adoption and align with the United Nations Sustainable Development Goal 6: Clean Water and Sanitation. In this work, we report the development of highly conductive thermoplastic polyurethane (TPU) filaments that can be easily cut and assembled into "sticks", functioning as standalone rod-like working electrodes for electrochemical and electroanalytical applications. Using TPU as the base polymer, filaments filled with 35, 40, and 45 wt% carbon black (CB) were fabricated and characterised both physicochemically and electrochemically at different lengths (2.
View Article and Find Full Text PDFBiomimetics (Basel)
April 2025
Advanced Materials and Manufacturing Technologies Laboratory, Department of Industrial Engineering and Management, School of Engineering, International Hellenic University, 57001 Thessaloniki, Greece.
The development of prosthetic limbs has benefited individuals who suffered amputations due to accidents or medical conditions. During the development of conventional prosthetics, several challenges have been observed regarding the functional limitations, the restricted degrees of freedom compared to an actual human limb, and the biocompatibility issues between the surface of the prosthetic limb and the human tissue or skin. These issues could result in mobility impairments due to failed mimicry of the actual stress distribution, causing discomfort, chronic pain, and tissue damage or possible infections.
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