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Bacterial cellulose (BC) lithium-ion batteries separators possess outstanding thermal dimensional stability and electrolyte wettability, but theirs nano diameter and high aspect ratio lead to poor porosity and pore size uniformity of dense BC separators, limiting the Li transmission in the separators. In this paper, chitosan (CS) with different molecular weight was grafted onto BC (named OBCS), and a high-performance OBCS separator with excellent pore structure and tunable pore size was prepared by simple suction filtration. The spacing and dispersion uniformity of OBCS were improved by the CS grafted on BC surface, thus improving the pore structure and porosity of OBCS separators. The results showed that the obtained OBCS separators not only have excellent physicochemical properties, but also exhibit higher electrochemical performances than the commercial polypropylene (PP) separator. This work provides a new feasible strategy for improving the pore structure and porosity of nanocellulose separators.
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http://dx.doi.org/10.1016/j.carbpol.2022.120489 | DOI Listing |
Nanoscale Adv
July 2025
University of Kentucky, Department of Chemical and Materials Engineering 177 F.P. Anderson Tower Lexington Kentucky 40506-0046 USA
The crystallization behavior of ionic liquids (ILs) 1-butyl-3-methylimidazolium [BMIM] hexafluorophosphate [PF] and chloride [Cl] is investigated upon confinement in 2.3 or 8.2 nm diameter silica nanopore arrays, along with the effects of covalently modifying the pore walls with 1-(3-trimethoxysilylpropyl)3-methylimidazolium [TMS-MIM] groups.
View Article and Find Full Text PDFNat Rev Mol Cell Biol
September 2025
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA, USA.
The defining property of eukaryotic cells is the storage of heritable genetic material in a nuclear compartment. For eukaryotic cells to carry out the myriad biochemical processes necessary for their function, macromolecules must be efficiently exchanged between the nucleus and cytoplasm. The nuclear pore complex (NPC) - which is a massive assembly of ~35 different proteins present in multiple copies totalling ~1,000 protein subunits and architecturally conserved across eukaryotes - establishes a size-selective channel for regulated bidirectional transport of folded macromolecules and macromolecular assemblies across the nuclear envelope.
View Article and Find Full Text PDFFood Res Int
November 2025
Institute of Food Science and Technology, Chinese Academy of Agricultural Sciences (CAAS) / Key Laboratory of Agro-Products Processing, Ministry of Agriculture and Rural Affairs, Beijing 100193, PR China; College of Food Science, Shenyang Agricultural University, Shenyang 110866, China. Electronic a
While restructuring agricultural products enhances heat and mass transfer during freeze-drying, the underlying mechanisms remain poorly understood. This study employed a multiscale approach, combining freezing dynamics, sublimation drying kinetics, X-ray tomography, gas permeability assessments, thermodynamic parameters analysis, and mathematical modeling to systematically investigate the differences in transfer properties between natural and restructured peaches across the freezing and sublimation drying processes. Key results demonstrated that restructuring decreased the freezing time by 21.
View Article and Find Full Text PDFJ Occup Environ Hyg
September 2025
Division of Biology, Chemistry, and Materials Science, Office of Science and Engineering Laboratories, US Food and Drug Administration (FDA), Oak Ridge, Tennessee.
This work assesses the current characterization framework of single-use personal protective equipment (PPE) per recognized consensus standards and presents a novel quantitative approach to refining characterization of barrier materials and predicting PPE performance. Scanning electron microscopy (SEM) and image analysis software (Diameter J) were used to examine the microscopic fiber and pore structure of filter layers of surgical N95 filtering facepiece respirators, before and after exposure to chemicals used in decontamination modalities (vaporized hydrogen peroxide or ozone). The effect of porosity on penetration was assessed by bacterial filtration efficiency (BFE) testing.
View Article and Find Full Text PDFAdv Sci (Weinh)
September 2025
Bazylak Group, Department of Mechanical & Industrial Engineering, University of Toronto, 5 King's College Road, Toronto, ON, M5S 3G8, Canada.
In this study, the effects of operating temperature on pore-scale gas bubble transport in a carbon-based anode porous transport layer (PTL) of a polymer electrolyte membrane (PEM) electrolyzer is revealed using operando X-ray computed tomography (CT). Higher temperature operation (80 °C compared to 40 °C) led to a lower total gas bubble volume fraction in the PTL (0.25 to 0.
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