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Excitons, electron-hole pairs in semiconductors, can be utilized as information carriers with a spin or valley degree of freedom. However, manipulation of excitons' motion is challenging because of their charge-neutral characteristic and short recombination lifetimes. Here we demonstrate electric-field-driven drift and funneling of charged excitons (i.e., trions) toward the center of a MoSe monolayer. Using a simple bottom-gate device, we control the electric fields in the vicinity of the suspended monolayer, which increases the trion density and pulls down the layer. We observe that locally excited trions are subjected to electric force and, consequently, drift toward the center of the stretched layer. The exerting electric force on the trion is estimated to be 10-10 times stronger than the strain-induced force in the stretched monolayer, leading to the successful observation of trion drift under continuous-wave excitation. Our findings provide a new route for manipulating trions and achieving new types of optoelectronic devices.
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http://dx.doi.org/10.1021/acs.nanolett.3c00460 | DOI Listing |
Nanophotonics
May 2025
Department of Physics, Korea University, Seoul, 02841, South Korea.
Excitons, which are bound states of electrons and holes, in transition metal dichalcogenides (TMDCs) have been studied as an information carrier for realizing new types of optoelectronic devices. However, the charge neutrality of excitons inhibits the electric control of their motion, as seen in conventional electronic devices, except when utilizing a heterostructure. Here, we investigated the drift motion of trions, quasiparticles composed of an exciton bound to an excess charge, at room temperature in a suspended WS monolayer by applying a gate-tunable electric field.
View Article and Find Full Text PDFNano Lett
May 2023
Department of Physics, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Republic of Korea.
Excitons, electron-hole pairs in semiconductors, can be utilized as information carriers with a spin or valley degree of freedom. However, manipulation of excitons' motion is challenging because of their charge-neutral characteristic and short recombination lifetimes. Here we demonstrate electric-field-driven drift and funneling of charged excitons (i.
View Article and Find Full Text PDFJ Phys Chem Lett
June 2022
Ultrafast Photophysics of Quantum Devices Laboratory, Department of Physics and Astronomy, Clemson University, Clemson, South Carolina 29634, United States.
It remains challenging to capture and investigate the drift dynamics of primary hot carriers because of their ultrashort lifetime (∼200 fs). Here we report a new mechanism for hot carrier (∼25 ps) generation in monolayer transition metal dichalcogenides such as WS and WSe, triggered by the Auger recombination of trions and biexcitons. Using ultrafast photocurrent spectroscopy, we measured and characterized the photocurrent stemming from the Auger recombination of trions and biexcitons in WS and WSe.
View Article and Find Full Text PDFSci Adv
February 2022
Department of Physics, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea.
Understanding and controlling the nanoscale transport of excitonic quasiparticles in atomically thin two-dimensional (2D) semiconductors are crucial to produce highly efficient nano-excitonic devices. Here, we present a nanogap device to selectively confine excitons or trions of 2D transition metal dichalcogenides at the nanoscale, facilitated by the drift-dominant exciton funneling into the strain-induced local spot. We investigate the spatiospectral characteristics of the funneled excitons in a WSe monolayer (ML) and converted trions in a MoS ML using hyperspectral tip-enhanced photoluminescence imaging with <15-nm spatial resolution.
View Article and Find Full Text PDFNano Lett
July 2021
Department of Physics, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong.
Monolayer transition metal dichalcogenides (ML-TMDCs) are a versatile platform to explore the transport dynamics of the tightly bound excitonic states. The diffusion of neutral excitons in various ML-TMDCs has been observed. However, the transport of charged excitons (trions), which can be driven by an in-plane electric field and facilitate the formation of an excitonic current, has yet been well investigated.
View Article and Find Full Text PDF